The desulfurization ability of refining slag with relative lower basicity (B) and Al2O3 content (B = 3.5-5.0; 20wt%-25wt% Al2O3) was studied. Firstly, the component activities and sulfide capacity (Cs) of the sl...The desulfurization ability of refining slag with relative lower basicity (B) and Al2O3 content (B = 3.5-5.0; 20wt%-25wt% Al2O3) was studied. Firstly, the component activities and sulfide capacity (Cs) of the slag were calculated. Then slag-metal equilibrium experiments were carried out to measure the equilibrium sulfur distribution (Ls). Based on the laboratorial experiments, slag composition was optimized for a better desulfurization ability, which was verified by industrial trials in a steel plant. The obtained results indicated that an MgO-saturated CaO-Al2O3-SiO2-MgO system with the basicity of about 3.5-5.0 and the Al2O3 content in the range of 20wt%-25wt% has high activity of CaO (αCaO), with no deterioration of Cs compared with conventional desulfurization slag. The measured Ls between high-strength low-alloyed (HSLA) steel and slag with a basicity of about 3.5 and an Al2O3 content of about 20wt% and between HSLA steel and slag with a basicity of about 5.0 and an Al2O3 content of about 25wt% is 350 and 275, respectively. The new slag with a basicity of about 3.5-5.0 and an Al2O3 content of about 20wt% has strong desulfurization ability. In particular, the key for high-efficiency desulfurization is to keep oxygen potential in the reaction system as low as possible, which was also verified by industrial trials.展开更多
Recently, large sized CaO-Alz 03 inclusions with low melting temperature have been the main reason for lowering mechanical properties of high strength low alloy (HSLA) steel plates. New philosophy, i.e. refining by ...Recently, large sized CaO-Alz 03 inclusions with low melting temperature have been the main reason for lowering mechanical properties of high strength low alloy (HSLA) steel plates. New philosophy, i.e. refining by top slag with relatively low basicity and Al2O3 content, was proposed to control such kind of inclusions. Firstly, the characteristics of refining slag, such as component activities and sulphide capacity (Cs) of CaO-Al2O3-SiO2-MgO slag, were studied through thermodynamic calculation. Then, slag-metal equilibrium experiments were carried out in laboratory to investigate the exact chemical composition of refining slag together with thermodynamic analysis. Finally, industrial trials were done to verify the desulphurization ability and inclusions control in steel refined by the new slag. Thermodynamic calculations indicated that the slags with basicity of 3.5 and Al2O3 content of 200/oo and basicity of 5.0 and Al2O3 content of 20 % or 25 % have high values of CaO activity, sulphide capacity and ratio of MgO activity to Al2O3 activity. Laboratory equilibrium experiments showed that the slag with basicity of about 4.5 and A12 03 content of about 20% is helpful for increasing the melting temperature of inclusions in steel. After introducing such kind of refining slag in industrial trials, the sulphur content in eight heats of steel is below 20 ×l0-6 , which meets the requirement of HSLA steel, and most inclusions distribute in relatively high melting zone (≥1773 K) of CaO- Al2O3-MgO(-SiO2) quasi-ternary diagram. New philosophy of top refining slag is feasible to control low melting point inclusions of CaO-Al2O3 system in HSLA steel.展开更多
A 14-year-old male visited the Guangzhou Medical University First Affiliated Hospital of with a complaint of a 2-year history of progressive exertional dyspnea and fingertips cyanosis. Physical examination revealed re...A 14-year-old male visited the Guangzhou Medical University First Affiliated Hospital of with a complaint of a 2-year history of progressive exertional dyspnea and fingertips cyanosis. Physical examination revealed remarkable desaturation measured by pulse oximetry (80% at rest) and marked cyanosis of lips.展开更多
基金financially supported by the National Basic Research Program of China (No. 2010CB630806)the State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing (No. 41603015)
文摘The desulfurization ability of refining slag with relative lower basicity (B) and Al2O3 content (B = 3.5-5.0; 20wt%-25wt% Al2O3) was studied. Firstly, the component activities and sulfide capacity (Cs) of the slag were calculated. Then slag-metal equilibrium experiments were carried out to measure the equilibrium sulfur distribution (Ls). Based on the laboratorial experiments, slag composition was optimized for a better desulfurization ability, which was verified by industrial trials in a steel plant. The obtained results indicated that an MgO-saturated CaO-Al2O3-SiO2-MgO system with the basicity of about 3.5-5.0 and the Al2O3 content in the range of 20wt%-25wt% has high activity of CaO (αCaO), with no deterioration of Cs compared with conventional desulfurization slag. The measured Ls between high-strength low-alloyed (HSLA) steel and slag with a basicity of about 3.5 and an Al2O3 content of about 20wt% and between HSLA steel and slag with a basicity of about 5.0 and an Al2O3 content of about 25wt% is 350 and 275, respectively. The new slag with a basicity of about 3.5-5.0 and an Al2O3 content of about 20wt% has strong desulfurization ability. In particular, the key for high-efficiency desulfurization is to keep oxygen potential in the reaction system as low as possible, which was also verified by industrial trials.
基金Item Sponsored by National Basic Research Program of China(2010CB630806)National Natural Science Foundation of CHina(51404020)State Key Laboratory of Advanced Metallurgy(USTB)of China(41603015)
文摘Recently, large sized CaO-Alz 03 inclusions with low melting temperature have been the main reason for lowering mechanical properties of high strength low alloy (HSLA) steel plates. New philosophy, i.e. refining by top slag with relatively low basicity and Al2O3 content, was proposed to control such kind of inclusions. Firstly, the characteristics of refining slag, such as component activities and sulphide capacity (Cs) of CaO-Al2O3-SiO2-MgO slag, were studied through thermodynamic calculation. Then, slag-metal equilibrium experiments were carried out in laboratory to investigate the exact chemical composition of refining slag together with thermodynamic analysis. Finally, industrial trials were done to verify the desulphurization ability and inclusions control in steel refined by the new slag. Thermodynamic calculations indicated that the slags with basicity of 3.5 and Al2O3 content of 200/oo and basicity of 5.0 and Al2O3 content of 20 % or 25 % have high values of CaO activity, sulphide capacity and ratio of MgO activity to Al2O3 activity. Laboratory equilibrium experiments showed that the slag with basicity of about 4.5 and A12 03 content of about 20% is helpful for increasing the melting temperature of inclusions in steel. After introducing such kind of refining slag in industrial trials, the sulphur content in eight heats of steel is below 20 ×l0-6 , which meets the requirement of HSLA steel, and most inclusions distribute in relatively high melting zone (≥1773 K) of CaO- Al2O3-MgO(-SiO2) quasi-ternary diagram. New philosophy of top refining slag is feasible to control low melting point inclusions of CaO-Al2O3 system in HSLA steel.
文摘A 14-year-old male visited the Guangzhou Medical University First Affiliated Hospital of with a complaint of a 2-year history of progressive exertional dyspnea and fingertips cyanosis. Physical examination revealed remarkable desaturation measured by pulse oximetry (80% at rest) and marked cyanosis of lips.