Cyanoethyl cellulose-based eutectogel electrolyte enabling high-voltage-tolerant and ion-conductive solid-state lithium metal batteries

Solid-state polymer electrolytes are an important factor in the deployment of highsafety and high-energy-density solid-state lithium metal batteries.Nevertheless,use of the traditional polyethylene oxide-based solid-state polymer electrolyte is limited due to its inherently low ionic conductivity and narrow electrochemical stability window.Herein,for the first time,we specifically designed a cyanoethyl cellulosein-deep eutectic solvent composite eutectogel as a promising candidate for hybrid solid-state polymer electrolytes.It is found that the proposed eutectogel electrolyte achieves high ionic conductivity(1.87×10^(−3) S cm^(−1) at 25℃),superior electrochemical stability(up to 4.8 V),and outstanding lithium plating/striping behavior(low overpotential of 0.04 V at 1mAcm^(−2) and 1mAh cm^(−2) over 300 h).With the eutectogel-based solid-state polymer electrolyte,a 4.45 V LiCoO_(2)/Li metal battery delivers prominent long-term lifespan(capacity retention of 85%after 200 cycles)and high average Coulombic efficiency(99.5%)under ambient conditions,significantly outperforming the traditional carbonate-based liquid electrolyte.Our work demonstrates a promising strategy for designing eutectogel-based solid-state polymer electrolytes to realize high-voltage and high-energy lithium metal batteries.

Forecast and Analysis of the Main Indicators for the Development of Ocean Fishery in China during the Twelfth Five-Year Plan Period

The ocean fishery is an important part of the marine economy and an important source of human food.The leaders at all levels attach great importance to the development and utilization of ocean fishery resources.Using the regression analysis method,we forecast the main indicators for the development of ocean fishery during the Twelfth Five-Year Plan period.Through the study,it is found that in 2015,the value added of ocean fishery in China is expected to exceed 360 billion yuan,and the output of marine products will exceed 30 million tons.The marine products make stable contribution to the marine economy and the residents'nutrient composition,conducive to maintaining the stable supply of the market and meeting the residents'daily needs for marine products.

Synergistic in-situ growth of silver nanoparticles with nanozyme activity for dual-mode biosensing and cancer theranostics

A multifunctional nanocomposite of AgNPs@GQDs is prepared by synergistic in-situ growth of silver nanoparticles(AgNPs)on the complex of tannic acid(TA)and graphene quantum dots(GQDs)for the construction of dual-mode biosensing platform and cancer theranostics.The nanocomposite exhibits a hydrogen peroxide(H_(2)O_(2))-responsive degradation,in which Ag^(0)is oxidized to Ag^(+)along with the release of oxidized TA and GQDs.The degradation induces the decreased absorbance and enhanced fluorescence(FL)intensity due to the suppression of Forster resonance ene rgy transfer(FRET)in AgNPs@GQDs,which is employed for colorimetric/fluorescence dual-mode sensing of H_(2)O_(2).The intrinsic peroxidase-like activity of GQDs nanozyme can effectively catalyze the oxidation reaction,enhancing the detection sensitivity significantly.Based on the generation of H_(2)O_(2)from the oxidation of glucose with the catalysis of glucose oxidase(GOx),this nanoprobe is versatilely used for the determination of glucose in human serum.Further,through combining the H_(2)O_(2)-responsive degradation of AgNPs@GQDs with high H_(2)O_(2)level in cancer cells,the nanocomposites exhibit good performance in cancer cell recognition and therapy,in which the synergistic anticancer effect of Ag^(+)and oxidized TA contribute to effective cell death,and the liberated GQDs are used to monitor the therapeutic effect by cell imaging.

Homological Dimensions Relative to Special Subcategories

Let A be an abelian category,C an additive,full and self-orthogonal subcategory of A closed under direct summands,rG(C)the right Gorenstein subcategory of A relative to C,and⊥C the left orthogonal class of C.For an object A in A,we prove that if A is in the right 1-orthogonal class of rG(C),then the C-projective and rG(C)-projective dimensions of A are identical;if the rG(C)-projective dimension of A is finite,then the rG(C)-projective and⊥C-projective dimensions of A are identical.We also prove that the supremum of the C-projective dimensions of objects with finite C-projective dimension and that of the rG(C)-projective dimensions of objects with finite rG(C)-projective dimension coincide.Then we apply these results to the category of modules.