He-Ar isotopic compositions of fluid inclusions trapped in pyrites from some representative PGE-polymetallic deposits in Lower Cambrian black rock series in South China were analyzed by using an inert gas isotopic mas...He-Ar isotopic compositions of fluid inclusions trapped in pyrites from some representative PGE-polymetallic deposits in Lower Cambrian black rock series in South China were analyzed by using an inert gas isotopic mass spectrometer. The results show that the ore-forming fluids possess a low 3He/4He ratio, varying from 0.43×10-8 to 26.39×10-8, with corresponding R/Ra value of 0.003-0.189. The 40Ar/36Ar ratios are 258-287, close to those of air saturated water (ASW). He-Ar isotopic indicator studies show that the ore-forming fluids were mainly derived from the formation water or basinal hot brine and sea water, while the content of mantle-derived fluid or deep-derived magmatic water might be negligible. The PGE-polymetallic mineralization might be related to the evolution of the Caledonian miogeosynclines distributed along the southern margin of the Yangtze Craton. During the Early Cambrian, the formation water or basinal hot brine trapped in Caledonian basins which accumulated giant thick sediments was expelled and migrated laterally along strata because of the pressure generated by overlying sediments. The basinal hot brine ascended along faults, mixed with sea water and finally deposited ore minerals.展开更多
With sodium dodecyl sulfonate(SDS) as the phase transferring catalyst, N,N-Dilauryl chitosans with a high degree of alkyl group substitution were prepared and characterized by means of FTIR, 1H NMR and elemental ana...With sodium dodecyl sulfonate(SDS) as the phase transferring catalyst, N,N-Dilauryl chitosans with a high degree of alkyl group substitution were prepared and characterized by means of FTIR, 1H NMR and elemental analyses. The results indicate that the average degree of alkyl group substitution on the chitosan increases with decreasing the molecular weight of the chitosan. The fully N,N-dilaurylated chitosan was found to be dissolvable in chloroform. The collapsed pressures of the samples derived from chitosan with 3000, 5000 and 10000 dalton are 47.6, 48.2 and 51.0 mN/m, respectively. The surface area occupied by the monomer unit(glucosamine) of all those samples is 0.6 nm2.展开更多
The Songxi deposit is a newly discovered large Ag (Sb) deposit. By using a suite of high-vacuum quadrupole gas mass spectrometer systems, the authors have recognized many kinds of light hydrocarbons in fluid inclusion...The Songxi deposit is a newly discovered large Ag (Sb) deposit. By using a suite of high-vacuum quadrupole gas mass spectrometer systems, the authors have recognized many kinds of light hydrocarbons in fluid inclusions of minerals. These hydrocarbons are mainly composed of C1-C4 saturated alkanes, while the contents of C2-C4 unsaturated alkenes and aromatic hydrocarbons are quite low, suggesting that the metallogenic processes have not been affected by magmatic activities. Chemical equilibrium studies show that these hydrocarbons may be a mixture of organic gases generated by microorganism activity and those by thermal cracking of type-n kerogens (kukersite) in sedimentary host rocks, and the former may constitute more than two-thirds, implying that microorganism might have played an important role in the metallogenesis. The equilibrium temperature of the latter is about 300℃, which is much higher than the geothermal temperature at the estimated depth of metallogenesis. Thus, the light hydrocarbons generated by thermal cracking of kerogens probably originated in the deep part of the sedimentary basins and then migrated through a long distance to shallower horizons of the basin. Based on the composition of light hydrocarbons in fluid inclusions, the authors infer that the Songxi deposit was formed in a continental rift. The analytical data presented in this paper support from one aspect the genetic model that the Songxi deposit may be a sedimentary hot brine transformed deposit instead of a submarine basic volcanic exhalation and low-medium temperature volcanic hydrothermal fluid filling deposit proposed by most previous researchers.展开更多
Carbon-carbon double bond functional groups are often protected through a popular bromination/debromination method because of their reactivity. An ultrasonic-enhanced stereoselective debromination of vic-dibromides wi...Carbon-carbon double bond functional groups are often protected through a popular bromination/debromination method because of their reactivity. An ultrasonic-enhanced stereoselective debromination of vic-dibromides with metallic zinc powder in aqueous media has been developed, which generates E-alkenes with excellent yields. The reactivity of vic-dibromides decreases in the order of 1,2-dibromo-1,2-diphenylethane>1,2-dibromo-1-phenylethane>1,2-dibromo-1,2-dialkylethane.展开更多
Mathematical model for hyperboloid grinding of twist drill and relationships between drill design and grinding parameters are introduced.Point angles at outer corner and chisel edge corner are proposed to be used as t...Mathematical model for hyperboloid grinding of twist drill and relationships between drill design and grinding parameters are introduced.Point angles at outer corner and chisel edge corner are proposed to be used as the drill design parameters to determine the type uniquely and the relicf andgle is used as a supplement parameter.Function relations between the twist drill design and the grinding parameters are derived.Hence a theeoretical basis is estab-lised for design and grinding of the hyperboloid twist drill.展开更多
