Soils from urban and suburban areas are normally enriched with phosphorus (P). Sixteen urban soils with a wide range of total P concentrations under typical urban land uses were sampled and analyzed for extractable P ...Soils from urban and suburban areas are normally enriched with phosphorus (P). Sixteen urban soils with a wide range of total P concentrations under typical urban land uses were sampled and analyzed for extractable P concentrations using water, sodium bicarbonate and citric acid. Meanwhile the soils were artificially leached in columns and P concentrations in the leachates were determined. With linear regression a two-stage linear relationship was found to exist between concentrations of P in the leachates and soil P contents obtained by various chemical measurements, i.e., there was a 'change-point' denoting the critical threshold value for extractable P between the regression lines, above which concentrations of P in leachates increased substantially. These threshold 'change-point' values were 1.5 mg kg-1 for water-soluble P and CaC12-P, 25 mg kg-1 for Olsen-P, and 250-350 mg kg-1 for citric acid-P with the sharpest change and the best predictor [r2 (upper) = 0.928, r2 (lower)= 0.807] appearing for Olsen-P. These 'change-points' were considered important criteria in assessing the risk of P leaching from urban soils and could be used as standards to delineate and target hazardous areas in urban and suburban areas.展开更多
文摘Soils from urban and suburban areas are normally enriched with phosphorus (P). Sixteen urban soils with a wide range of total P concentrations under typical urban land uses were sampled and analyzed for extractable P concentrations using water, sodium bicarbonate and citric acid. Meanwhile the soils were artificially leached in columns and P concentrations in the leachates were determined. With linear regression a two-stage linear relationship was found to exist between concentrations of P in the leachates and soil P contents obtained by various chemical measurements, i.e., there was a 'change-point' denoting the critical threshold value for extractable P between the regression lines, above which concentrations of P in leachates increased substantially. These threshold 'change-point' values were 1.5 mg kg-1 for water-soluble P and CaC12-P, 25 mg kg-1 for Olsen-P, and 250-350 mg kg-1 for citric acid-P with the sharpest change and the best predictor [r2 (upper) = 0.928, r2 (lower)= 0.807] appearing for Olsen-P. These 'change-points' were considered important criteria in assessing the risk of P leaching from urban soils and could be used as standards to delineate and target hazardous areas in urban and suburban areas.