The title compound, trans 4 [p (N ethyl N (hydroxyethyl)amino) styryl] N methylpyridinium tetraphenylborate(abbreviated as ESMT, C 46 H 49 N 4OB) crystallizes in a space group P 1 with ...The title compound, trans 4 [p (N ethyl N (hydroxyethyl)amino) styryl] N methylpyridinium tetraphenylborate(abbreviated as ESMT, C 46 H 49 N 4OB) crystallizes in a space group P 1 with a =0 983 23(15) nm, b =1 410 73(16) nm, c =1 54 21(12) nm, α=95 252(13)°, β= 91 959(17)°, γ= 107 421(12)°, Z=2, F(000)=712, μ =0 1 mm -1 Mo Kα radiation, R =0 093 8. The result shows that the cation of the molecule almost lies in one plane, the hydroxyethyl group is perpendicular to the plane, the anion takes a slight distorted tetrahedral geometry. Also the thermal stability, two photon fluorescence, two photon pumped lasing property for the title compound were studied.展开更多
Nonlinear optical properties of an organo-metallic compound[(C_(4)H_(9))_(4)N][Ni(dmit)_(2)](dmit=2−thioxo-1,3-dithiole-4,5-dithiolate),abbreviated as BuNi,dissolved in acetone,are investigated using the Z-scan techni...Nonlinear optical properties of an organo-metallic compound[(C_(4)H_(9))_(4)N][Ni(dmit)_(2)](dmit=2−thioxo-1,3-dithiole-4,5-dithiolate),abbreviated as BuNi,dissolved in acetone,are investigated using the Z-scan technique with a 40 ps pulse width at 1064 nm and a 1 ns and 15 ns pulse width at 1053 nm.Strong saturable absorption is found when the sample solution is irradiated by 40 ps and 1 ns laser pulses.When irradiated with a 15 ns laser pulse,a stronger reverse saturable absorption is found.The nonlinear optical absorption coefficients are-1.06×10^(-11),−2.02×10^(-11) and 2.73×10^(−10) m/W,respectively.All the results suggest that BuNi may be a promising candidate in the application of laser pulse compression in the near-infrared waveband.展开更多
The transient photoluminescence(PL)of DO-PPV(poly-(2,5-dioctyloxy-1,4-phenylene vinylene))solution in chloroform was investigated by picosecond time-resolved PL spectroscopy.An ultrafast rise of PL and the following s...The transient photoluminescence(PL)of DO-PPV(poly-(2,5-dioctyloxy-1,4-phenylene vinylene))solution in chloroform was investigated by picosecond time-resolved PL spectroscopy.An ultrafast rise of PL and the following single exponential decay with a time constant about 400ps were assigned to the formation of intrachain exciton and its decay process,respectively.The redshift of the PL emission spectrum with time was caused by the subsequent exciton migration among the different conjugated segments in the DO-PPV polymer.展开更多
The fluorescent decays and spectra of pump power density dependent emission demonstrated that the excitation power density was enhanced in Rh640 dye solution containing scattering nanoparticles.Lasing in disordered sc...The fluorescent decays and spectra of pump power density dependent emission demonstrated that the excitation power density was enhanced in Rh640 dye solution containing scattering nanoparticles.Lasing in disordered scattering medium with low threshold,narrow bandwidth,and short duration was observed.The mechanism of this enhancement,together with the lasing properties of low threshold and narrow bandwidth,was discussed.展开更多
文摘The title compound, trans 4 [p (N ethyl N (hydroxyethyl)amino) styryl] N methylpyridinium tetraphenylborate(abbreviated as ESMT, C 46 H 49 N 4OB) crystallizes in a space group P 1 with a =0 983 23(15) nm, b =1 410 73(16) nm, c =1 54 21(12) nm, α=95 252(13)°, β= 91 959(17)°, γ= 107 421(12)°, Z=2, F(000)=712, μ =0 1 mm -1 Mo Kα radiation, R =0 093 8. The result shows that the cation of the molecule almost lies in one plane, the hydroxyethyl group is perpendicular to the plane, the anion takes a slight distorted tetrahedral geometry. Also the thermal stability, two photon fluorescence, two photon pumped lasing property for the title compound were studied.
基金Supported by the National Natural Science Foundation of China under Grant Nos.60778037,50772059 and 60608010the Foundation for the Author of National Excellent Doctoral Dissertation of China(No.200539)the Youth Scientist Fund of Shandong Province(BS2011CL025).
文摘Nonlinear optical properties of an organo-metallic compound[(C_(4)H_(9))_(4)N][Ni(dmit)_(2)](dmit=2−thioxo-1,3-dithiole-4,5-dithiolate),abbreviated as BuNi,dissolved in acetone,are investigated using the Z-scan technique with a 40 ps pulse width at 1064 nm and a 1 ns and 15 ns pulse width at 1053 nm.Strong saturable absorption is found when the sample solution is irradiated by 40 ps and 1 ns laser pulses.When irradiated with a 15 ns laser pulse,a stronger reverse saturable absorption is found.The nonlinear optical absorption coefficients are-1.06×10^(-11),−2.02×10^(-11) and 2.73×10^(−10) m/W,respectively.All the results suggest that BuNi may be a promising candidate in the application of laser pulse compression in the near-infrared waveband.
基金Supported by the National Natural Science Foundation of China under Grant No.69977008.
文摘The transient photoluminescence(PL)of DO-PPV(poly-(2,5-dioctyloxy-1,4-phenylene vinylene))solution in chloroform was investigated by picosecond time-resolved PL spectroscopy.An ultrafast rise of PL and the following single exponential decay with a time constant about 400ps were assigned to the formation of intrachain exciton and its decay process,respectively.The redshift of the PL emission spectrum with time was caused by the subsequent exciton migration among the different conjugated segments in the DO-PPV polymer.
基金Supported by the National Natural Science Foundation of China under Grant No.19574077the National Reseach Project of 863-416 High Technology,and the Guangdong Natural Science Foundation.
文摘The fluorescent decays and spectra of pump power density dependent emission demonstrated that the excitation power density was enhanced in Rh640 dye solution containing scattering nanoparticles.Lasing in disordered scattering medium with low threshold,narrow bandwidth,and short duration was observed.The mechanism of this enhancement,together with the lasing properties of low threshold and narrow bandwidth,was discussed.
