将二氧化碳电化学还原为一氧化碳是一种实现碳循环和利用的有效途径。为了利用大量过剩的二氧化碳资源,本文制备了一种简单合成的电催化剂,以生物质壳聚糖为前体制备了含氮多孔碳基底,嵌入均匀分布的非贵金属铜纳米颗粒进行修饰,通过调...将二氧化碳电化学还原为一氧化碳是一种实现碳循环和利用的有效途径。为了利用大量过剩的二氧化碳资源,本文制备了一种简单合成的电催化剂,以生物质壳聚糖为前体制备了含氮多孔碳基底,嵌入均匀分布的非贵金属铜纳米颗粒进行修饰,通过调节铜的负载量,达到充分利用铜金属的活性,从而在电化学二氧化碳还原过程中实现了优异的一氧化碳法拉第效率和选择性。在-0.6V vs. RHE时下,一氧化碳的最大法拉第效率(FE)为78%,并且没有其他有效产物的生成,从而一氧化碳的选择性达到了100%,电流密度为1.9mA/cm2。并且在0.1mol/L KHCO3水溶液中连续电解13h以上,一氧化碳的法拉第效率和选择性基本保持不变,制备的电极材料具有优异的稳定性。展开更多
Since launching the reform and opening policy, and particularly since the mid-1990s with accelerating industrialization processes and further policy changes, the electronics and mechanical industry in China has made h...Since launching the reform and opening policy, and particularly since the mid-1990s with accelerating industrialization processes and further policy changes, the electronics and mechanical industry in China has made huge strides in production and tbreign trade value, now accounting for approximately half of total exports from China and becoming a pillar industry of China＇s foreign trade.展开更多
文摘将二氧化碳电化学还原为一氧化碳是一种实现碳循环和利用的有效途径。为了利用大量过剩的二氧化碳资源,本文制备了一种简单合成的电催化剂,以生物质壳聚糖为前体制备了含氮多孔碳基底,嵌入均匀分布的非贵金属铜纳米颗粒进行修饰,通过调节铜的负载量,达到充分利用铜金属的活性,从而在电化学二氧化碳还原过程中实现了优异的一氧化碳法拉第效率和选择性。在-0.6V vs. RHE时下,一氧化碳的最大法拉第效率(FE)为78%,并且没有其他有效产物的生成,从而一氧化碳的选择性达到了100%,电流密度为1.9mA/cm2。并且在0.1mol/L KHCO3水溶液中连续电解13h以上,一氧化碳的法拉第效率和选择性基本保持不变,制备的电极材料具有优异的稳定性。
文摘Since launching the reform and opening policy, and particularly since the mid-1990s with accelerating industrialization processes and further policy changes, the electronics and mechanical industry in China has made huge strides in production and tbreign trade value, now accounting for approximately half of total exports from China and becoming a pillar industry of China＇s foreign trade.
