The exploration of sustainable energy utilization requires the imple-mentation of advanced electrochemical devices for efficient energy conversion and storage,which are enabled by the usage of cost-effective,high-perf...The exploration of sustainable energy utilization requires the imple-mentation of advanced electrochemical devices for efficient energy conversion and storage,which are enabled by the usage of cost-effective,high-performance electro-catalysts.Currently,heterogeneous atomically dispersed catalysts are considered as potential candidates for a wide range of applications.Compared to conventional cata-lysts,atomically dispersed metal atoms in carbon-based catalysts have more unsatu-rated coordination sites,quantum size effect,and strong metal-support interactions,resulting in exceptional catalytic activity.Of these,dual-atomic catalysts(DACs)have attracted extensive attention due to the additional synergistic effect between two adja-cent metal atoms.DACs have the advantages of full active site exposure,high selectiv-ity,theoretical 100%atom utilization,and the ability to break the scaling relationship of adsorption free energy on active sites.In this review,we summarize recent research advancement of DACs,which includes(1)the comprehensive understanding of the synergy between atomic pairs;(2)the synthesis of DACs;(3)characterization meth-ods,especially aberration-corrected scanning transmission electron microscopy and synchrotron spectroscopy;and(4)electrochemical energy-related applications.The last part focuses on great potential for the electrochemical catalysis of energy-related small molecules,such as oxygen reduction reaction,CO_(2) reduction reaction,hydrogen evolution reaction,and N_(2) reduction reaction.The future research challenges and opportunities are also raised in prospective section.展开更多
The surface properties of oxidic supports and their interaction with the supported metals play critical roles in governing the catalytic activities of oxide‐supported metal catalysts.When metals are supported on redu...The surface properties of oxidic supports and their interaction with the supported metals play critical roles in governing the catalytic activities of oxide‐supported metal catalysts.When metals are supported on reducible oxides,dynamic surface reconstruction phenomena,including strong metal–support interaction(SMSI)and oxygen vacancy formation,complicate the determination of the structural–functional relationship at the active sites.Here,we performed a systematic investigation of the dynamic behavior of Au nanocatalysts supported on flame‐synthesized TiO_(2),which takes predominantly a rutile phase,using CO oxidation above room temperature as a probe reaction.Our analysis conclusively elucidated a negative correlation between the catalytic activity of Au/TiO_(2) and the oxygen vacancy at the Au/TiO_(2) interface.Although the reversible formation and retracting of SMSI overlayers have been ubiquitously observed on Au/TiO_(2) samples,the catalytic consequence of SMSI remains inconclusive.Density functional theory suggests that the electron transfer from TiO_(2) to Au is correlated to the presence of the interfacial oxygen vacancies,retarding the catalytic activation of CO oxidation.展开更多
Remote-sensing measurements indicate that heavy ions in the corona undergo an anisotropic and mass-charge dependent energization.A popular explanation to this phenomenon is the damping of the Alfven/ion cyclotron wave...Remote-sensing measurements indicate that heavy ions in the corona undergo an anisotropic and mass-charge dependent energization.A popular explanation to this phenomenon is the damping of the Alfven/ion cyclotron waves.In this paper,we propose that the ion beam instability can be an important source of the Alfven/ion cyclotron waves,and we study the excitation of the ion beam instability in the corona at the heliocentric distance~3R_(⊙)and the corresponding energy transfer process therein ba sed on plasma kinetic theory.The results indicate that the existence of the motionless heavy ions inhibits the ion beam instability.However,the anisotropic beams of heavy ions promote the excitation of the ion beam instability.Besides,the existence ofαbeams can provide a second energy source for exciting beam instability.However,when both the proton beam and the a beam reach the instability excitation threshold,the proton beam driven instability excites preferentially.Moreover,the excitation threshold of the Alfven/ion cyclotron instability driven by ion beam is of the local Alfven speed or even less in the corona.展开更多
