In order to reduce shrinkage and improve the mechanical properties of dental composite resins, we designed a hybrid resin formulation containing a novel matrix resin, Bis S-GMA [bisphenol-Sbis（3-methacrylato-2-hydrox...In order to reduce shrinkage and improve the mechanical properties of dental composite resins, we designed a hybrid resin formulation containing a novel matrix resin, Bis S-GMA [bisphenol-Sbis（3-methacrylato-2-hydroxypropyl）ether], and epoxy modifi ed by a spiro-orthocarbonate（SOC） expanding monomer. Then, we tested the effects of an iodonium salt, diphenyliodonium hexafl uorphosphate（DPIHFP）, on the properties of the hybrid resin with seven different concentrations. The hybrid resin was polymerized by a ternary photo-initiator system. The volumetric shrinkage（VS）, degree of conversion（DC） and compressive strength（CS） were assessed using Acu Vol^TM, FTIR and a universal testing machine, respectively. The VS, DC and CS were improved with increasing DPIHFP concentration, but a high concentration of DPIHFP had a negative infl uence on the mechanical properties of the hybrid resin and offered no added improvement in the VS and DC. The best performance of a composite resin containing Bis S-GMA and SOC-modifi ed epoxy was achieved with 2wt% DPIHFP. The results also indicated that the resin containing Bis S-GMA was superior to that containing Bis-GMA in terms of VS, DC and CS.展开更多
基金Funded by the National Natural Science Foundation of China(No.50673065)
文摘In order to reduce shrinkage and improve the mechanical properties of dental composite resins, we designed a hybrid resin formulation containing a novel matrix resin, Bis S-GMA [bisphenol-Sbis（3-methacrylato-2-hydroxypropyl）ether], and epoxy modifi ed by a spiro-orthocarbonate（SOC） expanding monomer. Then, we tested the effects of an iodonium salt, diphenyliodonium hexafl uorphosphate（DPIHFP）, on the properties of the hybrid resin with seven different concentrations. The hybrid resin was polymerized by a ternary photo-initiator system. The volumetric shrinkage（VS）, degree of conversion（DC） and compressive strength（CS） were assessed using Acu Vol^TM, FTIR and a universal testing machine, respectively. The VS, DC and CS were improved with increasing DPIHFP concentration, but a high concentration of DPIHFP had a negative infl uence on the mechanical properties of the hybrid resin and offered no added improvement in the VS and DC. The best performance of a composite resin containing Bis S-GMA and SOC-modifi ed epoxy was achieved with 2wt% DPIHFP. The results also indicated that the resin containing Bis S-GMA was superior to that containing Bis-GMA in terms of VS, DC and CS.
