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聚醚阴离子表面活性剂的制备及其在乳液聚合中的应用
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作者 郭泽华 张万斌 +5 位作者 王少武 唐明旋 李慧 孙棋 张鑫 张光华 《陕西科技大学学报》 北大核心 2023年第6期83-88,95,共7页
利用阴离子开环聚合(AROP)和巯基-烯(Thiol-ene)点击反应相结合的策略制备了一种聚醚阴离子表面活性剂.首先,以烯丙基缩水甘油醚(AGE)为单体,叔丁醇钾(t-BuOK)为引发剂,通过AROP制备聚烯丙基缩水甘油醚(PAGE),之后,以PAGE为不饱和聚醚骨... 利用阴离子开环聚合(AROP)和巯基-烯(Thiol-ene)点击反应相结合的策略制备了一种聚醚阴离子表面活性剂.首先,以烯丙基缩水甘油醚(AGE)为单体,叔丁醇钾(t-BuOK)为引发剂,通过AROP制备聚烯丙基缩水甘油醚(PAGE),之后,以PAGE为不饱和聚醚骨架,利用Thiol-ene点击反应依次将亲水基磺酸基及疏水基丁烷基团引入PAGE的侧链,形成两亲性结构.红外光谱(FT-IR)和核磁共振波谱(NMR)表征验证成功制备了系列中间产物及目标产物.表面张力的测试证明此类聚醚阴离子表面活性剂(缩写为PAGE anionic)可有效降低溶液的表面张力,其CMC值为:0.017 mg/mL,在此浓度下,溶液的表面张力可低至41.67 mN/m.接触角测试显示PAGE anionic对油性表面具有较好的润湿性.溶液电导率测试显示PAGE anionic的Krafft点低于0℃.将PAGE anionic应用于苯丙乳液的制备,激光粒度仪和透射电镜分析显示,成功获得稳定均匀的乳液,其平均粒径Dz=164 nm,PDI=0.038,乳液体现出较好的耐盐性. 展开更多
关键词 聚醚 巯基-烯点击反应 阴离子表面活性剂 乳化剂
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抗水性聚丙烯酸酯类土壤固化剂的制备及性能 被引量:8
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作者 邢世强 董勋 +5 位作者 张光华 张万斌 张妍 王少武 王静 解利荣 《应用化工》 CAS CSCD 北大核心 2022年第10期2875-2879,共5页
以丙烯酸丁酯(BA)和丙烯酸(AA)为原料,以十二烷基硫酸钠(SDS)和烷基酚聚氧乙烯醚(OP-10)为复合乳化剂,合成一种纯丙类乳液土壤固化剂PAA;为了提高其抗水性,聚合中引入苯乙烯(St)单体,制得聚丙烯酸酯类土壤固化剂PAAS,合成工艺均采用预... 以丙烯酸丁酯(BA)和丙烯酸(AA)为原料,以十二烷基硫酸钠(SDS)和烷基酚聚氧乙烯醚(OP-10)为复合乳化剂,合成一种纯丙类乳液土壤固化剂PAA;为了提高其抗水性,聚合中引入苯乙烯(St)单体,制得聚丙烯酸酯类土壤固化剂PAAS,合成工艺均采用预乳化半连续种子乳液聚合法;采用FTIR对其结构进行表征,同时对合成乳液的粒径进行测试;对固化土/水表面接触角进行测试;然后研究在不同固化剂掺量及养护龄期条件下,土壤固化剂对重塑土无侧限抗压强度的影响。结果表明,合成的乳液粒径分布均匀,分散性好;未掺固化剂所压土片与水接触直接润湿,而掺入固化剂所压土片接触角明显增强,且掺入固化剂PAAS使得固化土/水界面瞬间接触角增长至99.78°,其疏水性较强;随固化剂掺量的增加或养护龄期的延长,土壤固化剂对重塑土强度有明显增强效果;当养护龄期为3 d,PAAS固化剂掺入量为0.08%,其无侧限抗压强度增长至265.8 kPa;在养护龄期为3 d,固化剂掺量为0.08%时,改性土试样抗压强度相对空白样而言相对增量最大,且PAAS改性土强度相对增量达1.08倍。 展开更多
关键词 聚丙烯酸酯 乳液聚合 土壤固化剂 无侧限抗压强度 最佳掺量 养护龄期
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肾孤立性纤维瘤1例 被引量:5
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作者 李唐 王绍武 +3 位作者 边杰 黄杰 孙卫兵 王齐敏 《中国临床医学影像杂志》 CAS 2018年第4期301-302,共2页
病例男,26岁,外院体检超声发现左肾肿块1周后就诊本院。临床查体均呈阴性。本院超声检查:左肾中部一低回声光团,大小约34 mm×26 mm,向外凸,后方回声衰减,考虑肾癌。CT平扫和增强扫描:左肾中部肾实质内见等及稍高密度实性肿块,向... 病例男,26岁,外院体检超声发现左肾肿块1周后就诊本院。临床查体均呈阴性。本院超声检查:左肾中部一低回声光团,大小约34 mm×26 mm,向外凸,后方回声衰减,考虑肾癌。CT平扫和增强扫描:左肾中部肾实质内见等及稍高密度实性肿块,向肾轮廓外及肾盂突出,最大层面约27 mm×39 mm,病变内未见坏死及囊变,未见明确脂肪密度, 展开更多
关键词 肾肿瘤 纤维瘤 体层摄影术 X线计算机
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大腿肌内颗粒细胞瘤1例 被引量:3
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作者 张凯 张丽娜 +2 位作者 王绍武 宋清伟 时畅 《中国临床医学影像杂志》 CAS 2019年第6期455-456,共2页
病例女,44岁,4月前偶然发现左大腿肿物,自觉肿物逐渐增大而就诊。体检:左大腿中段内侧可触及肿块,大小约5 cm×5 cm,实性,活动度好,表面皮肤无红肿破溃,左下肢感觉和活动无异常。左股骨正侧位X线片未见确切异常。超声检查示左大腿... 病例女,44岁,4月前偶然发现左大腿肿物,自觉肿物逐渐增大而就诊。体检:左大腿中段内侧可触及肿块,大小约5 cm×5 cm,实性,活动度好,表面皮肤无红肿破溃,左下肢感觉和活动无异常。左股骨正侧位X线片未见确切异常。超声检查示左大腿中段内侧见一低回声区,大小约3.1 cm×2.2 cm,边界清楚。彩色多普勒超声示肿块周边见血流信号。 展开更多
关键词 颗粒细胞瘤 磁共振成像
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医学模拟技术在医学生临床实验教学中的应用研究 被引量:6