Radon is recognized as a powerful tracer of certain geophysical processes in marine and aquatic environments.In the past few decades,the instruments and methods for measuring radon concentration in water have been dev...Radon is recognized as a powerful tracer of certain geophysical processes in marine and aquatic environments.In the past few decades,the instruments and methods for measuring radon concentration in water have been developed to some extent but still lack underwater in-situ measurements.Here we present an in-situ detection equipment for radon-in-water(pulsed ionization chamber(PIC)-radon)to measure dissolved radon in ocean and groundwater settings.The equipment has been successfully deployed in the Jiaozhou Bay in July 2022 and has achieved 14 d of unattended underwater in-situ observation.Then it was successfully placed in a groundwater monitoring well in the Laizhou Bay in November 2022 and monitored radon activities for over 30 d.The results showed that this instrument had a good indication of submarine groundwater discharge.The PIC-radon detector takes advantage of smaller size,lower power consumption,and is barely influenced by humidity,making it particularly suitable for long-term in-situ measurement,especially in harsh environments with limited human care or deployment spaces.展开更多
Single atomic catalysts(SACs),especially metal-nitrogen doped carbon(M-NC)catalysts,have been extensively explored for the electrochemical oxygen reduction reaction(ORR),owing to their high activity and atomic utiliza...Single atomic catalysts(SACs),especially metal-nitrogen doped carbon(M-NC)catalysts,have been extensively explored for the electrochemical oxygen reduction reaction(ORR),owing to their high activity and atomic utilization efficiency.However,there is still a lack of systematic screening and optimization of local structures surrounding active centers of SACs for ORR as the local coordination has an essential impact on their electronic structures and catalytic performance.Herein,we systematic study the ORR catalytic performance of M-NC SACs with different central metals and environmental atoms in the first and second coordination sphere by using density functional theory(DFT)calculation and machine learning(ML).The geometric and electronic informed overpotential model(GEIOM)based on random forest algorithm showed the highest accuracy,and its R^(2) and root mean square errors(RMSE)were 0.96 and 0.21,respectively.30 potential high-performance catalysts were screened out by GEIOM,and the RMSE of the predicted result was only 0.12 V.This work not only helps us fast screen high-performance catalysts,but also provides a low-cost way to improve the accuracy of ML models.展开更多
Radon(Rn)is a naturally occurring radioactive inert gas in nature,and^(222)Rn has been routinely used as a powerful tracer in various aquatic environmental research on timescales of hours to days,such as submarine gro...Radon(Rn)is a naturally occurring radioactive inert gas in nature,and^(222)Rn has been routinely used as a powerful tracer in various aquatic environmental research on timescales of hours to days,such as submarine groundwater discharge.Here we developed a new approach to measure^(222)Rn in discrete water samples with a wide range of^(222)Rn concentrations using a Pulsed Ionization Chamber(PIC)Radon Detector.The sensitivity of the new PIC system is evaluated at 6.06 counts per minute for 1 Bq/L when a 500 mL water sample volume is used.A robust logarithmic correlation between sample volumes,ranging from 250 mL to 5000 mL,and system sensitivity obtained in this study strongly suggests that this approach is suitable for measuring radon concentration levels in various natural waters.Compared to the currently available methods for measuring radon in grab samples,the PIC system is cheaper,easier to operate and does not require extra accessories(e.g.,drying tubes etc.)to maintain stable measurements throughout the counting procedure.展开更多
When simulating the process from elastic–plastic deformation,damage to failure in a metal structure collision,it is necessary to use the large shell element due to the calculation efficiency,but this would affect the...When simulating the process from elastic–plastic deformation,damage to failure in a metal structure collision,it is necessary to use the large shell element due to the calculation efficiency,but this would affect the accuracy of damage evolution simulation.The compensation algorithm adjusting failure strain according to element size is usually used in the damage model to deal with the problem.In this paper,a new nonlinear compensation algorithm between failure strain and element size was proposed,which was incorporated in the damage model