The pore structural characteristics of strontium residue were studied with the N2 adsorption method(ASAP2010).The kinetic properties concerning dissolving and leaching strontium waste were described by determining the...The pore structural characteristics of strontium residue were studied with the N2 adsorption method(ASAP2010).The kinetic properties concerning dissolving and leaching strontium waste were described by determining the concentrations of Sr2+,Ba2+ and soluble sulphides in solutions.The results showed that the specific surface area and pore volume increased with decreasing granule diameter,and the micropore surface of the residue was fractal.In the dissolving and leaching processes of strontium residue,soluble ion concentrations increased with decreasing granule diameter of the residue,and the reaction dimension was lower than the fractal dimension of pore surface.Sr2+ and soluble sulphide concentrations significantly exceeded the defined standard values,while Ba2+ concentrations did not,either in the dissolving or leaching solutions.In addition,dissolving and leaching reactions selectively occurred on the micropore surface of strontium residue.展开更多
The accumulation of electrolytic manganese residue (EMR) has become a serious problem and its recycling will be of great benefit to protect the environment and assist sustainable development. The reusing method was co...The accumulation of electrolytic manganese residue (EMR) has become a serious problem and its recycling will be of great benefit to protect the environment and assist sustainable development. The reusing method was conducted by leaching EMR with sulfuric acid and the optimal leaching condition was 1:3 (g/g) as the ratio of solid to liquid with 20% (g/g) H2SO4 , heating at 90 ℃ for 3 hours, which aims at extracting Mn in a sulfuric acid medium. The produced MnSO4 solution was precipitated by adding alkali and oxidized in aqueous phase. The oxidized products were characterized by various techniques, including X-ray powder diffraction (XRD), Fourier transform infrared (IR) spectrometry, vibrating sample magnetometry (VSM), with Brunauer-Emmett-Teller (BET) specific surface area instrument and laser particle size analyzer. The final products were confirmed to be a single-phase Mn3O4 .展开更多
文摘The pore structural characteristics of strontium residue were studied with the N2 adsorption method(ASAP2010).The kinetic properties concerning dissolving and leaching strontium waste were described by determining the concentrations of Sr2+,Ba2+ and soluble sulphides in solutions.The results showed that the specific surface area and pore volume increased with decreasing granule diameter,and the micropore surface of the residue was fractal.In the dissolving and leaching processes of strontium residue,soluble ion concentrations increased with decreasing granule diameter of the residue,and the reaction dimension was lower than the fractal dimension of pore surface.Sr2+ and soluble sulphide concentrations significantly exceeded the defined standard values,while Ba2+ concentrations did not,either in the dissolving or leaching solutions.In addition,dissolving and leaching reactions selectively occurred on the micropore surface of strontium residue.
基金the China Scholarship Council (CSC) and Chongqing Science and Technology Commission (CSTC, 2010AC4054)
文摘The accumulation of electrolytic manganese residue (EMR) has become a serious problem and its recycling will be of great benefit to protect the environment and assist sustainable development. The reusing method was conducted by leaching EMR with sulfuric acid and the optimal leaching condition was 1:3 (g/g) as the ratio of solid to liquid with 20% (g/g) H2SO4 , heating at 90 ℃ for 3 hours, which aims at extracting Mn in a sulfuric acid medium. The produced MnSO4 solution was precipitated by adding alkali and oxidized in aqueous phase. The oxidized products were characterized by various techniques, including X-ray powder diffraction (XRD), Fourier transform infrared (IR) spectrometry, vibrating sample magnetometry (VSM), with Brunauer-Emmett-Teller (BET) specific surface area instrument and laser particle size analyzer. The final products were confirmed to be a single-phase Mn3O4 .