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作者 王乃琪 严艳 +5 位作者 李靖年 袁亮 曹丽华 高振明 宋贵军 王绍武 《高校医学教学研究(电子版)》 2018年第6期7-11,共5页
随着医学模拟技术逐渐被广泛使用,大连医科大学附属第二医院积极探索实践,9年来开展医学模拟技术的研究,全面用于医学人才的培育。连续多年对临床医学专业学生开展全员培训,组织医学生全员参加临床技能竞赛并参加全国高等医学院校大学... 随着医学模拟技术逐渐被广泛使用,大连医科大学附属第二医院积极探索实践,9年来开展医学模拟技术的研究,全面用于医学人才的培育。连续多年对临床医学专业学生开展全员培训,组织医学生全员参加临床技能竞赛并参加全国高等医学院校大学生临床技能竞赛,取得了优异成绩。同时总结出了建立医学本科生临床技能培训体系、重视师资梯队建设、将优秀选手留院转型培养为青年骨干教师等方面的成功经验。 展开更多
关键词 医学模拟技术 模拟医学教育 临床技能
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Debates on the Causes of Global Warming 被引量:1
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作者 HUANG Jian-Bin wang shao-wu +2 位作者 LUO Yong ZHAO Zong-Ci WEN Xin-Yu 《Advances in Climate Change Research》 SCIE 2012年第1期38-44,共7页
The controversy between the IPCC and Non-governmental IPCC(NIPCC) on the attribution of global warming are reviewed.IPCC holds that today's global warming is mainly due to anthropogenic activities rather than natu... The controversy between the IPCC and Non-governmental IPCC(NIPCC) on the attribution of global warming are reviewed.IPCC holds that today's global warming is mainly due to anthropogenic activities rather than natural variability,which is emphasized by NIPCC.The surface temperature observations since the mid-20th century support the hypothesis of anthropogenic impact,but for the last one hundred years or so,natural forcings such as solar activity, volcanic eruptions and thermohaline circulation variations also have had great influences on the Earth's climate,especially on inter-decadal timescales.In addition,evidence suggests that the Medieval Warm Period(MWP) and Little Ice Age (LIA) are closely associated with the solar activity over the past 1 thousand years.Over the past 10 thousand years, the North Atlantic cold events and solar activity are closely correlated.Nevertheless,the physical mechanisms of the solar-climate variability and interrelation are not well understood,yet.Notably,a prevailing view recently indicates that galactic cosmic rays may result in climatic cooling through modulating global low cloud cover.However,its process and mechanism need to be further investigated. 展开更多
关键词 global warming CAUSES greenhouse effect solar activity galactic cosmic rays
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Synthesis, Crystal Structure and Catalytic Activity of a Dinuclear Aluminum Alkyl Complex 被引量:1
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作者 WEI Yun ZHOU Shuang-Liu wang shao-wu 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2016年第2期307-312,共6页
