利用高效液相色谱-串联质谱法测定鸡肉中硝基咪唑类药物残留。采用乙腈(含体积分数0.2%甲酸)进行样品提取,然后经过Oasis Prime HLB固相萃取小柱净化处理,目标物在液相系统进行洗脱分离,并使用质谱电喷雾电离源正离子扫描模式进行检测...利用高效液相色谱-串联质谱法测定鸡肉中硝基咪唑类药物残留。采用乙腈(含体积分数0.2%甲酸)进行样品提取,然后经过Oasis Prime HLB固相萃取小柱净化处理,目标物在液相系统进行洗脱分离,并使用质谱电喷雾电离源正离子扫描模式进行检测。结果表明:在优化所得色谱流动相条件下,4种硝基咪唑类药物在一定质量浓度范围内(1.0~15.0 ng/mL)线性关系良好,相关系数≥0.991;在0.25、0.50、2.50μg/kg 3个水平的加标实验中,回收率分别为79.4%~105.8%、88.4%~104.6%、88.6%~101.3%,相应的标准偏差分别为≤11.9%、≤4.8%、≤2.8%,表明该方法准确度和精密度良好,能够满足日常快速检验的需求;4种硝基咪唑类药物均有不同程度的基质效应,其中洛硝达唑的基质效应最明显,且同一种物质加标水平越低,基质效应越明显。展开更多
Mn-Si-B system medium carbon hardfacing electrode with good wear resistance has been studied. The electrode uses mild steel type H08A as core rod which is easy to get, and alloy elements are supplied from the coated f...Mn-Si-B system medium carbon hardfacing electrode with good wear resistance has been studied. The electrode uses mild steel type H08A as core rod which is easy to get, and alloy elements are supplied from the coated flux.Chemical composition analysis, macrohardness measurement, microstructure observation and abrasion test have been applied to studying the deposited metal samples, and quantitative analysis and phase structure analysis have been applied to existing forms of boron in deposited metal as well. The mechanism of effect of boron on hardness and abrasion resistance of deposited metal has been explored.展开更多
文摘利用高效液相色谱-串联质谱法测定鸡肉中硝基咪唑类药物残留。采用乙腈(含体积分数0.2%甲酸)进行样品提取,然后经过Oasis Prime HLB固相萃取小柱净化处理,目标物在液相系统进行洗脱分离,并使用质谱电喷雾电离源正离子扫描模式进行检测。结果表明:在优化所得色谱流动相条件下,4种硝基咪唑类药物在一定质量浓度范围内(1.0~15.0 ng/mL)线性关系良好,相关系数≥0.991;在0.25、0.50、2.50μg/kg 3个水平的加标实验中,回收率分别为79.4%~105.8%、88.4%~104.6%、88.6%~101.3%,相应的标准偏差分别为≤11.9%、≤4.8%、≤2.8%,表明该方法准确度和精密度良好,能够满足日常快速检验的需求;4种硝基咪唑类药物均有不同程度的基质效应,其中洛硝达唑的基质效应最明显,且同一种物质加标水平越低,基质效应越明显。
文摘Mn-Si-B system medium carbon hardfacing electrode with good wear resistance has been studied. The electrode uses mild steel type H08A as core rod which is easy to get, and alloy elements are supplied from the coated flux.Chemical composition analysis, macrohardness measurement, microstructure observation and abrasion test have been applied to studying the deposited metal samples, and quantitative analysis and phase structure analysis have been applied to existing forms of boron in deposited metal as well. The mechanism of effect of boron on hardness and abrasion resistance of deposited metal has been explored.