Meteorological conditions,particularly the vertical wind field structure,have a direct influence on the PM2.5 concentrations over the Pearl River Delta(PRD).In October 2012,an exceptional air pollution event occurred ...Meteorological conditions,particularly the vertical wind field structure,have a direct influence on the PM2.5 concentrations over the Pearl River Delta(PRD).In October 2012,an exceptional air pollution event occurred in the PRD,and a high concentration of PM2.5 was registered at some stations.During days with PM2.5 air pollution,the wind speed was less than 3 m s-1 at the surface,and the vertical wind field featured a weak wind layer(WWL)with a thickness of approximately 1000 m.The mean atmospheric boundary layer height was less than 500 m during pollution days,but it was greater than 1400 m during non-pollution days.A strong negative correlation was detected between the PM2.5 concentration and the ventilation index(VI).The VI was less than 2000 m2 s-1 during PM2.5 air pollution days.Because of the weak wind,sea-land breezes occurred frequently,the recirculation factor(RF)values were small at a height of 800 m during pollution days,and the zones with the lowest RF values always occurred between the heights of 300 and 600 m.The RF values during PM2.5 pollution days were approximately 0.4 to 0.6 below a height of 800 m,reducing the transportation capacity of the wind field to only 40%to 60%.The RF and wind profile characteristics indicated that sealand breezes were highly important in the accumulation of PM2.5 air pollution in the PRD.The sea breezes may transport pollutants back inland and may result in the peak PM2.5 concentrations at night.展开更多
Wavelet analysis was applied to lidar observations to retrieve the planetary boundary layer height(PBLH)over Guangzhou from September 2013 to November 2014 over Guangzhou.Impact of the boundary effect and the wavelet ...Wavelet analysis was applied to lidar observations to retrieve the planetary boundary layer height(PBLH)over Guangzhou from September 2013 to November 2014 over Guangzhou.Impact of the boundary effect and the wavelet scale factor on the accuracy of the retrieved PBLH has been explored thoroughly.In addition,the PBLH diurnal variations and the relationship between PM_(2.5) concentration and PBLH during polluted and clean episodes were studied.Results indicate that the most steady retrieved PBLH can be obtained when scale factor is chosen between 300-390 m.The retrieved maximum and minimum PBLH in the annual mean diurnal cycle were~1100 m and~650 m,respectively.The PBLH was significantly lower in the dry season than in the wet season,with the average highest PBLH in the dry season and the wet season being~1050 m and~1200 m respectively.Compared to the wet season,the development of PBLH in the dry season was delayed by at least one hour due to the seasonal cycle of solar radiation.Episode analysis indicated that the PBLH was~50%higher during clean episodes than during haze episodes.The average highest PBLH in the haze episodes and clean episodes were~800 m and~1300 m,respectively.A significant negative correlation between PBLH and PM_(2.5) concentration(r=-0.55**)is discovered.According to China"Ambient Air Quality Standard",the PBLH values in good and slightly polluted conditions were 1/6-1/3 lower than that in excellent conditions,while the corresponding PM_(2.5) concentration were~2-2.5 times higher.展开更多
The climatic and environmental effects of atmospheric aerosols are a hot topic in global science community, and radiative properties of the aerosols are one of the important parameters in assessing climatic change. He...The climatic and environmental effects of atmospheric aerosols are a hot topic in global science community, and radiative properties of the aerosols are one of the important parameters in assessing climatic change. Here we studied the black carbon concentration and absorption coefficient measured with aethalometers, scattering coefficient measured with nephelometers, and single scattering albedo derived at an atmospheric composition watch station in Guangzhou from 2004 to 2007. Our main results are as follows. The data of black carbon concentration and absorption coefficients measured with instruments cannot be directly used until they are measured in parallel with internationally accepted instruments for comparison, calibration, and reduction. After evaluation of the data, the result shows that the monthly mean of BC concentration varies 3.1―14.8 μg·m-3 and the concentration decreases by about 1 μg·m-3 in average over the four years; It is higher in the dry season with a multi-year mean of 8.9 μg/m3 and lower in the rainy season with a multi-year mean of 8.0 μg·m-3; The extreme maximum of monthly mean concentration occurred in December 2004 and