Treatment of indolyl-3-aldimines(3-~tBuN=CH)C8H5NH with AlMe3 afforded the deprotonated indolyl aluminum complex cis-[(μ-η~1:η~1-3-~tBuN=CH)C8H5NAlMe2]2,and its crystal structure was determined by X-ray single... Treatment of indolyl-3-aldimines(3-~tBuN=CH)C8H5NH with AlMe3 afforded the deprotonated indolyl aluminum complex cis-[(μ-η~1:η~1-3-~tBuN=CH)C8H5NAlMe2]2,and its crystal structure was determined by X-ray single-crystal diffraction.The crystal belongs to the orthorhombic system,space group P21212 with a = 14.590(9),b = 15.860(2),c = 13.266(8) A,μ=0.118 mm^(-1),Mr = 512.64,V= 3069.5(3) A^3,Z = 4,Dc= 1.109 g/cm^3,F(000) = 1104,R= 0.0451 and wR = 0.0937 for 4978 observed reflections with I 2σ(I).In addition,the title compound exhibited a high catalytic activity toward the addition of amines to carbodiimide to form guanidines. 展开更多
关键词 INDOLE organoaluminum crystal structure guanylation reaction
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The Science of Global Warming
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作者 HUANG Jian-Bin wang shao-wu +2 位作者 LUO Yong ZHAO Zong-Ci WEN Xin-Yu 《Advances in Climate Change Research》 SCIE 2012年第3期174-178,共5页
Global warming is unequivocal, as is manifested in three internationally known global temperature records with the global average temperature rising at a rate of 0.70-0.75℃ per 100 years during 1910-2009 [Wen et al.,... Global warming is unequivocal, as is manifested in three internationally known global temperature records with the global average temperature rising at a rate of 0.70-0.75℃ per 100 years during 1910-2009 [Wen et al., 2011]. In other words, the earth has warmed more than 0.8℃ since the Industrial Revolution. If it is true that 2℃ above pre-industrial level is a threshold of climate "safety", we will have to confront a serious situation where less than 1.2℃ warmins is oermissible in the future [Liu et al.. 2011]. 展开更多
关键词 全球变暖 科学 气温上升 气温记录 工业革命 温家宝 工业化 地球
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Uncertainties in Global Warming Projection
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作者 WEN Xin-Yu wang shao-wu +2 位作者 LUO Yong ZHAO Zong-Ci HUANG Jian-Bin 《Advances in Climate Change Research》 SCIE 2012年第4期229-232,共4页
According to the IPCC Fourth Assessment Report (AR4) [IPCC, 2007], the global mean surface temperature in 2100 is projected to be 1.1-6.4℃ higher than the 1980 1999 mean state, with the best estimation of increase ... According to the IPCC Fourth Assessment Report (AR4) [IPCC, 2007], the global mean surface temperature in 2100 is projected to be 1.1-6.4℃ higher than the 1980 1999 mean state, with the best estimation of increase at 1.8-4.0℃. It should be noted that this is the projected range of increase rather than the so-called uncertainties in global warming projection. Specifically, 1.1℃ and 1.8℃ are the lower limit and the best estimation for the B1 emissions scenario (the low emissions scenario), respectively; while 4.0℃ and 6.4℃ are the corresponding upper limit and the best estimation for the A1F1 emissions scenario (the high emissions scenario). Therefore, 展开更多
