The oxidation state of sulfur is detected in Na20-CaO-SiO2 float glass by synchrotron radiation X-ray absorption near edge structure （XANES） spectra at the sulfur K edge. The measured spectra show the only presence ...The oxidation state of sulfur is detected in Na20-CaO-SiO2 float glass by synchrotron radiation X-ray absorption near edge structure （XANES） spectra at the sulfur K edge. The measured spectra show the only presence of S^6＋ in the Na20-CaO-SiO2 float glass and the oxidation state of sulfur do not change with the increase of glass depth. It is also found that, after the melt has gone through the molten tin bath, the S^6＋ is the dominant species, but S^2- is also present on both surfaces. It is not certain whether cation bonds to S^2- or not, because there are many cations dissolved in the melted tin which makes the spectrum complicated.展开更多
氢能是一种新型清洁无污染的二次能源,是我国能源结构调整中不可缺少的组成部分。在氢能的应用中,液氢具有较高的体积与质量存储密度,适合大规模运输及应用,能够显著降低市场化应用的成本。着重分析了氢液化技术的研究进展以及国际上的...氢能是一种新型清洁无污染的二次能源,是我国能源结构调整中不可缺少的组成部分。在氢能的应用中,液氢具有较高的体积与质量存储密度,适合大规模运输及应用,能够显著降低市场化应用的成本。着重分析了氢液化技术的研究进展以及国际上的液氢研究项目:日本WE-NET (World Energy Network)及欧洲IDEALHY (Integrated Design for Efficient Advanced Liquefaction of Hydrogen)。从压缩能耗、液化能耗、运输能耗、总能耗四个方面进行高压氢与液氢的能耗对比,分析结果表明,对于液氢的运输能耗随里程增加缓慢,高压气氢的运输能耗随里程增加成直线上升;运输里程在约500 km时,液氢的总能耗将低于高压气氢,液化能耗在总能耗中占的比例减少。总结了目前氢液化过程相关技术的研究热点跟难点,并对未来液氢的大规模应用进行展望。展开更多
基金Funded by the National Natural Science Foundation of China(No.50972136)
文摘The oxidation state of sulfur is detected in Na20-CaO-SiO2 float glass by synchrotron radiation X-ray absorption near edge structure （XANES） spectra at the sulfur K edge. The measured spectra show the only presence of S^6＋ in the Na20-CaO-SiO2 float glass and the oxidation state of sulfur do not change with the increase of glass depth. It is also found that, after the melt has gone through the molten tin bath, the S^6＋ is the dominant species, but S^2- is also present on both surfaces. It is not certain whether cation bonds to S^2- or not, because there are many cations dissolved in the melted tin which makes the spectrum complicated.
文摘氢能是一种新型清洁无污染的二次能源,是我国能源结构调整中不可缺少的组成部分。在氢能的应用中,液氢具有较高的体积与质量存储密度,适合大规模运输及应用,能够显著降低市场化应用的成本。着重分析了氢液化技术的研究进展以及国际上的液氢研究项目:日本WE-NET (World Energy Network)及欧洲IDEALHY (Integrated Design for Efficient Advanced Liquefaction of Hydrogen)。从压缩能耗、液化能耗、运输能耗、总能耗四个方面进行高压氢与液氢的能耗对比,分析结果表明,对于液氢的运输能耗随里程增加缓慢,高压气氢的运输能耗随里程增加成直线上升;运输里程在约500 km时,液氢的总能耗将低于高压气氢,液化能耗在总能耗中占的比例减少。总结了目前氢液化过程相关技术的研究热点跟难点,并对未来液氢的大规模应用进行展望。
