A new flexible 3D porous metal-organic framework (MOF) with 1D open nanotube,[Co2(μ5-CTAI)(dpe)(H2O)2]n·6n(H2O)(1) (CTA=cyclohexane-1,2,4,5-tetracarboxylic acid,dpe=1,2-di(4-pyridyl) ethylene) has been prepared ...A new flexible 3D porous metal-organic framework (MOF) with 1D open nanotube,[Co2(μ5-CTAI)(dpe)(H2O)2]n·6n(H2O)(1) (CTA=cyclohexane-1,2,4,5-tetracarboxylic acid,dpe=1,2-di(4-pyridyl) ethylene) has been prepared and structurally characterized.Meanwhile,each 1D nanotubes filled with 1D water chain with dimension of 13.711 × 12.275 2.Compound 1 represents a new example that collapse/deform upon dehydration/hydration and shows adsorb H 2 O selectively over organic solvents.展开更多
基金supported by the National Natural Science Foundation of China (20771090)State Key Program of National Natural Science Foundation of China (20931005)+1 种基金Major Research Plan of National Natural Science Foundation of China (91022004)Specialized Research Found for the Doctoral Program of Higher Education (20096101110005)
文摘A new flexible 3D porous metal-organic framework (MOF) with 1D open nanotube,[Co2(μ5-CTAI)(dpe)(H2O)2]n·6n(H2O)(1) (CTA=cyclohexane-1,2,4,5-tetracarboxylic acid,dpe=1,2-di(4-pyridyl) ethylene) has been prepared and structurally characterized.Meanwhile,each 1D nanotubes filled with 1D water chain with dimension of 13.711 × 12.275 2.Compound 1 represents a new example that collapse/deform upon dehydration/hydration and shows adsorb H 2 O selectively over organic solvents.
