The effect of Chemical Mechanical Modification (CMM) and dispersants on the ζ potential of nanodiamond particles in aqueous system and the influence of the ultrasonic or shearing techniques on its size distribution w...The effect of Chemical Mechanical Modification (CMM) and dispersants on the ζ potential of nanodiamond particles in aqueous system and the influence of the ultrasonic or shearing techniques on its size distribution were studied CMM and the addition of dispersants AD 2 and AD 8 improve the stability of its suspension With ultrasonic time prolonged, the mean average size of nanodiamond decreases, while with the prolongation of shearing time, its mean size decreases first, then increases a little In the speed range used, the mean size decreases with the rising speed If the whole ultrasonic time kept constant, it is better to add the dispersants before展开更多
Well-dispersed nanodiamond(ND) aqueous suspensions in both acidic and alkaline environments is prepared by mechanochemical treatment. All the ND particles in the suspensions are smaller than 100nm in dimension with a ...Well-dispersed nanodiamond(ND) aqueous suspensions in both acidic and alkaline environments is prepared by mechanochemical treatment. All the ND particles in the suspensions are smaller than 100nm in dimension with a narrow size distribution, and no destabilization phenomena were detected in a duration of more than one year. Stable dispersion of ND in the media may attributed to the strong electrostatic repulsion between particles because of the adsorption of dispersants, while mechanical forces may strengthen this adsorption reaction. Good adaptability and applicability of the suspensions to the change of ND concentration and surrounding temperature are observed, and improved performances of ND diamonds are obtained when used in ultrafine polishing and composite plating.展开更多
文摘The effect of Chemical Mechanical Modification (CMM) and dispersants on the ζ potential of nanodiamond particles in aqueous system and the influence of the ultrasonic or shearing techniques on its size distribution were studied CMM and the addition of dispersants AD 2 and AD 8 improve the stability of its suspension With ultrasonic time prolonged, the mean average size of nanodiamond decreases, while with the prolongation of shearing time, its mean size decreases first, then increases a little In the speed range used, the mean size decreases with the rising speed If the whole ultrasonic time kept constant, it is better to add the dispersants before
文摘Well-dispersed nanodiamond(ND) aqueous suspensions in both acidic and alkaline environments is prepared by mechanochemical treatment. All the ND particles in the suspensions are smaller than 100nm in dimension with a narrow size distribution, and no destabilization phenomena were detected in a duration of more than one year. Stable dispersion of ND in the media may attributed to the strong electrostatic repulsion between particles because of the adsorption of dispersants, while mechanical forces may strengthen this adsorption reaction. Good adaptability and applicability of the suspensions to the change of ND concentration and surrounding temperature are observed, and improved performances of ND diamonds are obtained when used in ultrafine polishing and composite plating.