A new kind of ndniature conductance cell with thick electrodes was made, which has high resolution, high sensitivity, but no dead volume. A set of capillary electrophoresis device with on-column conductivity detector ...A new kind of ndniature conductance cell with thick electrodes was made, which has high resolution, high sensitivity, but no dead volume. A set of capillary electrophoresis device with on-column conductivity detector was assembled. In order to test the performance of this kind of ndni-cell, different kinds of Anni-cells were used to detect Li+, Na+, K+, Ca2+and Mg2+ ions.展开更多
A simple and convenient electrochemical detection cell for capillary electrophoresis is described in this paper. In this cell, alignment of the capillary working electrode with the separation capillary outlet can be a...A simple and convenient electrochemical detection cell for capillary electrophoresis is described in this paper. In this cell, alignment of the capillary working electrode with the separation capillary outlet can be achieved precisely and easily without the aid of the micropositioner or microscope. With end-column detection, the applicability of the cell as an amperometric detector for capillary electrophoresis is demonstrated by running several phenolic compounds in 50 mu m i.d, capillary with a capillary Pt electrode as the working electrode. Results obtained are satisfactory.展开更多
文摘A new kind of ndniature conductance cell with thick electrodes was made, which has high resolution, high sensitivity, but no dead volume. A set of capillary electrophoresis device with on-column conductivity detector was assembled. In order to test the performance of this kind of ndni-cell, different kinds of Anni-cells were used to detect Li+, Na+, K+, Ca2+and Mg2+ ions.
文摘A simple and convenient electrochemical detection cell for capillary electrophoresis is described in this paper. In this cell, alignment of the capillary working electrode with the separation capillary outlet can be achieved precisely and easily without the aid of the micropositioner or microscope. With end-column detection, the applicability of the cell as an amperometric detector for capillary electrophoresis is demonstrated by running several phenolic compounds in 50 mu m i.d, capillary with a capillary Pt electrode as the working electrode. Results obtained are satisfactory.