Seeing that some commercial gas adsorption instrument still uses a too rough method for cal-culation of mesopore size distribution, we reviewed some practical methods of calculation so farproposed in the literature. W...Seeing that some commercial gas adsorption instrument still uses a too rough method for cal-culation of mesopore size distribution, we reviewed some practical methods of calculation so farproposed in the literature. We have found that most of these methods and many books have someincorrectness in the geometric factor Q_i used for the calculation of pore volume △V_i from corevolume △V_i^k. It has been proved that the correct expression for Q_i should be[_i/(_i^k+1/2△t_i)]~2for cylindrical pores, _i,/(_i^k+1/2△t_i)for slit-shaped pores. On the basis of this correct Q_i,these methods were applied to the desorption isotherms. The results were compared and analyzed.展开更多
文摘Seeing that some commercial gas adsorption instrument still uses a too rough method for cal-culation of mesopore size distribution, we reviewed some practical methods of calculation so farproposed in the literature. We have found that most of these methods and many books have someincorrectness in the geometric factor Q_i used for the calculation of pore volume △V_i from corevolume △V_i^k. It has been proved that the correct expression for Q_i should be[_i/(_i^k+1/2△t_i)]~2for cylindrical pores, _i,/(_i^k+1/2△t_i)for slit-shaped pores. On the basis of this correct Q_i,these methods were applied to the desorption isotherms. The results were compared and analyzed.
