The concentrations of semivolatile organic compounds, organochlorine pesticides and heavy metals in sediments from Jiangsu reach of Huaihe River, China, were presented. The organic compounds were extracted by acetone...The concentrations of semivolatile organic compounds, organochlorine pesticides and heavy metals in sediments from Jiangsu reach of Huaihe River, China, were presented. The organic compounds were extracted by acetone: n-hexane using a Soxhlet apparatus and concentrations were performed using HP6890 gas chromatography coupled by FID and ECD detector. The total contents of 8 heavy metals by inductively coupled plasma atomic emission spectrometry or cold-vapor/atomic absorption spectrometry were developed. 30 semivolatile organic compounds were detected, including substituted benzenes, phenols, phthalates and polycyclic aromatic hydrocarbons, from 0.01 to 3.01 mg/kg. 16 organochlorine pesticides were almost detected and from 0.010 to 2.339 μg/kg. Concentrations of major metals were 50 mg/kg or less, mean level of mercury was only 0.055 mg/kg. Compared to sediment quality guidelines (SQGs), concentrations of some semivolatilc organic compounds were high enough to cause possible toxic effects to living resources. The organochlorine pesticides presented relatively low, lower than threshold effect concentrations (TECs), harmful effects on sediment-dwelling organisms were not expected. Chromium posed probable toxic effects to the living resources, other heavy metals had no threat temporarily according to SQGs.展开更多
Based on the widely used DRASTIC method, a fuzzy pattern recognition and optimization method was proposed and applied to the fissured-karstic aquifer of Zhangji area for assessing groundwater vulnerability to pollutio...Based on the widely used DRASTIC method, a fuzzy pattern recognition and optimization method was proposed and applied to the fissured-karstic aquifer of Zhangji area for assessing groundwater vulnerability to pollution. The result is compared with DRASTIC method. It is shown that by taking the fuzziness into consideration, the fuzzy pattern recognition and optimization method reflects more efficiently the fuzzy nature of the groundwater vulnerability to pollution and is more applicable in reality.展开更多
文摘The concentrations of semivolatile organic compounds, organochlorine pesticides and heavy metals in sediments from Jiangsu reach of Huaihe River, China, were presented. The organic compounds were extracted by acetone: n-hexane using a Soxhlet apparatus and concentrations were performed using HP6890 gas chromatography coupled by FID and ECD detector. The total contents of 8 heavy metals by inductively coupled plasma atomic emission spectrometry or cold-vapor/atomic absorption spectrometry were developed. 30 semivolatile organic compounds were detected, including substituted benzenes, phenols, phthalates and polycyclic aromatic hydrocarbons, from 0.01 to 3.01 mg/kg. 16 organochlorine pesticides were almost detected and from 0.010 to 2.339 μg/kg. Concentrations of major metals were 50 mg/kg or less, mean level of mercury was only 0.055 mg/kg. Compared to sediment quality guidelines (SQGs), concentrations of some semivolatilc organic compounds were high enough to cause possible toxic effects to living resources. The organochlorine pesticides presented relatively low, lower than threshold effect concentrations (TECs), harmful effects on sediment-dwelling organisms were not expected. Chromium posed probable toxic effects to the living resources, other heavy metals had no threat temporarily according to SQGs.
基金Project (No. ICA4-CT-2001-10039) supported by Manporivers(Management policies for priority water pollutants and their effects onfoods and human health: general methodology and application toChinese river basins)
文摘Based on the widely used DRASTIC method, a fuzzy pattern recognition and optimization method was proposed and applied to the fissured-karstic aquifer of Zhangji area for assessing groundwater vulnerability to pollution. The result is compared with DRASTIC method. It is shown that by taking the fuzziness into consideration, the fuzzy pattern recognition and optimization method reflects more efficiently the fuzzy nature of the groundwater vulnerability to pollution and is more applicable in reality.