extreme minimum in July 2007, and a 4-year mean is 8.4 μg·m-3. It is also shown that monthly mean scattering coefficient derived varies 129 -565 Mm-1, monthly mean absorption coefficient 32-139 Mm-1, and monthly mean single scattering albedo 0.71-0.91, with annual mean values of 0.80, 0.82, 0.79 and 0.84 for 2004, 2005, 2006 and 2007, respectively. Three instruments were used to take simultaneous measurements of BC in PM10, PM2.5, and PM1 and the results showed that PM2.5 took up about 90% of PM10 and PM1 accounted for about 68% of PM2.5, and BC aerosols are mainly present in fine particulates. The variability of BC concentrations is quite consistent between the Nancun station (141 m above sea level) and the Panyu station (13 m above sea level), which are 8 km apart from each other. The concentration in higher altitude station (Panyu) is consistently lower than the lower altitude station (Nancun), and the difference of annual mean is about 4 μg·m-3.展开更多
We detected a severe haze process in Guangzhou area with lidar and microwave radiometer, performed an inversion to get boundary layer height by wavelet covariance transform, and analyzed the correlation between meteor...We detected a severe haze process in Guangzhou area with lidar and microwave radiometer, performed an inversion to get boundary layer height by wavelet covariance transform, and analyzed the correlation between meteorological factors of boundary layer and visibility from the perspective of dynamical and thermodynamic structures. Our results indicate that the boundary layer height shows significant daily changes, consistent with ground visibility variation. During the cleaning process, the boundary layer height exceeded 1 km; during severe haze, the height was only 500 m. Temperature gradient of 50–100 m, which was 30 h lag, was remarkably correlated with visibility, with the correlation coefficient of 0.77. High layer visibility(255 m) and low layer stability were significantly anticorrelation, and the maximum anticorrelation coefficient was up to-0.76 in cleaning days and-0.49 in haze days. In the related boundary layer meteorological factors, surface ventilation coefficient was linearly correlated with ground visibility, with the greatest correlation coefficient of 0.88. The correlation coefficients of boundary layer height, ground wind velocity, relative humidity and ground visibility were 0.76, 0.67, and-0.77, respectively. There was a strong correlation between different meteorological factors. The dominant meteorological factor during this haze process was surface ventilation coefficient. In the area without boundary layer height sounding, ground visibility and wind velocity could be used to estimate boundary layer height.展开更多
Our analysis of the surface aerosol and ultraviolet （UV） measurements in Pearl River Delta （PRD） region shows that the surface UV radiation is reduced by more than 50% due to high aerosol concentrations. This has ...Our analysis of the surface aerosol and ultraviolet （UV） measurements in Pearl River Delta （PRD） region shows that the surface UV radiation is reduced by more than 50% due to high aerosol concentrations. This has important impacts on urban ecosystem and photochemistry, especially on ozone photochemical production over the region. The quantitative effect of aerosols on surface ozone is evaluated by analyzing surface observations （including ozone, ultraviolet radiation, aerosol radiative parameters） and by using radiative and chemical models. A case study shows that the aerosol concentrations and UV radiation are significantly correlated with ozone concentrations. The correlation coefficient between the aerosol optical depth （AOD） and the PM10 mass concentration is very high, with a maximum of 0.98, and the AOD and UV radiation/ozone is anti- correlated, with a correlation coefficient of-0.90. The analysis suggests that ozone productivity is significantly decreased due to the reduction of UV radiation. The noon-time ozone maximum is considerably depressed when AOD is 0.6, and is further decreased when AOD is up to 1.2 due to the reduction of ozone photochemical productivity. Because the occurring probability of aerosol optical depth for AOD550m≥0.6 and AOD340mm ≥1.0 is 47, and 55% respectively during the dry season （October, November, December, January）, this heavy aerosol condition explains the low ozone maximum that often occurs in the dry season over the Guangzhou region. The analysis also suggests that the value of single scattering albedo （SSA） is very sensitive to the aerosol radiative effect when the radiative and chemical models are applied, implying that the value of SSA needs to be carefully studied when the models are used in calculating ozone production.展开更多