GISSMO(Generalized incremental stress state dependent damage model)to characterize ductile fracture.And associated material parameters were calibrated based on tensile experiments of aluminum alloy specimens with notches.Simulation and experimental results show that the new compensation algorithm significantly reduces the dependence of element size compared with the constant failure strain model and the damage model with the linear compensation algorithm.During the axial splitting process of a circular tubular structure,the new compensation algorithm keeps the failure prediction errors low over the stress states ranging from shear to biaxial tension,and achieves the objective prediction of the damage evolution process.This study demonstrates how the compensation algorithm resolves the contradiction between large element size and fracture prediction accuracy,and this facilitates the use of the damage model in ductile fracture prediction for engineering structures.展开更多
The high-rate cyclability of Li-rich Mn-based oxide(LMO)is highly limited by the electrochemical polarization resulting from the slow kinetic of the Li2MnO3 phase.Herein,the Prussian blue(PB)coating layer with specifi...The high-rate cyclability of Li-rich Mn-based oxide(LMO)is highly limited by the electrochemical polarization resulting from the slow kinetic of the Li2MnO3 phase.Herein,the Prussian blue(PB)coating layer with specific redox potential is introduced as a functionalized interface to overcome the side effect and the escaping of O on the surface of LMO,especially its poor rate capability.In detail,the PB layer can restrict the large polarization of LMO by sharing overloaded current at a high rate due to the synchronous redox of PB and LMO.Consequently,an enhanced high rate performance with capacity retention of 87.8%over 300 cycles is obtained,which is superior to 50.5%of the pristine electrode.Such strategies on the high-rate cyclability of Li-rich Mn-based oxide compatible with good low-rate performances may attract great attention for pursuing durable performances.展开更多
BACKGROUND Longus colli tendinitis(LCT)with dyspnea is a relatively less-reported condition in the literature,and physicians should be aware of its existence.Misdiagnosis of this condition may cause unnecessary treatm...BACKGROUND Longus colli tendinitis(LCT)with dyspnea is a relatively less-reported condition in the literature,and physicians should be aware of its existence.Misdiagnosis of this condition may cause unnecessary treatment for dyspnea.CASE SUMMARY Herein,we report the case of a 40-year-old man with acute neck tendonitis.The patient presented to the pneumology department clinic with a complaint of acute neck tendonitis with dyspnea.An emergency cervical magnetic resonance examination was performed,and the preliminary diagnosis was“acute longus cervicalis tendinitis.”After aggressive medical treatment,the symptoms obviously improved.CONCLUSION LCT is a self-limiting disease that usually improves after three to seven days of conservative treatment following a definite diagnosis.However,owing to its insidious onset and complex clinical manifestations,most relevant personnel are not fully understood.The definite diagnosis of LCT is based on a comprehensive understanding of the triad,rare symptoms,and the clear identification of cervical 1 and 2 levels calcification and prevertebral edema by medical imaging examination,especially magnetic resonance imaging and computed tomography.展开更多
How ions evolve in the Earth’s ion foreshock is a basic problem in the heliosphere community,and the ion beam instability is usually proposed to be one major mechanism affecting the ion dynamics therein.This work wil...How ions evolve in the Earth’s ion foreshock is a basic problem in the heliosphere community,and the ion beam instability is usually proposed to be one major mechanism affecting the ion dynamics therein.This work will perform comprehensive analyses of the oblique ion beam instability in the Earth’s ion foreshock.We show that in addition to two well-known parallel instabilities (i.e.,the parallel fast-magnetosonic whistler instability and the parallel Alfvén ion cyclotron instability),the oblique Alfvén ion beam (OA/IB) instability can also be triggered by free energy relating to the relative drift d V between the solar wind proton and reflected proton populations.For slow d V (e.g.,d V■2.2V_(A),where VAdenotes the Alfvén speed),it only triggers the OA/IB instability.When d V■2.2V_(A),the growth rate in the OA/IB instability can be about 0.6 times the maximum growth rate in parallel instabilities.Moreover,this work finds the existence of two types of