【目的】研究木材胶合界面的静态和动态力学行为,探讨树脂渗透对木材管胞壁层力学性能的影响,为木质复合材料制造工艺优化和增强改性提供理论依据。【方法】采用纳米压痕静态和动态力学测试技术(Nano-DMA),对针叶材火炬松与酚醛树脂(PF...【目的】研究木材胶合界面的静态和动态力学行为,探讨树脂渗透对木材管胞壁层力学性能的影响,为木质复合材料制造工艺优化和增强改性提供理论依据。【方法】采用纳米压痕静态和动态力学测试技术(Nano-DMA),对针叶材火炬松与酚醛树脂(PF)、脲醛树脂(UF)胶黏剂所形成胶合界面区域各相材料的静态弹性模量、硬度、蠕变性能以及储能模量和损耗模量等力学行为进行分析。【结果】静态力学行为方面,在界面区域,PF和UF渗透进入管胞壁层后,木材管胞壁的弹性模量( E r)和硬度( H )提高;经PF渗透后,木材管胞壁的 E r和 H 分别增加7%和26%;Burgers蠕变力学模型可有效描述胶合界面区域管胞壁的纳米压痕蠕变特性,经树脂渗透后,木材管胞壁的瞬时弹性模量增加,黏弹性模量和黏性系数减小;在保载初期,PF界面区域木材管胞壁的蠕变柔量约下降60%,UF界面区域木材管胞壁的蠕变柔量约下降58%。动态力学行为方面,随着加载频率增加,界面材料的储能模量( E ′ r)逐渐增大,而损耗模量( E ″ r)和损耗因子(tan δ)呈减小趋势;当加载频率为10 Hz时,PF和UF树脂渗透使得管胞壁层的储能模量分别增加16%和29%。【结论】胶合界面区域胶黏剂进入管胞壁层,对木材管胞的静态力学性能具有增强作用,同时胶黏剂可提高管胞壁的短期抗蠕变能力;木材管胞壁具有较高的储能模量和损耗模量,而树脂的储能模量和损耗模量较低,经树脂渗透后,木材管胞壁的储能模量增加,但损耗模量和损耗因子呈下降趋势,可能对界面传递和分散应力产生不利影响。展开更多
The objective of this study was to investigate the surface free energy of poplar and yellow pine strands by Wilhelmy Plate Method. The measurement items included the surface contact angle, surface free energy and chan...The objective of this study was to investigate the surface free energy of poplar and yellow pine strands by Wilhelmy Plate Method. The measurement items included the surface contact angle, surface free energy and change of sample weight. Thirty industrial strands were randomly collected for each condition. The samples were cut down to 25.0-26.0 mm long, 7.0-8.0 mm wide. The density and thickness of each sample were also tested. The range of density was from 0.35 to 0.75 g/cm^3 and the range of thickness was from 0.5 to 1.0 ram. The research result shows that there is a close relationship between the wettability, mass change and moisture content. Both the density and the thickness of the strand have a small influence on the surface contact angle and the surface free energy.展开更多
Nanoindentation technique is a technique that determines the mechanical properties of a material in sub-micron scale. The technique involves penetrating a sample material using an indenter, while the penetration depth...Nanoindentation technique is a technique that determines the mechanical properties of a material in sub-micron scale. The technique involves penetrating a sample material using an indenter, while the penetration depth and load are recorded so that stiffness and hardness of the indented location can be subsequently calculated. The micron spatial resolution in nanoindentaion tests renders the technique very useful in the investigation of the wood cell-wall level and polymer interphase. This review mainly discussed the principle of nanoindentation and its current applications in wood science field.展开更多
文摘【目的】研究木材胶合界面的静态和动态力学行为,探讨树脂渗透对木材管胞壁层力学性能的影响,为木质复合材料制造工艺优化和增强改性提供理论依据。【方法】采用纳米压痕静态和动态力学测试技术(Nano-DMA),对针叶材火炬松与酚醛树脂(PF)、脲醛树脂(UF)胶黏剂所形成胶合界面区域各相材料的静态弹性模量、硬度、蠕变性能以及储能模量和损耗模量等力学行为进行分析。【结果】静态力学行为方面,在界面区域,PF和UF渗透进入管胞壁层后,木材管胞壁的弹性模量( E r)和硬度( H )提高;经PF渗透后,木材管胞壁的 E r和 H 分别增加7%和26%;Burgers蠕变力学模型可有效描述胶合界面区域管胞壁的纳米压痕蠕变特性,经树脂渗透后,木材管胞壁的瞬时弹性模量增加,黏弹性模量和黏性系数减小;在保载初期,PF界面区域木材管胞壁的蠕变柔量约下降60%,UF界面区域木材管胞壁的蠕变柔量约下降58%。动态力学行为方面,随着加载频率增加,界面材料的储能模量( E ′ r)逐渐增大,而损耗模量( E ″ r)和损耗因子(tan δ)呈减小趋势;当加载频率为10 Hz时,PF和UF树脂渗透使得管胞壁层的储能模量分别增加16%和29%。【结论】胶合界面区域胶黏剂进入管胞壁层,对木材管胞的静态力学性能具有增强作用,同时胶黏剂可提高管胞壁的短期抗蠕变能力;木材管胞壁具有较高的储能模量和损耗模量,而树脂的储能模量和损耗模量较低,经树脂渗透后,木材管胞壁的储能模量增加,但损耗模量和损耗因子呈下降趋势,可能对界面传递和分散应力产生不利影响。
基金This study is supported by the project of natural science basic research in Jiangsu universities under Contact Number 05KJA22019,namely research on the properties modification of fast-growing poplar wood.
文摘The objective of this study was to investigate the surface free energy of poplar and yellow pine strands by Wilhelmy Plate Method. The measurement items included the surface contact angle, surface free energy and change of sample weight. Thirty industrial strands were randomly collected for each condition. The samples were cut down to 25.0-26.0 mm long, 7.0-8.0 mm wide. The density and thickness of each sample were also tested. The range of density was from 0.35 to 0.75 g/cm^3 and the range of thickness was from 0.5 to 1.0 ram. The research result shows that there is a close relationship between the wettability, mass change and moisture content. Both the density and the thickness of the strand have a small influence on the surface contact angle and the surface free energy.
文摘Nanoindentation technique is a technique that determines the mechanical properties of a material in sub-micron scale. The technique involves penetrating a sample material using an indenter, while the penetration depth and load are recorded so that stiffness and hardness of the indented location can be subsequently calculated. The micron spatial resolution in nanoindentaion tests renders the technique very useful in the investigation of the wood cell-wall level and polymer interphase. This review mainly discussed the principle of nanoindentation and its current applications in wood science field.
