Multiple sets of thick coal beds characterized by simple structure and shallow burial depth were developed in the Early and Middle Jurassic strata of the Ordos Basin, northwestern China. The huge reserves of this high...Multiple sets of thick coal beds characterized by simple structure and shallow burial depth were developed in the Early and Middle Jurassic strata of the Ordos Basin, northwestern China. The huge reserves of this high quality coal have a high commercial value. We studied the coal's petrologic characteristics and its maceral distribution to determine the maceral's contribution to generation of oil and gas. The results show that the Jurassic coals in the Ordos Basin have special petrological features because of the Basin's unique depo- sitional environment which was mainly a series of high-stand swamps in the upper fluvial system. These petro- graphic features are a result of the development of typical inland lakes where some sand bodies were formed by migrating rivers. After burial, the peat continued to undergo oxidizing conditions, this process generated extensive higher inertinite contents in the coals and the vitrinite components were altered to semi-vitrinite. The macroscopic petrographic types of these Jurassic coals are mainly semi-dull coal, dull coal, semilustrous and lustrous coal. The proportions of semi-dull coal and dull coal are higher in the basin margins, especially in the area near the northern margin. The numbers of semilustrous and lustrous coals increase southwards and towards the central basin. This situation indicates that different coal-forming swamp environments have major controlling effects on the coal components. Another observation is that in the Ordos' coal sequences, especially in the lower part, some sandstone beds are thick, up to 20 m with a coarse grain size. The higher fusinite content in the macerals accompanies a higher semi-vitrinite content with more complete and regular plant cell structure. The fusinite structure is clear and well preserved. After burial, the lithology of the roof and floor rocks can continue to affect the evolution of coal petrology. The sand bodies in the roof and floor exhibit good physical conditions so that pore water can maintain a long-term state of oxidation, circulation and connection to the coal. So coal components remain in an oxidation environment for a long time. Conversely, in the basin center, lacustrine facies developed and peat was rapidly covered by mudstone after burial and subsequent coal beds rapidly entered a reducing environment. As a result, abundant gelatification occurred and the vitrinite content increased. E^inite often accumulated in a specific position in the coal bed. Although the average exinite content is not high on the whole, it does significantly contribute to the total hydrocarbon generation. The exinite content has been underestimated, especially the amorphous bituminous fluid and its importance is emphasized here. The reason is that the fluid flows easily into fusinite which has strong rigidity, or flows into some fissures, where it is commonly neglected.展开更多
Solar energy is an ideal energy source for solving energy shortages and serious environmental problems.In the past few decades,photocatalytic technology which uses solar energy to deal with the above problems has caus...Solar energy is an ideal energy source for solving energy shortages and serious environmental problems.In the past few decades,photocatalytic technology which uses solar energy to deal with the above problems has caused great interest.ZnIn_(2)S_(4),as a layered ternary metal chalcogenide compound,has a series of advantages such as the wide light absorption range and adjustable bandgap.It has been applied in the different fields of photocatalysis in recent years.This review introduced the crystal structures and growth mechanism of ZnIn_(2)S_(4)and summarized the preparation methods of ZnIn_(2)S_(4).Also,the promoted strategies of ZnIn_(2)S_(4)based photocatalytic system and their applications in the pollutant removal,hydrogen evolution,reduction of CO_(2),nitrogen fixation,and chemical synthesis was summarized.Furthermore,the challenges and development directions of the current ZnIn_(2)S_(4)based photocatalytic system were proposed.It is hoped that this review will help researchers design a better ZnIn_(2)S_(4)based photocatalytic system.展开更多
基金supported by Chinese Ministry of Science and Technology Project(No.2006CB202202)the National Natural Science Foundation of China(No.40972106 and No.40772095)
文摘Multiple sets of thick coal beds characterized by simple structure and shallow burial depth were developed in the Early and Middle Jurassic strata of the Ordos Basin, northwestern China. The huge reserves of this high quality coal have a high commercial value. We studied the coal's petrologic characteristics and its maceral distribution to determine the maceral's contribution to generation of oil and gas. The results show that the Jurassic coals in the Ordos Basin have special petrological features because of the Basin's unique depo- sitional environment which was mainly a series of high-stand swamps in the upper fluvial system. These petro- graphic features are a result of the development of typical inland lakes where some sand bodies were formed by migrating rivers. After burial, the peat continued to undergo oxidizing conditions, this process generated extensive higher inertinite contents in the coals and the vitrinite components were altered to semi-vitrinite. The macroscopic petrographic types of these Jurassic coals are mainly semi-dull coal, dull coal, semilustrous and lustrous coal. The proportions of semi-dull coal and dull coal are higher in the basin margins, especially in the area near the northern margin. The numbers of semilustrous and lustrous coals increase southwards and towards the central basin. This situation indicates that different coal-forming swamp environments have major controlling effects on the coal components. Another observation is that in the Ordos' coal sequences, especially in the lower part, some sandstone beds are thick, up to 20 m with a coarse grain size. The higher fusinite content in the macerals accompanies a higher semi-vitrinite content with more complete and regular plant cell structure. The fusinite structure is clear and well preserved. After burial, the lithology of the roof and floor rocks can continue to affect the evolution of coal petrology. The sand bodies in the roof and floor exhibit good physical conditions so that pore water can maintain a long-term state of oxidation, circulation and connection to the coal. So coal components remain in an oxidation environment for a long time. Conversely, in the basin center, lacustrine facies developed and peat was rapidly covered by mudstone after burial and subsequent coal beds rapidly entered a reducing environment. As a result, abundant gelatification occurred and the vitrinite content increased. E^inite often accumulated in a specific position in the coal bed. Although the average exinite content is not high on the whole, it does significantly contribute to the total hydrocarbon generation. The exinite content has been underestimated, especially the amorphous bituminous fluid and its importance is emphasized here. The reason is that the fluid flows easily into fusinite which has strong rigidity, or flows into some fissures, where it is commonly neglected.
基金the National Natural Science Foundation of China(Grant No.51201936)the Fundamental Research Funds for the Central Universities of China(No.292018302 and 292018326)。
文摘Solar energy is an ideal energy source for solving energy shortages and serious environmental problems.In the past few decades,photocatalytic technology which uses solar energy to deal with the above problems has caused great interest.ZnIn_(2)S_(4),as a layered ternary metal chalcogenide compound,has a series of advantages such as the wide light absorption range and adjustable bandgap.It has been applied in the different fields of photocatalysis in recent years.This review introduced the crystal structures and growth mechanism of ZnIn_(2)S_(4)and summarized the preparation methods of ZnIn_(2)S_(4).Also,the promoted strategies of ZnIn_(2)S_(4)based photocatalytic system and their applications in the pollutant removal,hydrogen evolution,reduction of CO_(2),nitrogen fixation,and chemical synthesis was summarized.Furthermore,the challenges and development directions of the current ZnIn_(2)S_(4)based photocatalytic system were proposed.It is hoped that this review will help researchers design a better ZnIn_(2)S_(4)based photocatalytic system.