为建立雷公藤种植过程中常用农药的残留含量检测方法,采用快速样品前处理结合超高效液相色谱-串联质谱法(quick,easy,cheap,effective,rugged and safe/ultra performance liquid chromatography tandem mass spectrometry,QuEChERS/UPL...为建立雷公藤种植过程中常用农药的残留含量检测方法,采用快速样品前处理结合超高效液相色谱-串联质谱法(quick,easy,cheap,effective,rugged and safe/ultra performance liquid chromatography tandem mass spectrometry,QuEChERS/UPLC-MS/MS)测定雷公藤及根际土壤中辛硫磷、氯氰菊酯和乙基多杀菌素的含量。样品中加入适量的水浸润后用乙腈超声提取,N-丙基乙二胺(PSA)吸附净化,利用优化后的UPLC-MS/MS方法进行检测,基质外标法定量。结果显示,3种农药在根样基质中的检出限(LOD)为0.001~0.714μg/kg,定量限(LOQ)为0.002~2.380μg/kg;在土壤基质中的检出限(LOD)为0.002~0.810μg/kg,定量限(LOQ)为0.006~2.410μg/kg。线性关系、回收率和相对标准偏差均符合农药残留检测的相关规定。结果表明,该方法能满足雷公藤及根际土壤中3种农药残留含量的快速检测要求。展开更多
1 Introduction There exist calcium and sulfate ions outside sodium chloride in solution mining for calcium sulfate brine.The calcium and sulfate ions not only affect the purity of the vacuum salt products,but also inc...1 Introduction There exist calcium and sulfate ions outside sodium chloride in solution mining for calcium sulfate brine.The calcium and sulfate ions not only affect the purity of the vacuum salt products,but also increase the scaling of vacuum evaporation tanks and brine reusing pipes.Additives have certain impacts on the crystallization dynamics(Randolph et al.,1971).The crystallization展开更多
1 Introduction The main production of Yabulai salt lake was original salt and recycled salt many years ago.After decade’s production,the sale lake resource is more and more deficient.Glauber’s salt and magnesium sal...1 Introduction The main production of Yabulai salt lake was original salt and recycled salt many years ago.After decade’s production,the sale lake resource is more and more deficient.Glauber’s salt and magnesium salt are concentrated in brine now.It could affect the quality of the salt.In recent years,research had done much work to展开更多
1 Introduction Calcium sulfate deposition is one of the most important and serious problems faced by heat transfer equipment during operation(Pavlos et al.,1999;Liu et al.,1996).The crystallization of calcium sulfate ...1 Introduction Calcium sulfate deposition is one of the most important and serious problems faced by heat transfer equipment during operation(Pavlos et al.,1999;Liu et al.,1996).The crystallization of calcium sulfate is known as a major展开更多
As an excellent chemical fertilizer,Potassium Sulphate(K2SO4)could provide both potassium and sulfur elements for crops.However,it is well known that potassium resource is very poor in China.To understand the Crystall...As an excellent chemical fertilizer,Potassium Sulphate(K2SO4)could provide both potassium and sulfur elements for crops.However,it is well known that potassium resource is very poor in China.To understand the Crystallization Kinetics(CK)of K2SO4could be conducive to utilize the limited potassium resource,promote the yield and purity of K2SO4.In this study saturated solution of potassium sulphate was prepared according to the phase diagram of Mg2+、展开更多
1 Introduction Tibet has nurmerous salt lakes.Laguocuo is one of the salt lakes,which is located to the sorthern of Ali Plateau,31°59′02″N-32°04′08″N,84°02′03″E-84°12′03″E.Its lake water is...1 Introduction Tibet has nurmerous salt lakes.Laguocuo is one of the salt lakes,which is located to the sorthern of Ali Plateau,31°59′02″N-32°04′08″N,84°02′03″E-84°12′03″E.Its lake water is rich in potassium,magnesium,lithium,boron,rubidium,cesium and other resources.The study of展开更多
1 Introduction Snow salt is one of the multi-salt with highly added value,in named for its snowflakes structure appearance.In the present situation,the stacking density gap between different commercial snow salt is bi...1 Introduction Snow salt is one of the multi-salt with highly added value,in named for its snowflakes structure appearance.In the present situation,the stacking density gap between different commercial snow salt is big,mainly ranged from700 kg/m3to 800 kg/m3.The competition in the market展开更多
1 Introduction Bromine,an important industrial raw material,was widely applied in industry,agriculture and medicine.At present,many methods of producing bromine have been found.The air blowing method and steam distill...1 Introduction Bromine,an important industrial raw material,was widely applied in industry,agriculture and medicine.At present,many methods of producing bromine have been found.The air blowing method and steam distillation展开更多
As a natural mineral,Potash Magnesium Sulphate fertilizer has a quite high nutrient utilization rate without affecting soil p H in long time running related to Potassium Sulphate.And to displace Potassium Sulphate wit...As a natural mineral,Potash Magnesium Sulphate fertilizer has a quite high nutrient utilization rate without affecting soil p H in long time running related to Potassium Sulphate.And to displace Potassium Sulphate with Potash展开更多
文摘为建立雷公藤种植过程中常用农药的残留含量检测方法,采用快速样品前处理结合超高效液相色谱-串联质谱法(quick,easy,cheap,effective,rugged and safe/ultra performance liquid chromatography tandem mass spectrometry,QuEChERS/UPLC-MS/MS)测定雷公藤及根际土壤中辛硫磷、氯氰菊酯和乙基多杀菌素的含量。样品中加入适量的水浸润后用乙腈超声提取,N-丙基乙二胺(PSA)吸附净化,利用优化后的UPLC-MS/MS方法进行检测,基质外标法定量。结果显示,3种农药在根样基质中的检出限(LOD)为0.001~0.714μg/kg,定量限(LOQ)为0.002~2.380μg/kg;在土壤基质中的检出限(LOD)为0.002~0.810μg/kg,定量限(LOQ)为0.006~2.410μg/kg。线性关系、回收率和相对标准偏差均符合农药残留检测的相关规定。结果表明,该方法能满足雷公藤及根际土壤中3种农药残留含量的快速检测要求。
