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氨基烤漆用丙烯酸树脂二级分散体的合成研究
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作者 刘豪 闫福安 +2 位作者 周勇 万书青 李晓东 《中国涂料》 CAS 2023年第4期30-34,共5页
以甲基丙烯酸甲酯、苯乙烯、甲基丙烯酸丁酯、丙烯酸异辛酯、甲基丙烯酸为共聚单体,甲基丙烯酸羟乙酯为功能单体,过氧化苯甲酸叔丁酯为引发剂,通过溶液聚合经相反转制备出水性丙烯酸树脂二级分散体,再与氨基树脂配备制成氨基烤漆。考察... 以甲基丙烯酸甲酯、苯乙烯、甲基丙烯酸丁酯、丙烯酸异辛酯、甲基丙烯酸为共聚单体,甲基丙烯酸羟乙酯为功能单体,过氧化苯甲酸叔丁酯为引发剂,通过溶液聚合经相反转制备出水性丙烯酸树脂二级分散体,再与氨基树脂配备制成氨基烤漆。考察了溶剂、引发剂、甲基丙烯酸羟乙酯、甲基丙烯酸等因素对分散体性能的影响。当引发剂用量为单体总量的2%(质量分数,后同)、甲基丙烯酸用量为3%、羟值为4%时能够得到综合性能最优异的丙烯酸二级分散体。 展开更多
关键词 二级分散体 合成 氨基烤漆
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环氧酯改性水性聚氨酯的合成及性能研究
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作者 黎柳冰 闫福安 +2 位作者 周勇 万书青 李晓东 《中国涂料》 CAS 2023年第3期18-24,共7页
以1,6–己二醇二缩水甘油醚(XY-632)和脂肪酸为原料合成环氧酯,再以此原料作为改性单体,制备得到环氧酯改性水性聚氨酯。利用傅里叶变换红外光谱(FT-IR)、透射电镜(TEM)、热重分析(TGA)和激光粒度分析仪对产品及涂膜进行测试及表征;研... 以1,6–己二醇二缩水甘油醚(XY-632)和脂肪酸为原料合成环氧酯,再以此原料作为改性单体,制备得到环氧酯改性水性聚氨酯。利用傅里叶变换红外光谱(FT-IR)、透射电镜(TEM)、热重分析(TGA)和激光粒度分析仪对产品及涂膜进行测试及表征;研究了二羟甲基丙酸(DMPA)、环氧酯、1,4–环己烷二甲醇(CHDM)的用量及中和度对产品的状态和性能的影响。同时,考察了自乳化过程、DMPA的用量和中和度对电导率的影响。结果表明:通过在聚氨酯分子中引入环氧酯结构,所制得的乳液稳定性好,且涂膜具有优异的耐水性、附着力、硬度等性能。 展开更多
关键词 环氧酯 改性 水性聚氨酯
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Preparation, Characterization and Nematicidal Activity of Lansiumamide B Nano-Capsules 被引量:3
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作者 YIN Yan-hua GUO Qing-ming +2 位作者 HAN Yun wanG Ling-jing wan shu-qing 《Journal of Integrative Agriculture》 SCIE CSCD 2012年第7期1151-1158,共8页
In this study, nano-capsules of lansiumamide B (NCLB) was prepared by the microemulsion polymerization method to improve the nematicidal efficacy of lansiumamide B (LB). An optimal formulation was gained by orthog... In this study, nano-capsules of lansiumamide B (NCLB) was prepared by the microemulsion polymerization method to improve the nematicidal efficacy of lansiumamide B (LB). An optimal formulation was gained by orthogonal experiment design based on the encapsulation efficiency (E, %) value. The optimized NCLB were spherical and uniform under transmission electron microscopy (TEM). The mean particle size, zeta potential and E, were (38.50~0.64) nm, (-70.5~0.76) mV and (95.13± 1.16)%, respectively. The release profile indicated that the accumulated release of LB in NCLB reached up to 82% within 96 h. Effects of NCLB against Bursaphelenehus xylophilus and J2 ofMeloidogyne incognita were reported in this paper. The nematicidal activity of NCLB has been remarkably increased, with LCs0 values of 2.1407 mg L-1 and 19.3608 mg L-1, respectively, at 24 h after treatment. The disease progression and the average number of root knots of Ipomoea aquatica were 1.50 and 7.25, respectively, in the treatment of NCLB, at concentration of 200 mg L-1 significantly lower than the treatment of LB and ethoprophos. Compared to control, the treatments of NCLB, LB and ethoprophos leaded the disease progression to drop 68.42, 36.84 and 26.32%, respectively, and caused the average number of root knots to fall 83.94, 78.03 and 63.66%. These results suggested that NCLB, as a novel nematicides formulation, performed more efficient and longer effective maintenance against plant parasitic nematodes. 展开更多
关键词 lansiumamide B nano-capsules structure characterization nematicidal activity
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Repellent Activity of Extracts of Wild Rice Species against Panonychus citri and Aphis citricola in Associated with Esterase Isoenzyme in Insests 被引量:2
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作者 wan shu-qing LIU Xiang-fa +1 位作者 FENG Guo-zhong PAN Da-jian 《Rice science》 SCIE 2006年第2期146-148,共3页
Six species of wild rice with different ecophenotypes including Oryza grandiglumis (E6-1, E6-3 / 6-4), O. minuta (E13-9, E13-13), O. officinalis(E15-8, E15-13), O. punctata (E16-1, E16-3, E16-13), O. granulata... Six species of wild rice with different ecophenotypes including Oryza grandiglumis (E6-1, E6-3 / 6-4), O. minuta (E13-9, E13-13), O. officinalis(E15-8, E15-13), O. punctata (E16-1, E16-3, E16-13), O. granulata(E7-4), and O. latifolia(101392, E9-1, E9-10) were extracted with methnol and the repellent activity of the extracts against the two insects Aphis citricola and Panonychus citri were studied. The extracts of O. officinalis E15-8 showed higher repellent rate to the two insects than those of the other species. The repellent rates of the extracts of E15-8 to P. citriand A. citricola were 83.26% and 87.86% at 5×10^4 μg/mL in 24 h and 87.95% and 82.43% in 48 h, respectively. The extracts of O. officinalis E15-8 had the effect of inhibition to the esterase of the two insects. 展开更多
关键词 wild rice Panonychus citrr Aphis citricola repellent activity esterase isoenzyme EXTRACTS biological control
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现代涂料生产工艺的探讨 被引量:1
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作者 万书青 孟祥刚 《中国涂料》 CAS 2018年第8期63-66,共4页
分析了当前涂料常用工艺并提出了现代涂料生产工艺,分析了面漆仓库配色的技术可行性与法律的局限性。
关键词 涂料生产工艺 分散 砂磨 仓库配色
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