The tendency and dynamic characteristics of horizontal movement along the Shanxi fault zone have been analyzed using the data obtained from 6 repeated measurements (1996～2001) in the GPS monitoring network arranged a...The tendency and dynamic characteristics of horizontal movement along the Shanxi fault zone have been analyzed using the data obtained from 6 repeated measurements (1996～2001) in the GPS monitoring network arranged along the Shanxi fault zone. The results indicate: (1) the tendentious activity of the present stage is characterized by a W trending movement along the northern segment of the zone, an E trending movement along the southern segment and counter clockwise differential activity on the whole, but the intensity of the tendentious activity is not high. The tendentious differential movement is only about 3 mm/a in the direction perpendicular to the fault zone from the south to the north, and its stretch in the SN direction is only 1 mm/a and mainly occurs along the north segment of the fault; (2) The azimuth of the principal compressive stress field reflected by the tendentious movement is 72°; (3) The property of annual activity is not the same, even contrary to one another or deviates from the tendentious activity. Therefore, the parameters of the strain field derived from them dont reflect the physical characteristics of the basic stress field. (4) The high frequency movement (yearly) does not only exist but is also complicated by an intensity several times higher than that of the tendentious movement; (5) Obvious differential movements, including strike slip, can not be seen in either in secular activity or annual activity on both sides of any fault. The tendentious movement not only verifies the conjecture of “strong in the south and weak in north”, which is the basic feature forcing the western boundary of the North China area, but it also extends to the hinterland of North China. The fact that there is no obvious differential activity on both sides of the fault might indicate that the differential activity among the intraplate blocks is completed by gradual variation in a certain space, rather than the abrupt change bordered by a fault or narrow stripe zone. The obvious dynamic activity might indicate: (1) there is stress disturbance in the basic stress field; (2) the inhomogeneous or non synchronous variation that appeared in the regional stress and strain fields was due to the different physical property of the medium; (3)the response occurred because of a variety of external variations. The movement in 2001 shows that the Daixian county and its adjacent area might be the boundary segment for the relative differential activity. More attention should be paid here.展开更多
Let G1 and G2 be two graphs of the same order,If G1 is isomorphic to a spanning subgraph of the complement of G2,then we say that G1 and G2 are packable.A graph G is called a (p,m)-graph if G has p vertices and m edge...Let G1 and G2 be two graphs of the same order,If G1 is isomorphic to a spanning subgraph of the complement of G2,then we say that G1 and G2 are packable.A graph G is called a (p,m)-graph if G has p vertices and m edges.The main purpose of this paper is to present a necessary and sufficient condition for a tree of order p and a (p,p+1)-graph to be packable.展开更多
Hydrothermal clay minerals that formed in the main metallogenic stage of the Changkeng disseminated-type gold deposit in central Guangdong were analyzed by the 40Ar/39Ar laser probe. The results give Ar-Ar isochron ag...Hydrothermal clay minerals that formed in the main metallogenic stage of the Changkeng disseminated-type gold deposit in central Guangdong were analyzed by the 40Ar/39Ar laser probe. The results give Ar-Ar isochron ages of 109.9 1.4 to 110.1 1.3 Ma, which are 30 to 50 Ma older than the age of silver ore bodies in the deposit. Both gold and silver mineralizations were not related to hidden granite batholith in the mining district, but probably related to evo-lution of sedimentary basins. This study shows that the 40Ar/39Ar laser probe is a sound dating tool applicable to sediment-hosted disseminated-type gold deposit.展开更多
In this paper, orthogonal/turbo-codes for mobile DS-CDMA communications are considered. We compare the performances of turbo-codes with those of convolutional codes for noncoherent M-ary orthogonal modulation in ...In this paper, orthogonal/turbo-codes for mobile DS-CDMA communications are considered. We compare the performances of turbo-codes with those of convolutional codes for noncoherent M-ary orthogonal modulation in multipath fading channels. One method to calculate the branch transition probability of turbo-codes is suggested.By using the parameter of cut-off rate capacity efficiency, 1/2/5 (37,21) turbo-codes are more efficient for 1/3/9(557,663,711) convolutional codes. Given the same spread gain, turbo-codes will increase system's capacity.If SOVA is used in the decoding for turbo-codes case, the dime-delay caused by turbo-decoding is only 1.2 times of that of convolutional codes. Obviously, turbo-codes show better performances at the cost of the hardware complexity of the encoder and the decoder.展开更多
基金the National Natural Sciences Foundation of China(grants40173025,49928201)Trans-century Training Program Foundation for the Talents by the Ministry of Education the Visiting Scholar Foundation of Labs in Universities.
