The title Schiff base compound C13H19N3O3 synthesized by the condensation of equimolar 5-nitrosalicylaldehyde and N,N-diethylethane-1,2-diamine consists of two independent molecules. The compound was characterized by ...The title Schiff base compound C13H19N3O3 synthesized by the condensation of equimolar 5-nitrosalicylaldehyde and N,N-diethylethane-1,2-diamine consists of two independent molecules. The compound was characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The crystal belongs to the orthorhombic system, space group Pbca with a = 13.151 （3）, b = 20.609（4）, c = 20.991 （4） °A, Z = 16, V = 5689（2） °A^3, Dc = 1.239 g/cm^3, Mr = 265.31, λ（MoKa） = 0.71073 °A, μ= 0.089 mm^-1, F（000） = 2272, R = 0.0732 and wR = 0.1454. A total of 5264 unique reflections were collected, of which 2023 with I 〉 2σ（I） were observed. As expected, the molecule adopts trans configuration about the C=N double bond. The molecules in the crystal are linked through intermolecular hydrogen bonds and π-π interactions, forming a 3-D network.展开更多
基金The project was supported by the Natural Science Foundation of Anhui Provincial Universities (No. 2005KJ019ZD)
文摘The title Schiff base compound C13H19N3O3 synthesized by the condensation of equimolar 5-nitrosalicylaldehyde and N,N-diethylethane-1,2-diamine consists of two independent molecules. The compound was characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The crystal belongs to the orthorhombic system, space group Pbca with a = 13.151 （3）, b = 20.609（4）, c = 20.991 （4） °A, Z = 16, V = 5689（2） °A^3, Dc = 1.239 g/cm^3, Mr = 265.31, λ（MoKa） = 0.71073 °A, μ= 0.089 mm^-1, F（000） = 2272, R = 0.0732 and wR = 0.1454. A total of 5264 unique reflections were collected, of which 2023 with I 〉 2σ（I） were observed. As expected, the molecule adopts trans configuration about the C=N double bond. The molecules in the crystal are linked through intermolecular hydrogen bonds and π-π interactions, forming a 3-D network.