OA/IB instabilities.The first one appears at slow d V and in the small wavenumber region at fast d V,and this instability can be described by the cold fluid model.The second one arises in large wavenumber regions at fast d V,and this instability only appears in warm plasmas.Furthermore,through the energy transfer rate method,we propose that the OA/IB instability is driven by the competition among the Landau and cyclotron wave-particle interactions of beam protons,the cyclotron wave-particle interaction of core protons,and the Landau wave-particle interaction of electrons.Because oblique waves can experience significant damping,the importance of the OA/IB instability may be the effective heating of ions in the Earth’s foreshock.展开更多
The study of entrepreneurial models carries significance in guiding the development of entrepreneurial activities.On the basis of a literature review,this paper reviews and analyzes six classic and widely influential ...The study of entrepreneurial models carries significance in guiding the development of entrepreneurial activities.On the basis of a literature review,this paper reviews and analyzes six classic and widely influential entrepreneurial models:entrepreneurial event model(EEM),entrepreneurial intention model(EIM),revised EIM,theory of planned behavior(TPB),economic psychological model(EPM),and structural model of entrepreneurial intention(SMEI).This paper aims to discuss the similarities and differences of these entrepreneurial intention models and their applications in different contexts,which carries important theoretical and practical significance for further research on entrepreneurial behavior and intention.展开更多
By applying nonequilibrium Green’s functions (NEGF) in combination with the density functional theory (DFT), we investigate the electronic transport properties of gated phenalenyl molecular devices with two different...By applying nonequilibrium Green’s functions (NEGF) in combination with the density functional theory (DFT), we investigate the electronic transport properties of gated phenalenyl molecular devices with two different contact geometries. The calculated results show that electronic transport properties of the two different devices can be modulated by external transverse gates. When the molecule contacts the Au electrodes through two second-nearest sites, the current-voltage (<em>I</em>-<em>V</em>) characteristic curves are symmetric and suppressed by the gate electrodes. However, a rectifying behavior will occur when the electrodes connect the molecule on both sides, one second-nearest site and one third-nearest site, respectively. Mechanisms for such phenomena are proposed and these findings suggest a new opportunity for developing molecular devices.展开更多
基金This work was financially supported by the National Key Research and Development Program of China(2018YFA0702002)the Beijing Natural Science Foundation(Z210016)+1 种基金the National Natural Science Foundation of China(51967020,21935001)Shanxi Energy Internet Research Institute(SXEI 2023A004).
文摘The exploration of sustainable energy utilization requires the imple-mentation of advanced electrochemical devices for efficient energy conversion and storage,which are enabled by the usage of cost-effective,high-performance electro-catalysts.Currently,heterogeneous atomically dispersed catalysts are considered as potential candidates for a wide range of applications.Compared to conventional cata-lysts,atomically dispersed metal atoms in carbon-based catalysts have more unsatu-rated coordination sites,quantum size effect,and strong metal-support interactions,resulting in exceptional catalytic activity.Of these,dual-atomic catalysts(DACs)have attracted extensive attention due to the additional synergistic effect between two adja-cent metal atoms.DACs have the advantages of full active site exposure,high selectiv-ity,theoretical 100%atom utilization,and the ability to break the scaling relationship of adsorption free energy on active sites.In this review,we summarize recent research advancement of DACs,which includes(1)the comprehensive understanding of the synergy between atomic pairs;(2)the synthesis of DACs;(3)characterization meth-ods,especially aberration-corrected scanning transmission electron microscopy and synchrotron spectroscopy;and(4)electrochemical energy-related applications.The last part focuses on great potential for the electrochemical catalysis of energy-related small molecules,such as oxygen reduction reaction,CO_(2) reduction reaction,hydrogen evolution reaction,and N_(2) reduction reaction.The future research challenges and opportunities are also raised in prospective section.