文摘He-Ar isotopic compositions of fluid inclusions trapped in pyrites from some representative PGE-polymetallic deposits in Lower Cambrian black rock series in South China were analyzed by using an inert gas isotopic mass spectrometer. The results show that the ore-forming fluids possess a low 3He/4He ratio, varying from 0.43×10-8 to 26.39×10-8, with corresponding R/Ra value of 0.003-0.189. The 40Ar/36Ar ratios are 258-287, close to those of air saturated water (ASW). He-Ar isotopic indicator studies show that the ore-forming fluids were mainly derived from the formation water or basinal hot brine and sea water, while the content of mantle-derived fluid or deep-derived magmatic water might be negligible. The PGE-polymetallic mineralization might be related to the evolution of the Caledonian miogeosynclines distributed along the southern margin of the Yangtze Craton. During the Early Cambrian, the formation water or basinal hot brine trapped in Caledonian basins which accumulated giant thick sediments was expelled and migrated laterally along strata because of the pressure generated by overlying sediments. The basinal hot brine ascended along faults, mixed with sea water and finally deposited ore minerals.
基金Supported by the National Natural Science Foundation of China(No.2 0 2 74 0 13) ,Key Project of the Fujian ProvincialScience and Technology(No.2 0 0 2 I0 0 4 ) and the Fujian Provincial Science Foundation of China(No.E0 110 0 2 7and C0 310 0 0 9)
文摘With sodium dodecyl sulfonate(SDS) as the phase transferring catalyst, N,N-Dilauryl chitosans with a high degree of alkyl group substitution were prepared and characterized by means of FTIR, 1H NMR and elemental analyses. The results indicate that the average degree of alkyl group substitution on the chitosan increases with decreasing the molecular weight of the chitosan. The fully N,N-dilaurylated chitosan was found to be dissolvable in chloroform. The collapsed pressures of the samples derived from chitosan with 3000, 5000 and 10000 dalton are 47.6, 48.2 and 51.0 mN/m, respectively. The surface area occupied by the monomer unit(glucosamine) of all those samples is 0.6 nm2.
基金supported by the National Natural Science Foundation of China(grants 49502029,49928201 and 49773195)the Natural Sciences Foundation of Guangdong Province(No.970123)+3 种基金the Visiting Scholar Foundation of Labs in Universitiesthe Research Foundation of the State Key Laboratory for Mineral Deposits Research in Nanjing UniversityResearch Foundation of Young(originally translated as Youth)Teachers of the National Educational Department and the Training Program of Middle-aged and Young(originally translated as Medium-Youth)Teachers supported by the Lingnan Foundationsupported by the Trans-century Training Program Foundation for the Talents by the Ministry of Education
文摘The Songxi deposit is a newly discovered large Ag (Sb) deposit. By using a suite of high-vacuum quadrupole gas mass spectrometer systems, the authors have recognized many kinds of light hydrocarbons in fluid inclusions of minerals. These hydrocarbons are mainly composed of C1-C4 saturated alkanes, while the contents of C2-C4 unsaturated alkenes and aromatic hydrocarbons are quite low, suggesting that the metallogenic processes have not been affected by magmatic activities. Chemical equilibrium studies show that these hydrocarbons may be a mixture of organic gases generated by microorganism activity and those by thermal cracking of type-n kerogens (kukersite) in sedimentary host rocks, and the former may constitute more than two-thirds, implying that microorganism might have played an important role in the metallogenesis. The equilibrium temperature of the latter is about 300℃, which is much higher than the geothermal temperature at the estimated depth of metallogenesis. Thus, the light hydrocarbons generated by thermal cracking of kerogens probably originated in the deep part of the sedimentary basins and then migrated through a long distance to shallower horizons of the basin. Based on the composition of light hydrocarbons in fluid inclusions, the authors infer that the Songxi deposit was formed in a continental rift. The analytical data presented in this paper support from one aspect the genetic model that the Songxi deposit may be a sedimentary hot brine transformed deposit instead of a submarine basic volcanic exhalation and low-medium temperature volcanic hydrothermal fluid filling deposit proposed by most previous researchers.
基金Supported by the National Natural Science Foundation of China(No.2 0 372 0 2 4 2 0 172 0 18) +2 种基金the Excellent ScientistFoundation of Anhui ProvinceChina(No.2 0 0 10 4 0 ) the Natural Science Foundation of the Educational Departm entof AnhuiProvince
文摘Carbon-carbon double bond functional groups are often protected through a popular bromination/debromination method because of their reactivity. An ultrasonic-enhanced stereoselective debromination of vic-dibromides with metallic zinc powder in aqueous media has been developed, which generates E-alkenes with excellent yields. The reactivity of vic-dibromides decreases in the order of 1,2-dibromo-1,2-diphenylethane>1,2-dibromo-1-phenylethane>1,2-dibromo-1,2-dialkylethane.