The UV attenuation due to atmospheric aerosols in Guangzhou was quantitatively assessed using surface ultraviolet radiation (UV,295-385 nm) observation,sun photometer and radiation models.Observations showed that the ...The UV attenuation due to atmospheric aerosols in Guangzhou was quantitatively assessed using surface ultraviolet radiation (UV,295-385 nm) observation,sun photometer and radiation models.Observations showed that the annual average value of aerosol optical depth (AOD) was 1.19 in UV spectral region of 340 nm,the annual average occurrence frequency of aerosol optical depth AOD 340 nm >1.0 was 55%,and the annual average attenuation rate of surface UV direct radiation of 340 nm was 68%.It was proven in the observation of surface UV radiation and model evaluation that annual average attenuation of UV due to atmosphere was 75%,and that reached 72% in the dry season (October,November,December and January);while average attenuation of UV due to atmospheric aerosols reached 62% in the dry season.It was indicated that very significant UV attenuations due to atmospheric aerosols existed in Guangzhou urban agglomeration,and at least half of UV radiation was attenuated due to atmospheric aerosols.Such large-amplitude attenuation will have a significant impact on urban ecosystem and species chemical cycles,especially photochemical reaction processes.展开更多
基金National Key R&D Plan of China(2017YFC0209606,2016YFC0203305)Major Program of National Natural Science Foundation of China(41630422,41801326,41275017)Science and Technology Program of Foshan Meteorological Bureau(201804)
文摘Meteorological conditions,particularly the vertical wind field structure,have a direct influence on the PM2.5 concentrations over the Pearl River Delta(PRD).In October 2012,an exceptional air pollution event occurred in the PRD,and a high concentration of PM2.5 was registered at some stations.During days with PM2.5 air pollution,the wind speed was less than 3 m s-1 at the surface,and the vertical wind field featured a weak wind layer(WWL)with a thickness of approximately 1000 m.The mean atmospheric boundary layer height was less than 500 m during pollution days,but it was greater than 1400 m during non-pollution days.A strong negative correlation was detected between the PM2.5 concentration and the ventilation index(VI).The VI was less than 2000 m2 s-1 during PM2.5 air pollution days.Because of the weak wind,sea-land breezes occurred frequently,the recirculation factor(RF)values were small at a height of 800 m during pollution days,and the zones with the lowest RF values always occurred between the heights of 300 and 600 m.The RF values during PM2.5 pollution days were approximately 0.4 to 0.6 below a height of 800 m,reducing the transportation capacity of the wind field to only 40%to 60%.The RF and wind profile characteristics indicated that sealand breezes were highly important in the accumulation of PM2.5 air pollution in the PRD.The sea breezes may transport pollutants back inland and may result in the peak PM2.5 concentrations at night.
基金National Key R&D Program of China(2019YFC0214605,2018YFC0213901)National Natural Science Foundation of China(41775037)+1 种基金Guangdong Provincial Key R&D Program(2020B1111360003)Scientific and Technological Innovation Team Project of Guangdong Meteorological Service(GRMCTD202003)。
文摘Wavelet analysis was applied to lidar observations to retrieve the planetary boundary layer height(PBLH)over Guangzhou from September 2013 to November 2014 over Guangzhou.Impact of the boundary effect and the wavelet scale factor on the accuracy of the retrieved PBLH has been explored thoroughly.In addition,the PBLH diurnal variations and the relationship between PM_(2.5) concentration and PBLH during polluted and clean episodes were studied.Results indicate that the most steady retrieved PBLH can be obtained when scale factor is chosen between 300-390 m.The retrieved maximum and minimum PBLH in the annual mean diurnal cycle were~1100 m and~650 m,respectively.The PBLH was significantly lower in the dry season than in the wet season,with the average highest PBLH in the dry season and the wet season being~1050 m and~1200 m respectively.Compared to the wet season,the development of PBLH in the dry season was delayed by at least one hour due to the seasonal cycle of solar radiation.Episode analysis indicated that the PBLH was~50%higher during clean episodes than during haze episodes.The average highest PBLH in the haze episodes and clean episodes were~800 m and~1300 m,respectively.A significant negative correlation between PBLH and PM_(2.5) concentration(r=-0.55**)is discovered.According to China"Ambient Air Quality Standard",the PBLH values in good and slightly polluted conditions were 1/6-1/3 lower than that in excellent conditions,while the corresponding PM_(2.5) concentration were~2-2.5 times higher.
