This study presents geochemical characteristics of glauconites in estuarine deposits within the Maastrichtian Lameta Formation in central India. Resting conformably over the Bagh Group, the Lameta Formation consists o...This study presents geochemical characteristics of glauconites in estuarine deposits within the Maastrichtian Lameta Formation in central India. Resting conformably over the Bagh Group, the Lameta Formation consists of ~4-5 m thick arenaceous, argillaceous and calcareous green sandstones underlying the Deccan Traps. The sandstone is friable, medium-to coarse-grained, well-sorted and thoroughly crossstratified, and contains marine fossils. Detailed petrography, spectroscopy and mineral chemistry indicates unique chemical composition of glauconite with high KO, MgO, AlOand moderate TFeO. Glauconite is formed by the replacement of K-feldspars, initially as stringers in the cleavages and fractures of feldspars. Incipient glauconite subsequently evolves fully, appearing as pellets. Fully-evolved glauconite pellets often leave tiny relics of K-feldspar. XRD exhibits characteristic peak of 10A from basal(001)reflection of glauconite, indicating the "evolved" character. The KO content of glauconites in the Lameta Formation varies from 5.51% to 8.29%, corroborating the "evolved" to "highly-evolved" maturation stage.The TFeOcontent of glauconite varies from 12.56% to 18.90%. The PASS-normalized-REE patterns of glauconite exhibit a "hat-shape" confirming the authigenic origin of glauconites. The slightly-negative to slightly-positive Ce anomaly value and the moderate TFeOcontent of glauconite agree well with a suboxic,estuarine condition. The replacement of K-feldspar by the glauconite contributes towards the high KO content. Compositional evolution of glauconites in the Lameta Formation is similar to those observed in many Precambrian sedimentary sequences.展开更多
This study presents a review on palaeogeographic implications and temporal variations of giaucony coveringboth modern and ancient records. Phanerozoic giaucony preferably forms in a shelf depositional setting. Deep ma...This study presents a review on palaeogeographic implications and temporal variations of giaucony coveringboth modern and ancient records. Phanerozoic giaucony preferably forms in a shelf depositional setting. Deep marine conditions and low seawater temperature discourage formation of glaucony. Around 75% of glaucony is recorded from the Cretaceous to the Holo- eene sediments, which are related to the abundance of the most common substrates, faecal pellets and bioclasts. TFe203 (total), A1203, K20 and MgO contents of glaucony vary appreciably through geological time. IMhile TFe203 content of most Mesozoic and Cenozoic giaucony ex- ceeds 20%, it is always less than 20% in Precambrian varieties. High K20, A1203, MgO and low TFe203 distinguish the Precambrian glaucony from its Phanerozoic counterpart. Precambrian glaucony, preferably formed within a K-feldspar substrate, is always rich in potassium irre- spective of its degree of evolution, while high K-content in Phanerozoic evolved glaucony in- dicates significant stratigraphic condensation. K20 iJs. TFe203 relationship of glaucony exhibits three different evolutionary trends corresponding to three common modes of origin. Depositional conditions may influence the composition of glaucony as slightly reducing conditions favour Fe enrichment, whereas oxidising conditions cause Fe depletion in giaucony.展开更多
基金Ministry of Mines, Government of India for financial support through grant F No. 14/77/2015Met. IV
文摘This study presents geochemical characteristics of glauconites in estuarine deposits within the Maastrichtian Lameta Formation in central India. Resting conformably over the Bagh Group, the Lameta Formation consists of ~4-5 m thick arenaceous, argillaceous and calcareous green sandstones underlying the Deccan Traps. The sandstone is friable, medium-to coarse-grained, well-sorted and thoroughly crossstratified, and contains marine fossils. Detailed petrography, spectroscopy and mineral chemistry indicates unique chemical composition of glauconite with high KO, MgO, AlOand moderate TFeO. Glauconite is formed by the replacement of K-feldspars, initially as stringers in the cleavages and fractures of feldspars. Incipient glauconite subsequently evolves fully, appearing as pellets. Fully-evolved glauconite pellets often leave tiny relics of K-feldspar. XRD exhibits characteristic peak of 10A from basal(001)reflection of glauconite, indicating the "evolved" character. The KO content of glauconites in the Lameta Formation varies from 5.51% to 8.29%, corroborating the "evolved" to "highly-evolved" maturation stage.The TFeOcontent of glauconite varies from 12.56% to 18.90%. The PASS-normalized-REE patterns of glauconite exhibit a "hat-shape" confirming the authigenic origin of glauconites. The slightly-negative to slightly-positive Ce anomaly value and the moderate TFeOcontent of glauconite agree well with a suboxic,estuarine condition. The replacement of K-feldspar by the glauconite contributes towards the high KO content. Compositional evolution of glauconites in the Lameta Formation is similar to those observed in many Precambrian sedimentary sequences.
基金Department of Science and Technology,Government of India for financial support through Grant IR/S4/ESF-16/2009(2)DST-IITB National Facility for EPMA,Department of Earth Sciences,Indian Institute of Technology Bombay
文摘This study presents a review on palaeogeographic implications and temporal variations of giaucony coveringboth modern and ancient records. Phanerozoic giaucony preferably forms in a shelf depositional setting. Deep marine conditions and low seawater temperature discourage formation of glaucony. Around 75% of glaucony is recorded from the Cretaceous to the Holo- eene sediments, which are related to the abundance of the most common substrates, faecal pellets and bioclasts. TFe203 (total), A1203, K20 and MgO contents of glaucony vary appreciably through geological time. IMhile TFe203 content of most Mesozoic and Cenozoic giaucony ex- ceeds 20%, it is always less than 20% in Precambrian varieties. High K20, A1203, MgO and low TFe203 distinguish the Precambrian glaucony from its Phanerozoic counterpart. Precambrian glaucony, preferably formed within a K-feldspar substrate, is always rich in potassium irre- spective of its degree of evolution, while high K-content in Phanerozoic evolved glaucony in- dicates significant stratigraphic condensation. K20 iJs. TFe203 relationship of glaucony exhibits three different evolutionary trends corresponding to three common modes of origin. Depositional conditions may influence the composition of glaucony as slightly reducing conditions favour Fe enrichment, whereas oxidising conditions cause Fe depletion in giaucony.