We describe a simple method to increase the conductivity of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS)film by exposure to ultraviolet(UV)light in vacuum.Up to four order of conductivity improve...We describe a simple method to increase the conductivity of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS)film by exposure to ultraviolet(UV)light in vacuum.Up to four order of conductivity improvement(from 10 3to 50 S/cm)is achieved by irradiating PEDOT:PSS film with 254 nm ultraviolet(UV)light.Increased conductivity in UV treated PEDOT:PSS film is stable under ambient exposure.The mechanism for conductivity improvement is investigated by current-voltage measurement,atomic force microscopy,and absorption spectrum.Photo-cross-linking of PSS chains is determined as the reason for conductivity improvement.Our result demonstrates that UV treatment is capable of modifying the conductivity of PEDOT:PSS film independent of the process of film formation.展开更多
In this paper,configuration parameters of the waveguide are altered independently or simultaneously to control the cutoff frequencies of the guided band.The independent control range of the upper and lower cutoff freq...In this paper,configuration parameters of the waveguide are altered independently or simultaneously to control the cutoff frequencies of the guided band.The independent control range of the upper and lower cutoff frequencies is 55.0% and 63.9% of the photonic band gap(PBG),respectively.The regulating range of the simultaneous tuning can be as large as 28.6% in terms of the PBG,or 240% in terms of the bandwidth.This tuning cutoff frequency method provides an efficient way to tailor the guided band and further tune the optical properties of PhCWs.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.61076057,61376059,91221202,61171023)the National Basic Research Program of China("973"Program)(Grant Nos.2012CB932701,2011CB933001)
文摘We describe a simple method to increase the conductivity of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS)film by exposure to ultraviolet(UV)light in vacuum.Up to four order of conductivity improvement(from 10 3to 50 S/cm)is achieved by irradiating PEDOT:PSS film with 254 nm ultraviolet(UV)light.Increased conductivity in UV treated PEDOT:PSS film is stable under ambient exposure.The mechanism for conductivity improvement is investigated by current-voltage measurement,atomic force microscopy,and absorption spectrum.Photo-cross-linking of PSS chains is determined as the reason for conductivity improvement.Our result demonstrates that UV treatment is capable of modifying the conductivity of PEDOT:PSS film independent of the process of film formation.
基金supported by the Ministry of Science and Technology of China (Grant No. 2007CB936204)the National Natural Science Foundation of China (Grant Nos. 61271050,61076057 and 61171023)
文摘In this paper,configuration parameters of the waveguide are altered independently or simultaneously to control the cutoff frequencies of the guided band.The independent control range of the upper and lower cutoff frequencies is 55.0% and 63.9% of the photonic band gap(PBG),respectively.The regulating range of the simultaneous tuning can be as large as 28.6% in terms of the PBG,or 240% in terms of the bandwidth.This tuning cutoff frequency method provides an efficient way to tailor the guided band and further tune the optical properties of PhCWs.
