By replacing hexyl chains in poly(3-hexylthiophene)(P3HT)with 2-propoxyethyls,four poly(3-(2-propoxyethyl)thiophene)(P3POET)homopolymers with comparable polydispersity indexes(PDI)and regioregularities were prepared h...By replacing hexyl chains in poly(3-hexylthiophene)(P3HT)with 2-propoxyethyls,four poly(3-(2-propoxyethyl)thiophene)(P3POET)homopolymers with comparable polydispersity indexes(PDI)and regioregularities were prepared herein in addition with step increment of about 7 kDa on numberaverage molecular weight(M_(n))from around 11 to 32 kDa(accordingly denoted as P11k,P18k,P25k,and P32k).When doped in film by FeCl_(3)at the optimized conditions,the maximum power factor(PF_(max))increases greatly from 4.3μW·m^(-1)·K^(-2)for P11k to 8.8μW·m^(-1)·K^(-2)for P18k,and further to 9.7μW·m^(-1)·K^(-2)for P25k,followed by a slight decrease to 9.2μW·m^(-1)·K^(-2)for P32k.The close Seebeck coefficients(S)at PF_(max)are observed in these doped polymer films due to their consistent frontier orbital energy levels and Fermi levels.The main contribution to this PF_(max)evolution thus comes from the corresponding conductivities(σ).Theσvariation of the doped films can be rationally correlated with their microstructure evolution.展开更多
基于晶闸管换流器的特高压直流输电系统(ultra-high voltage direct current based on line commutated converter,LCC-UHVDC)的故障定位算法对智能电网的安全稳定运行起着重要作用。针对长距离特高压直流输电系统故障测距方法精准度低...基于晶闸管换流器的特高压直流输电系统(ultra-high voltage direct current based on line commutated converter,LCC-UHVDC)的故障定位算法对智能电网的安全稳定运行起着重要作用。针对长距离特高压直流输电系统故障测距方法精准度低、快速性差的问题,提出了一种基于变分模态分解法(variational mode decomposition,VMD)和Teager能量算子(Teager energy operator,TEO)的双端行波故障测距方法。首先,研究了LCC-UHVDC线路故障电压行波的传播特性。利用零模电压随线路传播衰减明显的特征,通过VMD算法提取采样点处零模电压行波的时频特性。针对VMD参数选择不当导致的模态混叠问题,利用K-L散度(Kullback-Leibler divergence)对提取的模态指标进行优化。然后采用TEO对分解后信号进行瞬时能量谱提取,精确标定波头到达时间,最后采用双端迭代测距法迭代求解故障距离。在PSCAD/EMTDC搭建±800 kV LCC-UHVDC仿真模型进行验证。结果表明,所提方法在不同故障位置、过渡电阻和故障类型下具有较强的鲁棒性。展开更多
基金Funded by the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan Univesity of Technology。
文摘By replacing hexyl chains in poly(3-hexylthiophene)(P3HT)with 2-propoxyethyls,four poly(3-(2-propoxyethyl)thiophene)(P3POET)homopolymers with comparable polydispersity indexes(PDI)and regioregularities were prepared herein in addition with step increment of about 7 kDa on numberaverage molecular weight(M_(n))from around 11 to 32 kDa(accordingly denoted as P11k,P18k,P25k,and P32k).When doped in film by FeCl_(3)at the optimized conditions,the maximum power factor(PF_(max))increases greatly from 4.3μW·m^(-1)·K^(-2)for P11k to 8.8μW·m^(-1)·K^(-2)for P18k,and further to 9.7μW·m^(-1)·K^(-2)for P25k,followed by a slight decrease to 9.2μW·m^(-1)·K^(-2)for P32k.The close Seebeck coefficients(S)at PF_(max)are observed in these doped polymer films due to their consistent frontier orbital energy levels and Fermi levels.The main contribution to this PF_(max)evolution thus comes from the corresponding conductivities(σ).Theσvariation of the doped films can be rationally correlated with their microstructure evolution.
文摘基于晶闸管换流器的特高压直流输电系统(ultra-high voltage direct current based on line commutated converter,LCC-UHVDC)的故障定位算法对智能电网的安全稳定运行起着重要作用。针对长距离特高压直流输电系统故障测距方法精准度低、快速性差的问题,提出了一种基于变分模态分解法(variational mode decomposition,VMD)和Teager能量算子(Teager energy operator,TEO)的双端行波故障测距方法。首先,研究了LCC-UHVDC线路故障电压行波的传播特性。利用零模电压随线路传播衰减明显的特征,通过VMD算法提取采样点处零模电压行波的时频特性。针对VMD参数选择不当导致的模态混叠问题,利用K-L散度(Kullback-Leibler divergence)对提取的模态指标进行优化。然后采用TEO对分解后信号进行瞬时能量谱提取,精确标定波头到达时间,最后采用双端迭代测距法迭代求解故障距离。在PSCAD/EMTDC搭建±800 kV LCC-UHVDC仿真模型进行验证。结果表明,所提方法在不同故障位置、过渡电阻和故障类型下具有较强的鲁棒性。