基金Science and Technology Innovation Program of Hunan Province,Grant/Award Numbers:2020GK2070,2021RC4006Innovation‐Driven Project of Central South University,Grant/Award Number:2020CX008+3 种基金China Scholarship Council(CSC)National Key R&D Program of China,Grant/Award Number:2022YFE0105900National Natural Science Foundation of China,Grant/Award Number:52276093National Research Foundation Singapore,Grant/Award Number:CREATE。
文摘The surface properties of oxidic supports and their interaction with the supported metals play critical roles in governing the catalytic activities of oxide‐supported metal catalysts.When metals are supported on reducible oxides,dynamic surface reconstruction phenomena,including strong metal–support interaction(SMSI)and oxygen vacancy formation,complicate the determination of the structural–functional relationship at the active sites.Here,we performed a systematic investigation of the dynamic behavior of Au nanocatalysts supported on flame‐synthesized TiO_(2),which takes predominantly a rutile phase,using CO oxidation above room temperature as a probe reaction.Our analysis conclusively elucidated a negative correlation between the catalytic activity of Au/TiO_(2) and the oxygen vacancy at the Au/TiO_(2) interface.Although the reversible formation and retracting of SMSI overlayers have been ubiquitously observed on Au/TiO_(2) samples,the catalytic consequence of SMSI remains inconclusive.Density functional theory suggests that the electron transfer from TiO_(2) to Au is correlated to the presence of the interfacial oxygen vacancies,retarding the catalytic activation of CO oxidation.
基金funded by the National Natural Science Foundation of China(NSFC)under No.12347166。
文摘Remote-sensing measurements indicate that heavy ions in the corona undergo an anisotropic and mass-charge dependent energization.A popular explanation to this phenomenon is the damping of the Alfven/ion cyclotron waves.In this paper,we propose that the ion beam instability can be an important source of the Alfven/ion cyclotron waves,and we study the excitation of the ion beam instability in the corona at the heliocentric distance~3R_(⊙)and the corresponding energy transfer process therein ba sed on plasma kinetic theory.The results indicate that the existence of the motionless heavy ions inhibits the ion beam instability.However,the anisotropic beams of heavy ions promote the excitation of the ion beam instability.Besides,the existence ofαbeams can provide a second energy source for exciting beam instability.However,when both the proton beam and the a beam reach the instability excitation threshold,the proton beam driven instability excites preferentially.Moreover,the excitation threshold of the Alfven/ion cyclotron instability driven by ion beam is of the local Alfven speed or even less in the corona.
基金The National Natural Science Foundation of China under contract Nos U22A20580 and 42130410the Fundamental Research Funds for the Central Universities under contract No.202341002the Pilot Project for the Integration of Science,Education,and Industry under contract No.2022PY069.
文摘Radon is recognized as a powerful tracer of certain geophysical processes in marine and aquatic environments.In the past few decades,the instruments and methods for measuring radon concentration in water have been developed to some extent but still lack underwater in-situ measurements.Here we present an in-situ detection equipment for radon-in-water(pulsed ionization chamber(PIC)-radon)to measure dissolved radon in ocean and groundwater settings.The equipment has been successfully deployed in the Jiaozhou Bay in July 2022 and has achieved 14 d of unattended underwater in-situ observation.Then it was successfully placed in a groundwater monitoring well in the Laizhou Bay in November 2022 and monitored radon activities for over 30 d.The results showed that this instrument had a good indication of submarine groundwater discharge.The PIC-radon detector takes advantage of smaller size,lower power consumption,and is barely influenced by humidity,making it particularly suitable for long-term in-situ measurement,especially in harsh environments with limited human care or deployment spaces.
基金financially supported by the National Key Research and Development Program of China (2018YFA0702002)the Beijing Natural Science Foundation (Z210016)the National Natural Science Foundation of China (21935001)。
文摘Single atomic catalysts(SACs),especially metal-nitrogen doped carbon(M-NC)catalysts,have been extensively explored for the electrochemical oxygen reduction reaction(ORR),owing to their high activity and atomic utilization efficiency.However,there is still a lack of systematic screening and optimization of local structures surrounding active centers of SACs for ORR as the local coordination has an essential impact on their electronic structures and catalytic performance.Herein,we systematic study the ORR catalytic performance of M-NC SACs with different central metals and environmental atoms in the first and second coordination sphere by using density functional theory(DFT)calculation and machine learning(ML).The geometric and electronic informed overpotential model(GEIOM)based on random forest algorithm showed the highest accuracy,and its R^(2) and root mean square errors(RMSE)were 0.96 and 0.21,respectively.30 potential high-performance catalysts were screened out by GEIOM,and the RMSE of the predicted result was only 0.12 V.This work not only helps us fast screen high-performance catalysts,but also provides a low-cost way to improve the accuracy of ML models.