文摘Mathematical model for hyperboloid grinding of twist drill and relationships between drill design and grinding parameters are introduced.Point angles at outer corner and chisel edge corner are proposed to be used as the drill design parameters to determine the type uniquely and the relicf andgle is used as a supplement parameter.Function relations between the twist drill design and the grinding parameters are derived.Hence a theeoretical basis is estab-lised for design and grinding of the hyperboloid twist drill.
文摘The tendency and dynamic characteristics of horizontal movement along the Shanxi fault zone have been analyzed using the data obtained from 6 repeated measurements (1996～2001) in the GPS monitoring network arranged along the Shanxi fault zone. The results indicate: (1) the tendentious activity of the present stage is characterized by a W trending movement along the northern segment of the zone, an E trending movement along the southern segment and counter clockwise differential activity on the whole, but the intensity of the tendentious activity is not high. The tendentious differential movement is only about 3 mm/a in the direction perpendicular to the fault zone from the south to the north, and its stretch in the SN direction is only 1 mm/a and mainly occurs along the north segment of the fault; (2) The azimuth of the principal compressive stress field reflected by the tendentious movement is 72°; (3) The property of annual activity is not the same, even contrary to one another or deviates from the tendentious activity. Therefore, the parameters of the strain field derived from them dont reflect the physical characteristics of the basic stress field. (4) The high frequency movement (yearly) does not only exist but is also complicated by an intensity several times higher than that of the tendentious movement; (5) Obvious differential movements, including strike slip, can not be seen in either in secular activity or annual activity on both sides of any fault. The tendentious movement not only verifies the conjecture of “strong in the south and weak in north”, which is the basic feature forcing the western boundary of the North China area, but it also extends to the hinterland of North China. The fact that there is no obvious differential activity on both sides of the fault might indicate that the differential activity among the intraplate blocks is completed by gradual variation in a certain space, rather than the abrupt change bordered by a fault or narrow stripe zone. The obvious dynamic activity might indicate: (1) there is stress disturbance in the basic stress field; (2) the inhomogeneous or non synchronous variation that appeared in the regional stress and strain fields was due to the different physical property of the medium; (3)the response occurred because of a variety of external variations. The movement in 2001 shows that the Daixian county and its adjacent area might be the boundary segment for the relative differential activity. More attention should be paid here.
基金This research is partially supported by the National Natural Science Foundation of China(19971053).
文摘Let G1 and G2 be two graphs of the same order,If G1 is isomorphic to a spanning subgraph of the complement of G2,then we say that G1 and G2 are packable.A graph G is called a (p,m)-graph if G has p vertices and m edges.The main purpose of this paper is to present a necessary and sufficient condition for a tree of order p and a (p,p+1)-graph to be packable.
基金supported by the National Natural Science Foundation of China(Grant Nos.49773195,49502029 and 49928201)the Key Scientific and Technology Project from the Land and Resources Ministry of China(Grant No.200206)+3 种基金Trans—century Training Programme Foundation for the Talents from the Ministry of Education of ChinaVisiting Scholar Foundation of the State Key Laboratory of Mineral Deposit Research in Naniing Universitythe Visiting Scholar Foundation of Labs in Universitiesalso by the Lingnan Foundation of USA.
文摘Hydrothermal clay minerals that formed in the main metallogenic stage of the Changkeng disseminated-type gold deposit in central Guangdong were analyzed by the 40Ar/39Ar laser probe. The results give Ar-Ar isochron ages of 109.9 1.4 to 110.1 1.3 Ma, which are 30 to 50 Ma older than the age of silver ore bodies in the deposit. Both gold and silver mineralizations were not related to hidden granite batholith in the mining district, but probably related to evo-lution of sedimentary basins. This study shows that the 40Ar/39Ar laser probe is a sound dating tool applicable to sediment-hosted disseminated-type gold deposit.
文摘In this paper, orthogonal/turbo-codes for mobile DS-CDMA communications are considered. We compare the performances of turbo-codes with those of convolutional codes for noncoherent M-ary orthogonal modulation in multipath fading channels. One method to calculate the branch transition probability of turbo-codes is suggested.By using the parameter of cut-off rate capacity efficiency, 1/2/5 (37,21) turbo-codes are more efficient for 1/3/9(557,663,711) convolutional codes. Given the same spread gain, turbo-codes will increase system's capacity.If SOVA is used in the decoding for turbo-codes case, the dime-delay caused by turbo-decoding is only 1.2 times of that of convolutional codes. Obviously, turbo-codes show better performances at the cost of the hardware complexity of the encoder and the decoder.
