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MnFe0.6Ni0.4Si1-xGax化合物的结构及磁性
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作者 赵丹 杭盖 +2 位作者 欧志强 伊博乐 特古斯 《功能材料》 EI CAS CSCD 北大核心 2020年第10期10105-10109,共5页
真空熔炼和特殊热处理方法制备了MnFe0.6Ni0.4Si1-xGax(x=0,0.05,0.06,0.07,0.08,0.09,0.10,0.15,0.20)系列化合物,并用X射线衍射和磁性测量对样品进行表征。X射线衍射数据分析表明随着Ga含量的增加,化合物从TiNiSi型正交结构(空间群为P... 真空熔炼和特殊热处理方法制备了MnFe0.6Ni0.4Si1-xGax(x=0,0.05,0.06,0.07,0.08,0.09,0.10,0.15,0.20)系列化合物,并用X射线衍射和磁性测量对样品进行表征。X射线衍射数据分析表明随着Ga含量的增加,化合物从TiNiSi型正交结构(空间群为Pnma)变为Ni 2In型六角结构(空间群为P63/mmc),其中当x=0.07时出现了两相共存;磁性测量结果表明随着Ga含量的增加该系列化合物的居里温度降低。除此之外,当x=0.08时,M-T曲线上出现大热滞现象。用等温磁化曲线测量方法对该系列化合物的磁热效应进行表征,随着Ga含量的增加等温磁熵变减小。在磁场变化为0~3 T下,x=0.08的样品磁熵变最大,约为7.1 J/(kgK)。磁性测量和DSC结果表明,当x=0.08时,发生磁-结构耦合相变,x=0.07样品的磁相变和结构相变并不耦合,x=0.10样品的DSC曲线的峰强非常微弱,其符合二级相变的特征。 展开更多
关键词 磁热效应 居里温度 热滞 磁熵变
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Applications of optical control materials based on localized surface plasmon resonance effect in smart windows 被引量:1
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作者 Na Ta Jing-Yi Huang +2 位作者 Shuai He w.hanggai Luo-Meng Chao 《Tungsten》 EI CSCD 2024年第4期711-731,共21页
The increasing energy consumption in buildings due to cooling and heating,accounting for over one-third of the total energy consumption in society,has become a growing concern.Therefore,reducing building energy consum... The increasing energy consumption in buildings due to cooling and heating,accounting for over one-third of the total energy consumption in society,has become a growing concern.Therefore,reducing building energy consumption has become an urgent issue for countries worldwide.Windows serve as the primary channel for energy exchange between the indoor and the outdoor environments.While providing natural lighting for occupants,windows are also the weakest link in terms of energy consumption.In recent years,there have been some new and superior coating glass technologies compared to traditional low-emissivity glass.These coatings utilize various optical functional materials to regulate the incident sunlight,aiming to save cooling and heating energy consumption.Materials,such as tungsten-based compounds,vanadium dioxide,lanthanum hexaboride,or copper monosulfide,can absorb near-infrared light to effectively control solar radiation by leveraging the localized surface plasmon resonance(LSPR)effect of nanoparticles.This paper mainly introduces the micro-mechanisms of these materials and provides a detailed summary of the latest advancements in coating materials.The application and effects of these coatings in building energy conservation are emphasized.Finally,the challenges and prospects of LSPRbased smart windows are discussed.It is expected that this review will provide new insights into the application of smart windows in green buildings. 展开更多
关键词 TUNGSTEN Localized surface plasmon resonance(LSPR) Tungsten-based compounds Vanadium dioxide Lanthanum hexaboride Copper monosulfide
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