文摘利用2013年9月—2014年11月广州地区激光雷达观测结果,使用小波分析反演边界层高度(PBLH),通过归一化后向散射信号(NRB)的小波分解对小波分析中直接影响PBLH识别的尺度因子a进行了选取.并以2014年1月发生的一次灰霾过程为例,对灰霾过程的PBLH等边界层特征进行了分析,并对边界层垂直结构进行了初步探究.同时,利用自组织映射神经网络(SOM)进行了天气分型,对整个观测时段激光雷达反演的PBLH与天气型之间的关系进行了统计.结果表明,通过对NRB廓线的小波分解,小波分析尺度因子a取300较为合适.灰霾过程中PBLH均存在日变化.从平均结果来看,PBLH最高值出现在13:00,为850 m;最低值出现在5:00,为483 m.灰霾过程PBLH与PM_(2.5)之间呈显著负相关(r=-0.62,p<0.01),风速与PM_(2.5)之间也呈显著负相关(r=-0.39,p<0.01).对流边界层平均高度约为稳定边界层的1.5倍,峰值高度约为稳定边界层的3倍.低压天气系统控制下灰霾天气出现的概率较低,对应的PBLH明显较高,峰值高度在1200～1600 m,日间边界层发展极为明显.而高压天气系统控制下边界层发展容易受到抑制,峰值高度均低于1000 m.
基金Supported by Natural Science Foundation of China (Grant Nos. U0733004,40375002, 40418008, 40775011)National High Technology R & D Program of China (Grant Nos. 2006AA06A306 and 2006AA06A308)National Basic Research Program of China (Grant No. 2005CB422207)
文摘The climatic and environmental effects of atmospheric aerosols are a hot topic in global science community, and radiative properties of the aerosols are one of the important parameters in assessing climatic change. Here we studied the black carbon concentration and absorption coefficient measured with aethalometers, scattering coefficient measured with nephelometers, and single scattering albedo derived at an atmospheric composition watch station in Guangzhou from 2004 to 2007. Our main results are as follows. The data of black carbon concentration and absorption coefficients measured with instruments cannot be directly used until they are measured in parallel with internationally accepted instruments for comparison, calibration, and reduction. After evaluation of the data, the result shows that the monthly mean of BC concentration varies 3.1―14.8 μg·m-3 and the concentration decreases by about 1 μg·m-3 in average over the four years; It is higher in the dry season with a multi-year mean of 8.9 μg/m3 and lower in the rainy season with a multi-year mean of 8.0 μg·m-3; The extreme maximum of monthly mean concentration occurred in December 2004 and extreme minimum in July 2007, and a 4-year mean is 8.4 μg·m-3. It is also shown that monthly mean scattering coefficient derived varies 129 -565 Mm-1, monthly mean absorption coefficient 32-139 Mm-1, and monthly mean single scattering albedo 0.71-0.91, with annual mean values of 0.80, 0.82, 0.79 and 0.84 for 2004, 2005, 2006 and 2007, respectively. Three instruments were used to take simultaneous measurements of BC in PM10, PM2.5, and PM1 and the results showed that PM2.5 took up about 90% of PM10 and PM1 accounted for about 68% of PM2.5, and BC aerosols are mainly present in fine particulates. The variability of BC concentrations is quite consistent between the Nancun station (141 m above sea level) and the Panyu station (13 m above sea level), which are 8 km apart from each other. The concentration in higher altitude station (Panyu) is consistently lower than the lower altitude station (Nancun), and the difference of annual mean is about 4 μg·m-3.
