Organic optocoupler(OOC) or organic photocoupler,optical coupler is a novel and one of the most promising organic optoelectronic devices for its well electrical isolation and anti-jamming ability in long-distance and ...Organic optocoupler(OOC) or organic photocoupler,optical coupler is a novel and one of the most promising organic optoelectronic devices for its well electrical isolation and anti-jamming ability in long-distance and real-time digital communications.The performance parameters of OOC were greatly raised during the past decade,and its development was strongly associated with basic organic devices such as organic light emitting diodes(OLED),organic photodiodes(OPD) and organic phototransistors(OPT) etc.Here we describe the principles of OOC,review recent breakthroughs in this field,and summarize the photosensor and light emitting parts which could be used in the device.Key technical points,such as current transfer ratio,frequency,matching and stability were also discussed in this paper.展开更多
The hole and electron mobilities of the amorphous films of the organic semiconductor 4,4′-N,N′-dicarbazole-biphenyl (CBP) at different electric fields were measured through the time of flight (TOF) method. Based on ...The hole and electron mobilities of the amorphous films of the organic semiconductor 4,4′-N,N′-dicarbazole-biphenyl (CBP) at different electric fields were measured through the time of flight (TOF) method. Based on its crystalline structure, the hole and electron mobilities of CBP were calculated. A detailed comparison between experimental and theoretical results is necessary for further understanding its charge transport properties. In order to do this, charge mobilities at zero electric field, μ(0), were deduced from experimental data as a link between experimental and theoretical data. It was found that the electron transport of CBP is less affected by traps compared with its hole transport. This unusual phenomenon can be understood through the distributions of frontier molecular orbitals. We showed that designing materials with frontier molecular orbitals localized at the center of the molecule has the potency to reduce the influence of traps on charge transport and provide new insights into designing high mobility charge transport materials.展开更多
Short range order model is commonly used to explain the charge transport property of disordered organic semiconductors.However,its validity is not yet studied.In this paper,the hole and electron mobilities of a bipola...Short range order model is commonly used to explain the charge transport property of disordered organic semiconductors.However,its validity is not yet studied.In this paper,the hole and electron mobilities of a bipolar material,N,N'-dicarbazolyl-1,4dimethene-benzene(DCB),were measured through time of flight method.The hole and electron mobilities of DCB based on the crystalline structure were calculated.In order to investigate the short range order model,the ratios of charge mobilities at zero electric field of holes to electrons were calculated.The results showed that this model cannot fully explain our case.The reason was discussed in detail,and a correction method was proposed.We showed that using the short range order model without preconditions to explain the charge transport property of amorphous materials may lead to deviations,which is often neglected in the past.展开更多
A series of tetracene-doped anthracene crystals with different doping concentrations(the highest mo-lar ratio 100:1) are grown from solution.Crystal structures and optical characteristics of the above mixed crystals a...A series of tetracene-doped anthracene crystals with different doping concentrations(the highest mo-lar ratio 100:1) are grown from solution.Crystal structures and optical characteristics of the above mixed crystals are investigated at room temperature.By changing the doping concentrations,the fluorescence can be adjusted from blue-green to green and even to yellow-green.The emission spectra of anthracene/tetracene(An/Te) mixed crystals reveal the sensitized fluorescence of tetracene and the partial quenching of anthracene emission.The data of transient photoluminescence(PL) decays illus-trate that in An/Te mixed crystals,the decay of anthracene becomes faster,while the PL lifetime of tet-racene is longer than that of the tetracene single crystals.All above experimental results suggest that there is excitation energy transfer from anthracene to tetracene in the mixed crystals.展开更多
基金supported by the National Natural Science Foundation of China (60877026 and 50990062)the National Basic Research Program of China (973Program,2009CB930602 and 2009CB623604)
文摘Organic optocoupler(OOC) or organic photocoupler,optical coupler is a novel and one of the most promising organic optoelectronic devices for its well electrical isolation and anti-jamming ability in long-distance and real-time digital communications.The performance parameters of OOC were greatly raised during the past decade,and its development was strongly associated with basic organic devices such as organic light emitting diodes(OLED),organic photodiodes(OPD) and organic phototransistors(OPT) etc.Here we describe the principles of OOC,review recent breakthroughs in this field,and summarize the photosensor and light emitting parts which could be used in the device.Key technical points,such as current transfer ratio,frequency,matching and stability were also discussed in this paper.
基金supported by the National Key Basic Research and Development Program of China (2009CB623604)the National Natural Science Foundation of China (50990060, 51073809 and 21161160447)
文摘The hole and electron mobilities of the amorphous films of the organic semiconductor 4,4′-N,N′-dicarbazole-biphenyl (CBP) at different electric fields were measured through the time of flight (TOF) method. Based on its crystalline structure, the hole and electron mobilities of CBP were calculated. A detailed comparison between experimental and theoretical results is necessary for further understanding its charge transport properties. In order to do this, charge mobilities at zero electric field, μ(0), were deduced from experimental data as a link between experimental and theoretical data. It was found that the electron transport of CBP is less affected by traps compared with its hole transport. This unusual phenomenon can be understood through the distributions of frontier molecular orbitals. We showed that designing materials with frontier molecular orbitals localized at the center of the molecule has the potency to reduce the influence of traps on charge transport and provide new insights into designing high mobility charge transport materials.
基金supported by the National Basic Research and Development Program of China (2009CB623604)the National Natural Science Foundation of China (50990060,51073809 and 61177023)
文摘Short range order model is commonly used to explain the charge transport property of disordered organic semiconductors.However,its validity is not yet studied.In this paper,the hole and electron mobilities of a bipolar material,N,N'-dicarbazolyl-1,4dimethene-benzene(DCB),were measured through time of flight method.The hole and electron mobilities of DCB based on the crystalline structure were calculated.In order to investigate the short range order model,the ratios of charge mobilities at zero electric field of holes to electrons were calculated.The results showed that this model cannot fully explain our case.The reason was discussed in detail,and a correction method was proposed.We showed that using the short range order model without preconditions to explain the charge transport property of amorphous materials may lead to deviations,which is often neglected in the past.
基金Supported by the National Natural Science Foundation of China (Grant No. 5057 3039)the National Key Basic Research and Development Program of China (Grant No. 2006CB806200)
文摘A series of tetracene-doped anthracene crystals with different doping concentrations(the highest mo-lar ratio 100:1) are grown from solution.Crystal structures and optical characteristics of the above mixed crystals are investigated at room temperature.By changing the doping concentrations,the fluorescence can be adjusted from blue-green to green and even to yellow-green.The emission spectra of anthracene/tetracene(An/Te) mixed crystals reveal the sensitized fluorescence of tetracene and the partial quenching of anthracene emission.The data of transient photoluminescence(PL) decays illus-trate that in An/Te mixed crystals,the decay of anthracene becomes faster,while the PL lifetime of tet-racene is longer than that of the tetracene single crystals.All above experimental results suggest that there is excitation energy transfer from anthracene to tetracene in the mixed crystals.
