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超润湿膜在乳化液破乳中的应用及作用机制 被引量:1
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作者 尹晓庆 陈玮豪 +3 位作者 邓博苑 张佳路 刘婉琪 彭开铭 《化学进展》 SCIE CAS CSCD 北大核心 2022年第3期580-592,共13页
超润湿膜材料由于对水和油有独特的润湿性质,可显著提高膜材料处理乳化液的通量,有效缓解严重的膜污染问题,因此在乳化液废水处理领域受到越来越多的重视。本文从超润湿膜的设计制备、分离效果和作用机制三个方面进行分析和总结。超润... 超润湿膜材料由于对水和油有独特的润湿性质,可显著提高膜材料处理乳化液的通量,有效缓解严重的膜污染问题,因此在乳化液废水处理领域受到越来越多的重视。本文从超润湿膜的设计制备、分离效果和作用机制三个方面进行分析和总结。超润湿膜材料包括超亲水膜、Janus膜和功能位点膜,主要通过构建亲水表面和粗糙结构进行膜的设计制备,其中静电纺丝法合成的交联纤维膜由于可以突破筛分效应对膜孔径的限制,在乳化液分离中具有较好的应用前景。同时,归纳超亲水膜的滤水破乳模式和Janus膜的集油破乳模式,前者具有操作压力低、过滤通量高、抗污染性能好的特点,后者具有高纯度集油的特点;并分析膜润湿性、膜孔径、膜上功能位点等膜结构性质和表面活性剂浓度大小等因素对乳化液破乳分离效能的影响规律。最后,总结液滴在膜垂向和切向上的迁移转化规律,以及在Janus膜集油破乳过程中液滴穿透过膜的机制及其力学分析探讨,该部分研究当前主要是基于液滴形态变化的推测和力学的定性分析,对于相关机制的实证和定量的力学分析还有待进一步探究。 展开更多
关键词 含油废水 乳化液 表面活性剂 超润湿 膜分离
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Incomplete data management: a survey 被引量:1
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作者 Xiaoye MIAO Yunjun GAO +1 位作者 Su GUO wanqi liu 《Frontiers of Computer Science》 SCIE EI CSCD 2018年第1期4-25,共22页
Incomplete data accompanies our life processes and covers almost all fields of scientific studies, as a result of delivery failure, no power of battery, accidental loss, etc. However, how to model, index, and query in... Incomplete data accompanies our life processes and covers almost all fields of scientific studies, as a result of delivery failure, no power of battery, accidental loss, etc. However, how to model, index, and query incomplete data in- curs big challenges. For example, the queries struggling with incomplete data usually have dissatisfying query results due to the improper incompleteness handling methods. In this pa- per, we systematically review the management of incomplete data, including modelling, indexing, querying, and handling methods in terms of incomplete data. We also overview sev- eral application scenarios of incomplete data, and summa- rize the existing systems related to incomplete data. It is our hope that this survey could provide insights to the database community on how incomplete data is managed, and inspire database researchers to develop more advanced processing techniques and tools to cope with the issues resulting from incomplete data in the real world. 展开更多
关键词 incomplete data query processing indexing application SYSTEM
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Destructing surfactant network in nanoemulsions by positively charged magnetic nanorods to enhance oil-water separation
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作者 Yongjiao Xiong Xiangfeng Huang +6 位作者 Lexue Li wanqi liu Jialu Zhang Mengfan He Jia liu Lijun Lu Kaiming Peng 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2022年第8期112-121,共10页
The separation of ultrafine oil droplets from wasted nanoemulsions stabilized with high concentration of surfactants is precondition for oil reuse and the safe discharge of effluent.However, the double barriers of the... The separation of ultrafine oil droplets from wasted nanoemulsions stabilized with high concentration of surfactants is precondition for oil reuse and the safe discharge of effluent.However, the double barriers of the interfacial film and network structures formed by surfactants in nanoemulsions significantly impede the oil-water separation. To destroy these surfactant protective layers, we proposed a newly-developed polyethyleneimine micelle template approach to achieve simultaneous surface charge manipulation and morphology transformation of magnetic nanospheres to magnetic nanorods. The results revealed that positively charged magnetic nanospheres exhibited limited separation performance of nanoemulsions, with a maximum chemical oxygen demand(COD) removal of 50%, whereas magnetic nanorods achieved more than 95% COD removal in less than 30 s. The magnetic nanorods were also applicable to wasted nanoemulsions from different sources and exhibited excellent resistance to wide pH changes. Owing to their unique one-dimensional structure, the interfacial dispersion of magnetic nanorods was significantly promoted, leading to the efficient capture of surfactants and widespread destruction of both the interfacial film and network structure, which facilitated droplet merging into the oil phase. The easy-toprepare and easy-to-tune strategy in this study paves a feasible avenue to simultaneously tailor surface charge and morphology of magnetic nanoparticles, and reveals the huge potential of morphology manipulation for producing high-performance nanomaterials to be applied in complex interfacial interaction process. We believe that the newly-developed magnetic-nanorods significantly contribute to hazardous oily waste remediation and advances technology evolution toward problematic oil-pollution control. 展开更多
关键词 NANOEMULSIONS Surface charge Magnetic nanorods SURFACTANT Interfacial film Oil-water separation
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