A new POM-based coordination polymer,[Cl_(2)Cu^(Ⅰ)_(11)(trz)_(8)][H_(3)SiW_(12)O_(40)](1),was successfully obtained under hydrothermal reaction.The compound was characterized by single-crystal X-ray diffraction,TGana...A new POM-based coordination polymer,[Cl_(2)Cu^(Ⅰ)_(11)(trz)_(8)][H_(3)SiW_(12)O_(40)](1),was successfully obtained under hydrothermal reaction.The compound was characterized by single-crystal X-ray diffraction,TGanalyses,IR spectra and PXRD analysis.Compound 1 shows extreme stability and outstanding catalytic activity to the degradation of organic dye pollutant.展开更多
Two polyoxometalate-based host-guest compounds,(HL1)2(HPW12O40)〜11H2O(1),(HL2)3(PWi2O40)·3H2O(2)(L_(1)=guanine,L_(2)=2-(1H-1,2,4-triazol-3-yl)pyridine),were synthesized under hydrothermal conditions and character...Two polyoxometalate-based host-guest compounds,(HL1)2(HPW12O40)〜11H2O(1),(HL2)3(PWi2O40)·3H2O(2)(L_(1)=guanine,L_(2)=2-(1H-1,2,4-triazol-3-yl)pyridine),were synthesized under hydrothermal conditions and characterized by EA,PXRD,TG,FT-IR and X-ray single-crystal diffraction.Compound 1 crystallizes in trigonal space group P-3 with a=18.2917(5),b=18.2917(5),c=13.5441(5)A,V=3924.5(3)A^(3),Z=3,Mr=3383.26 g/mol,pcak=4.036 g/cm^(3),F(000)=4137,=48.532 mm^(-1),GOOF=1.062,the final R=0.0713 and wR=0.1865 for 9037 observed reflections with I>2σ(I).Compound 2 crystallizes in trigonal space group R-3 with a=19.0017(6),b=19.0017(6),c=25.6361(9)A,V=8016.2(6)A^(3),Z=6,Mr=3372.45 g/mol,p_(calc)=4.188 g/cm,F(000)=8886,μ=47.644 mm^(-1),GOOF=1.077,the final R=0.0380 and wR=0.0976 for 5904 observed reflections with I>2σ(I).These two compounds can catalyze selective oxidation of aniline with H2O2 as the oxidant.Under optimal conditions,the conversion of aniline with compound 1 can reach up to 91.25%,and the selectivity of nitrosobenzene is 78.81%.展开更多
基金Supported by the Key Research Program of Frontier Science,CAS(QYZDJ-SSW-SLH033)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20000000)the National Natural Science Foundation of China(21521061,21773247,21875252,52073286)。
文摘A new POM-based coordination polymer,[Cl_(2)Cu^(Ⅰ)_(11)(trz)_(8)][H_(3)SiW_(12)O_(40)](1),was successfully obtained under hydrothermal reaction.The compound was characterized by single-crystal X-ray diffraction,TGanalyses,IR spectra and PXRD analysis.Compound 1 shows extreme stability and outstanding catalytic activity to the degradation of organic dye pollutant.
基金This work was supported by the Key Research Program of Frontier Science,CAS(QYZDJ-SSW-SLH033)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20000000)the National Natural Science Foundation of China(21773247,21521061,21875252,52073286)。
文摘Two polyoxometalate-based host-guest compounds,(HL1)2(HPW12O40)〜11H2O(1),(HL2)3(PWi2O40)·3H2O(2)(L_(1)=guanine,L_(2)=2-(1H-1,2,4-triazol-3-yl)pyridine),were synthesized under hydrothermal conditions and characterized by EA,PXRD,TG,FT-IR and X-ray single-crystal diffraction.Compound 1 crystallizes in trigonal space group P-3 with a=18.2917(5),b=18.2917(5),c=13.5441(5)A,V=3924.5(3)A^(3),Z=3,Mr=3383.26 g/mol,pcak=4.036 g/cm^(3),F(000)=4137,=48.532 mm^(-1),GOOF=1.062,the final R=0.0713 and wR=0.1865 for 9037 observed reflections with I>2σ(I).Compound 2 crystallizes in trigonal space group R-3 with a=19.0017(6),b=19.0017(6),c=25.6361(9)A,V=8016.2(6)A^(3),Z=6,Mr=3372.45 g/mol,p_(calc)=4.188 g/cm,F(000)=8886,μ=47.644 mm^(-1),GOOF=1.077,the final R=0.0380 and wR=0.0976 for 5904 observed reflections with I>2σ(I).These two compounds can catalyze selective oxidation of aniline with H2O2 as the oxidant.Under optimal conditions,the conversion of aniline with compound 1 can reach up to 91.25%,and the selectivity of nitrosobenzene is 78.81%.