基金financial support of National Nature Science Foundation (21376178)TIDA giant growth plan (2011-XJR13020)+3 种基金Tianjin Science and technology support program (12ZCDZSF06900)Tianjin University of Science and Technology fund for scientific research (20120119)Tianjin education commission program (20130509)Research fund for the doctoral program of higher education of China (20131208120001)
文摘1 Introduction There exist calcium and sulfate ions outside sodium chloride in solution mining for calcium sulfate brine.The calcium and sulfate ions not only affect the purity of the vacuum salt products,but also increase the scaling of vacuum evaporation tanks and brine reusing pipes.Additives have certain impacts on the crystallization dynamics(Randolph et al.,1971).The crystallization
基金financial support of National Nature Science Foundation (21376178)TIDA giant growth plan (2011-XJR13020)+3 种基金Tianjin Science and technology support program (12ZCDZSF06900)Tianjin University of Science and Technology fund for scientific research (20120119)Tianjin education commission program (20130509)Research fund for the doctoral program of higher education of China (20131208120001)
文摘1 Introduction The main production of Yabulai salt lake was original salt and recycled salt many years ago.After decade’s production,the sale lake resource is more and more deficient.Glauber’s salt and magnesium salt are concentrated in brine now.It could affect the quality of the salt.In recent years,research had done much work to
基金financial support of National Nature Science Foundation (21376178)TIDA giant growth plan (2011-XJR13020)+3 种基金Tianjin Science and technology support program (12ZCDZSF06900)Tianjin University of Science and Technology fund for scientific research (20120119)Tianjin education commission program (20130509)Research fund for the doctoral program of higher education of China(20131208120001)
文摘1 Introduction Calcium sulfate deposition is one of the most important and serious problems faced by heat transfer equipment during operation(Pavlos et al.,1999;Liu et al.,1996).The crystallization of calcium sulfate is known as a major
基金financial support of National Nature Science Foundation (21376178)TIDA giant growth plan (2011-XJR13020)+3 种基金Tianjin Science and technology support program (12ZCDZSF06900)Tianjin University of Science and Technology fund for scientific research (20120119)Tianjin education commission program (20130509)Research fund for the doctoral program of higher education of China(20131208120001)
文摘As an excellent chemical fertilizer,Potassium Sulphate(K2SO4)could provide both potassium and sulfur elements for crops.However,it is well known that potassium resource is very poor in China.To understand the Crystallization Kinetics(CK)of K2SO4could be conducive to utilize the limited potassium resource,promote the yield and purity of K2SO4.In this study saturated solution of potassium sulphate was prepared according to the phase diagram of Mg2+、
文摘1 Introduction Tibet has nurmerous salt lakes.Laguocuo is one of the salt lakes,which is located to the sorthern of Ali Plateau,31°59′02″N-32°04′08″N,84°02′03″E-84°12′03″E.Its lake water is rich in potassium,magnesium,lithium,boron,rubidium,cesium and other resources.The study of
基金supported by a grant from the Tianjin Binhai New Area (TBNA) Science & Technology commission project, and grant No. 1400050006
文摘1 Introduction Snow salt is one of the multi-salt with highly added value,in named for its snowflakes structure appearance.In the present situation,the stacking density gap between different commercial snow salt is big,mainly ranged from700 kg/m3to 800 kg/m3.The competition in the market
基金financial support of National Nature Science Foundation (21376178)TIDA giant growth plan (2011-XJR13020)+3 种基金Tianjin Science and technology support program (12ZCDZSF06900)Tianjin University of Science and Technology fund for scientific research (20120119)Tianjin education commission program (20130509)Research fund for the doctoral program of higher education of China(20131208120001)
文摘1 Introduction Bromine,an important industrial raw material,was widely applied in industry,agriculture and medicine.At present,many methods of producing bromine have been found.The air blowing method and steam distillation
基金financial support of National Nature Science Foundation (21376178)TIDA giant growth plan (2011-XJR13020)+3 种基金Tianjin Science and technology support program (12ZCDZSF06900)Tianjin University of Science and Technology fund for scientific research (20120119)Tianjin education commission program (20130509)Research fund for the doctoral program of higher education of China(20131208120001)
文摘As a natural mineral,Potash Magnesium Sulphate fertilizer has a quite high nutrient utilization rate without affecting soil p H in long time running related to Potassium Sulphate.And to displace Potassium Sulphate with Potash