Synthesis and antibacterial activity of some novel urea and thiourea derivatives (8a - 8k, 9a - 9f) of anacardic acid prepared from commercially available anacardic acid which is obtained from natural product Cashew N...Synthesis and antibacterial activity of some novel urea and thiourea derivatives (8a - 8k, 9a - 9f) of anacardic acid prepared from commercially available anacardic acid which is obtained from natural product Cashew Nut Shell Liquid (CNSL). Compounds (8a - 8k, 9a - 9f) were tested for Gram positive and Gram negative bacterial cultures. Most of the compounds were showed active compared with standard drug ampicilline.展开更多
Synthesis and antibacterial activity of some novel urea and thiourea derivatives (7a-7k, 8a-8f) of anacardic acid prepared from commercially available anacardic acid which is obtained from natural product Cashew Nut S...Synthesis and antibacterial activity of some novel urea and thiourea derivatives (7a-7k, 8a-8f) of anacardic acid prepared from commercially available anacardic acid which is obtained from natural product Cashew Nut Shell Liquid (CNSL). Compounds (7a-7k, 8a-8f) were tested for Gram positive and Gram negative bac- terial cultures. Most of the compounds were showed active compared with standard drug ampicilline.展开更多
<span style="font-family:Verdana;">A metal matrix composite constitutes a continuous metallic matrix and a </span><span style="font-family:Verdana;">discontinuous phase known as r...<span style="font-family:Verdana;">A metal matrix composite constitutes a continuous metallic matrix and a </span><span style="font-family:Verdana;">discontinuous phase known as reinforcement. The hybrid metal matrix composites</span><span style="font-family:Verdana;"> (Hmmcs) have been used to manufacture drive shafts, disc brake rotors, brake drums, connecting rods pistons, engine block cylinder liners for automotive and rail vehicle applications. The Hmmcs castings of diameter 120 mm and length 300 mm were prepared through sand mould technique following stir casting methodology. The cast components further subjected to evaluation of physical properties and machining tests using two grades of coated inserts and PCD inserts. The experiments were carried out following ISO 3685 standards. The coating thickness of the TiN coated and TiAlN coated inserts were measured using Kalo testing method</span></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">;</span></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> the results of the test show that the interface of the substrate and coating was free from the porosity, and the coating thickness of TiN coating was 4.84 microns and TiAlN coating was measured 4.6 microns. The results of the experiments show that performance of the PCD insert was better than coated inserts at 0.1 mm/rev feed</span></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">;</span></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> however at 0.2 mm/revolution feed PCD insert failed by micro chipping of cutting edge while machining Hmmcs. When TiAlN coated inserts were used to machine Hmmcs the coated inserts failed by gradual wear and BUE formation.展开更多
Hybrid metal matrix composites (Hmmc) are found to be more superior than the conventional composite materials because of their improved mechanical properties, which can be suited for an extensive range of engineering ...Hybrid metal matrix composites (Hmmc) are found to be more superior than the conventional composite materials because of their improved mechanical properties, which can be suited for an extensive range of engineering applications. Automobile and aerospace industries widely make use of hybrid composites as they possess excellent corrosion, wear resistance, low density, and high strength. This paper displays the strategy to build the hybrid composite utilizing Stir casting Method. Present investigation includes the creation of composites utilizing boron carbide (2%, 4%, 6% volume) and Red mud (2% volume) as the reinforcements and Structural aluminium as the matrix. Experimental investigation of wear analysis of the composites was carried out according to the L9 Taguchi method. The designated number of experiments was accomplished to probe the impact of control factors on the specific wear rate (SWR) of the developed composites. ANOVA was carried out and Wt%. Reinforcement was found to be the decisive factor on the SWR of the developed hybrid composite. The Confirmatory test was successfully carried out and the computed error was found to be varying from 0.878% to 2.58%.展开更多
The Metal Matrix Composites application has increased in many areas of science and technology, because of its additional physical, wear and mechanical properties. In comparison with all MMC’s, aluminum-based MMC’s a...The Metal Matrix Composites application has increased in many areas of science and technology, because of its additional physical, wear and mechanical properties. In comparison with all MMC’s, aluminum-based MMC’s are finding wide applications due to their better strength to weight ratio, better stiffness, and high thermal conductivity as well as very good wear and corrosion properties. The properties of a composite mainly depend on better distribution of reinforcement in the matrix, which is very difficult to achieve. Basically Redmud is a byproduct of alumina, and it is waste product obtained during Bayer’s process. This waste product must be recycled else it may be dangerous to the environment. Redmud can be used as reinforcement for aluminium composites in order to achieve better properties. The proposed research work includes preparation of Aluminum 6061-Red mud metal matrix composites using liquid metallurgy route following stir casting technique. An alloy Al6061 containing 0.60 percent silicon and Magnesium of 0.82 percent was used as the matrix material. Two different compositions of the Aluminum 6061-Red mud composites are prepared in addition to the base matrix and evaluated for mechanical properties also the force acting on the cutting tool at different spindle speeds during machining of the composite materials were analyzed.展开更多
The aim is to develop a mechanically flexible polymer nanocomposite film-based strain sensors that could act towards sustainable structural health monitoring for civil structures. The developed polymer nanocomposite f...The aim is to develop a mechanically flexible polymer nanocomposite film-based strain sensors that could act towards sustainable structural health monitoring for civil structures. The developed polymer nanocomposite film combinations will be monitored for their structural, electrical and mechanical behaviors and the optimized formulations will be tried for strain sensing applications. The films were cast by using PVA as the base polymer and copper doped silver nitrate as the nanofiller along with the use of glycine as fuel which is a combination of silver and copper nitrate. After preparing the films, they were tested for conductivity under tensile loading using a digital multi meter connected to a UTM. The samples were subjected to XRD, FTIR and SEM for further analysis. The results of the experiments shown I-V characteristics of PVA-CuAgO composites from 5% to 25% CuAgO have been increased tremendously with the incorporation of filler material. For 100 V, the maximum current value obtained for plain PVA is only 7.7E-8 A, whereas CuAgO particles shown 0.0025 A at 5% reinforcements and further increased nearly to 0.025 A for 25% of CuAgO particles into the PVA matrix.展开更多
文摘Synthesis and antibacterial activity of some novel urea and thiourea derivatives (8a - 8k, 9a - 9f) of anacardic acid prepared from commercially available anacardic acid which is obtained from natural product Cashew Nut Shell Liquid (CNSL). Compounds (8a - 8k, 9a - 9f) were tested for Gram positive and Gram negative bacterial cultures. Most of the compounds were showed active compared with standard drug ampicilline.