关键词 不确定性 全球变暖 政府间气候变化专门委员会 投影 最佳估计 低排放 评估报告 地表温度
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Equilibrium Climate Sensitivity
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作者 WEN Xin-Yu wang shao-wu +2 位作者 LUO Yong ZHAO Zong-Ci HUANG Jian-Bin 《Advances in Climate Change Research》 SCIE 2013年第1期69-72,共4页
Equilibrium climate sensitivity (ECS) is usually defined as the global mean equilibrium temperature response to a doubling CO2 concentration of its preindustrial level in the atmosphere[Hegerl et al., 2007;Meehl et ... Equilibrium climate sensitivity (ECS) is usually defined as the global mean equilibrium temperature response to a doubling CO2 concentration of its preindustrial level in the atmosphere[Hegerl et al., 2007;Meehl et al., 2007]. 展开更多
关键词 气候敏感性 平衡温度 CO2浓度倍增 ECS 工业化 大气
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Crystal and Molecular Structure of(η~5-C_5H_5)_2Yb(NC_4H_4)(OC_4H_8)
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作者 wang shao-wu Yu Yong-Fei +2 位作者 Hu Ji-ping Ye Zhong-Wen(Institute of Organic Chemistry,Anhui Normal University,Wuhu,Anhui 241000,China) Wei Ge-Cheng Jin Zhong-Sheng(Changchun Institute of Applied Chemistry,Academia Sinica,Changchun,Jilin 130022,China) 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 1994年第5期346-349,共4页
The complex(C_5H_5)2 Yb(NC4H4)(OC_4H_8) crystallizes in orthorhombic system with space group Pnma and a=15.552(4),b=12.491(3),c=8. 711(3),V=1692. 2(7),Z=4 and Dc=1.733 g/cm3. Crystal study has shown that the molecule ... The complex(C_5H_5)2 Yb(NC4H4)(OC_4H_8) crystallizes in orthorhombic system with space group Pnma and a=15.552(4),b=12.491(3),c=8. 711(3),V=1692. 2(7),Z=4 and Dc=1.733 g/cm3. Crystal study has shown that the molecule has crystallographic mirror symmetry.The Yb(Ⅲ) has a distorted tetrahedral coordination geometry. 展开更多
关键词 crystal structure LANTHANIDE pyrrolyl complex
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Greenhouse Production Technical Procedure for Pollution-free Food
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作者 wang shao-wu LI Qing 《Asian Agricultural Research》 2012年第9期64-66,共3页
This procedure specifies production area environment, production technology, prevention and control of plant diseases and insect pests, and production files of pollution-free foods by taking tomato as an example. This... This procedure specifies production area environment, production technology, prevention and control of plant diseases and insect pests, and production files of pollution-free foods by taking tomato as an example. This procedure is applicable to greenhouse production of pollution-free food in Shandong Province. 展开更多
关键词 POLLUTION-FREE FOOD TOMATO TECHNICAL PROCEDURE
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