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Coordination Insertion Mechanism of Ring-Opening Polymerization of Lactide Catalyzed by Stannous Octoate 被引量:3
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作者 weihan rao Caiyun Cai +4 位作者 Jingyu Tang Yiman Wei Caiyun Gao Lin Yu Jiandong Ding 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2021年第7期1965-1974,共10页
Main observation and conclusion Ring-opening polymerization(ROP)of cyclic esters in the presence of stannous octoate(Sn(Oct)2)is the main way to obtain biodegradable aliphatic polyesters,an important family of biodegr... Main observation and conclusion Ring-opening polymerization(ROP)of cyclic esters in the presence of stannous octoate(Sn(Oct)2)is the main way to obtain biodegradable aliphatic polyesters,an important family of biodegradable polymers which have been widely used and still rapidly developed in the fields of biomedical polymers and environment-friendly materials. 展开更多
关键词 Ring-opening polymerization Transition states Curtin-Hammett principle POLYLACTIDE Density functional theory
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