基金supported by the National Basic Research Program of China(Grant No.2011CB403403)the National Natural Science Foundation of China(Grant Nos.41205123,41375156,1175117)Guangdong Provincial Natural Science Foundation(Grant No.10151008019000004)
文摘We detected a severe haze process in Guangzhou area with lidar and microwave radiometer, performed an inversion to get boundary layer height by wavelet covariance transform, and analyzed the correlation between meteorological factors of boundary layer and visibility from the perspective of dynamical and thermodynamic structures. Our results indicate that the boundary layer height shows significant daily changes, consistent with ground visibility variation. During the cleaning process, the boundary layer height exceeded 1 km; during severe haze, the height was only 500 m. Temperature gradient of 50–100 m, which was 30 h lag, was remarkably correlated with visibility, with the correlation coefficient of 0.77. High layer visibility(255 m) and low layer stability were significantly anticorrelation, and the maximum anticorrelation coefficient was up to-0.76 in cleaning days and-0.49 in haze days. In the related boundary layer meteorological factors, surface ventilation coefficient was linearly correlated with ground visibility, with the greatest correlation coefficient of 0.88. The correlation coefficients of boundary layer height, ground wind velocity, relative humidity and ground visibility were 0.76, 0.67, and-0.77, respectively. There was a strong correlation between different meteorological factors. The dominant meteorological factor during this haze process was surface ventilation coefficient. In the area without boundary layer height sounding, ground visibility and wind velocity could be used to estimate boundary layer height.
基金supported by National Natural Science Foundation of China (Grant Nos. 40875090, 40375002, 40775011)Natural Science Foundation of Guangdong Province (Grant No. 7035008)Tropical Marine Meteorological Science Foundation (Grant No. 200502)
文摘Our analysis of the surface aerosol and ultraviolet （UV） measurements in Pearl River Delta （PRD） region shows that the surface UV radiation is reduced by more than 50% due to high aerosol concentrations. This has important impacts on urban ecosystem and photochemistry, especially on ozone photochemical production over the region. The quantitative effect of aerosols on surface ozone is evaluated by analyzing surface observations （including ozone, ultraviolet radiation, aerosol radiative parameters） and by using radiative and chemical models. A case study shows that the aerosol concentrations and UV radiation are significantly correlated with ozone concentrations. The correlation coefficient between the aerosol optical depth （AOD） and the PM10 mass concentration is very high, with a maximum of 0.98, and the AOD and UV radiation/ozone is anti- correlated, with a correlation coefficient of-0.90. The analysis suggests that ozone productivity is significantly decreased due to the reduction of UV radiation. The noon-time ozone maximum is considerably depressed when AOD is 0.6, and is further decreased when AOD is up to 1.2 due to the reduction of ozone photochemical productivity. Because the occurring probability of aerosol optical depth for AOD550m≥0.6 and AOD340mm ≥1.0 is 47, and 55% respectively during the dry season （October, November, December, January）, this heavy aerosol condition explains the low ozone maximum that often occurs in the dry season over the Guangzhou region. The analysis also suggests that the value of single scattering albedo （SSA） is very sensitive to the aerosol radiative effect when the radiative and chemical models are applied, implying that the value of SSA needs to be carefully studied when the models are used in calculating ozone production.
基金supported by the National Natural Science Foundation of China(41175117,40875090and40375002)the National Basic Research Program(2011CB403403)+1 种基金the Science and Technology Foundation of Guangdong Province(2010A030200012)the Science and Technology Innovation Team Plan of Guangdong Meteorological Bureau(201103)
文摘The UV attenuation due to atmospheric aerosols in Guangzhou was quantitatively assessed using surface ultraviolet radiation (UV,295-385 nm) observation,sun photometer and radiation models.Observations showed that the annual average value of aerosol optical depth (AOD) was 1.19 in UV spectral region of 340 nm,the annual average occurrence frequency of aerosol optical depth AOD 340 nm >1.0 was 55%,and the annual average attenuation rate of surface UV direct radiation of 340 nm was 68%.It was proven in the observation of surface UV radiation and model evaluation that annual average attenuation of UV due to atmosphere was 75%,and that reached 72% in the dry season (October,November,December and January);while average attenuation of UV due to atmospheric aerosols reached 62% in the dry season.It was indicated that very significant UV attenuations due to atmospheric aerosols existed in Guangzhou urban agglomeration,and at least half of UV radiation was attenuated due to atmospheric aerosols.Such large-amplitude attenuation will have a significant impact on urban ecosystem and species chemical cycles,especially photochemical reaction processes.