文摘Synthesis and antibacterial activity of some novel urea and thiourea derivatives (7a-7k, 8a-8f) of anacardic acid prepared from commercially available anacardic acid which is obtained from natural product Cashew Nut Shell Liquid (CNSL). Compounds (7a-7k, 8a-8f) were tested for Gram positive and Gram negative bac- terial cultures. Most of the compounds were showed active compared with standard drug ampicilline.
文摘<span style="font-family:Verdana;">A metal matrix composite constitutes a continuous metallic matrix and a </span><span style="font-family:Verdana;">discontinuous phase known as reinforcement. The hybrid metal matrix composites</span><span style="font-family:Verdana;"> (Hmmcs) have been used to manufacture drive shafts, disc brake rotors, brake drums, connecting rods pistons, engine block cylinder liners for automotive and rail vehicle applications. The Hmmcs castings of diameter 120 mm and length 300 mm were prepared through sand mould technique following stir casting methodology. The cast components further subjected to evaluation of physical properties and machining tests using two grades of coated inserts and PCD inserts. The experiments were carried out following ISO 3685 standards. The coating thickness of the TiN coated and TiAlN coated inserts were measured using Kalo testing method</span></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">;</span></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> the results of the test show that the interface of the substrate and coating was free from the porosity, and the coating thickness of TiN coating was 4.84 microns and TiAlN coating was measured 4.6 microns. The results of the experiments show that performance of the PCD insert was better than coated inserts at 0.1 mm/rev feed</span></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">;</span></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> however at 0.2 mm/revolution feed PCD insert failed by micro chipping of cutting edge while machining Hmmcs. When TiAlN coated inserts were used to machine Hmmcs the coated inserts failed by gradual wear and BUE formation.
文摘Hybrid metal matrix composites (Hmmc) are found to be more superior than the conventional composite materials because of their improved mechanical properties, which can be suited for an extensive range of engineering applications. Automobile and aerospace industries widely make use of hybrid composites as they possess excellent corrosion, wear resistance, low density, and high strength. This paper displays the strategy to build the hybrid composite utilizing Stir casting Method. Present investigation includes the creation of composites utilizing boron carbide (2%, 4%, 6% volume) and Red mud (2% volume) as the reinforcements and Structural aluminium as the matrix. Experimental investigation of wear analysis of the composites was carried out according to the L9 Taguchi method. The designated number of experiments was accomplished to probe the impact of control factors on the specific wear rate (SWR) of the developed composites. ANOVA was carried out and Wt%. Reinforcement was found to be the decisive factor on the SWR of the developed hybrid composite. The Confirmatory test was successfully carried out and the computed error was found to be varying from 0.878% to 2.58%.
文摘The Metal Matrix Composites application has increased in many areas of science and technology, because of its additional physical, wear and mechanical properties. In comparison with all MMC’s, aluminum-based MMC’s are finding wide applications due to their better strength to weight ratio, better stiffness, and high thermal conductivity as well as very good wear and corrosion properties. The properties of a composite mainly depend on better distribution of reinforcement in the matrix, which is very difficult to achieve. Basically Redmud is a byproduct of alumina, and it is waste product obtained during Bayer’s process. This waste product must be recycled else it may be dangerous to the environment. Redmud can be used as reinforcement for aluminium composites in order to achieve better properties. The proposed research work includes preparation of Aluminum 6061-Red mud metal matrix composites using liquid metallurgy route following stir casting technique. An alloy Al6061 containing 0.60 percent silicon and Magnesium of 0.82 percent was used as the matrix material. Two different compositions of the Aluminum 6061-Red mud composites are prepared in addition to the base matrix and evaluated for mechanical properties also the force acting on the cutting tool at different spindle speeds during machining of the composite materials were analyzed.
文摘The aim is to develop a mechanically flexible polymer nanocomposite film-based strain sensors that could act towards sustainable structural health monitoring for civil structures. The developed polymer nanocomposite film combinations will be monitored for their structural, electrical and mechanical behaviors and the optimized formulations will be tried for strain sensing applications. The films were cast by using PVA as the base polymer and copper doped silver nitrate as the nanofiller along with the use of glycine as fuel which is a combination of silver and copper nitrate. After preparing the films, they were tested for conductivity under tensile loading using a digital multi meter connected to a UTM. The samples were subjected to XRD, FTIR and SEM for further analysis. The results of the experiments shown I-V characteristics of PVA-CuAgO composites from 5% to 25% CuAgO have been increased tremendously with the incorporation of filler material. For 100 V, the maximum current value obtained for plain PVA is only 7.7E-8 A, whereas CuAgO particles shown 0.0025 A at 5% reinforcements and further increased nearly to 0.025 A for 25% of CuAgO particles into the PVA matrix.