基金The National Natural Science Foundation of China under contract Nos 42130410,41876075 and U1906210the Fundamental Research Funds for the Central Universities under contract No.201962003.
文摘Radon(Rn)is a naturally occurring radioactive inert gas in nature,and^(222)Rn has been routinely used as a powerful tracer in various aquatic environmental research on timescales of hours to days,such as submarine groundwater discharge.Here we developed a new approach to measure^(222)Rn in discrete water samples with a wide range of^(222)Rn concentrations using a Pulsed Ionization Chamber(PIC)Radon Detector.The sensitivity of the new PIC system is evaluated at 6.06 counts per minute for 1 Bq/L when a 500 mL water sample volume is used.A robust logarithmic correlation between sample volumes,ranging from 250 mL to 5000 mL,and system sensitivity obtained in this study strongly suggests that this approach is suitable for measuring radon concentration levels in various natural waters.Compared to the currently available methods for measuring radon in grab samples,the PIC system is cheaper,easier to operate and does not require extra accessories(e.g.,drying tubes etc.)to maintain stable measurements throughout the counting procedure.
基金National Natural Science Foundation of China(Grant No.52172353)。
文摘When simulating the process from elastic–plastic deformation,damage to failure in a metal structure collision,it is necessary to use the large shell element due to the calculation efficiency,but this would affect the accuracy of damage evolution simulation.The compensation algorithm adjusting failure strain according to element size is usually used in the damage model to deal with the problem.In this paper,a new nonlinear compensation algorithm between failure strain and element size was proposed,which was incorporated in the damage model GISSMO(Generalized incremental stress state dependent damage model)to characterize ductile fracture.And associated material parameters were calibrated based on tensile experiments of aluminum alloy specimens with notches.Simulation and experimental results show that the new compensation algorithm significantly reduces the dependence of element size compared with the constant failure strain model and the damage model with the linear compensation algorithm.During the axial splitting process of a circular tubular structure,the new compensation algorithm keeps the failure prediction errors low over the stress states ranging from shear to biaxial tension,and achieves the objective prediction of the damage evolution process.This study demonstrates how the compensation algorithm resolves the contradiction between large element size and fracture prediction accuracy,and this facilitates the use of the damage model in ductile fracture prediction for engineering structures.
基金supported by the National Natural Science Foundation of China (51802261,52072298,and 52172228)the Natural Science Foundation of Shaanxi (2019GHJD-13 and 2020JC-41)+2 种基金the Natural Science Basic Research Plan in Shaanxi province of China (2019JLP-04)Xi'an Science and Technology Project of China (2019219714SYS012CG034)the foundation of National Key Laboratory (6142808200202),PR China.
文摘The high-rate cyclability of Li-rich Mn-based oxide(LMO)is highly limited by the electrochemical polarization resulting from the slow kinetic of the Li2MnO3 phase.Herein,the Prussian blue(PB)coating layer with specific redox potential is introduced as a functionalized interface to overcome the side effect and the escaping of O on the surface of LMO,especially its poor rate capability.In detail,the PB layer can restrict the large polarization of LMO by sharing overloaded current at a high rate due to the synchronous redox of PB and LMO.Consequently,an enhanced high rate performance with capacity retention of 87.8%over 300 cycles is obtained,which is superior to 50.5%of the pristine electrode.Such strategies on the high-rate cyclability of Li-rich Mn-based oxide compatible with good low-rate performances may attract great attention for pursuing durable performances.
文摘BACKGROUND Longus colli tendinitis(LCT)with dyspnea is a relatively less-reported condition in the literature,and physicians should be aware of its existence.Misdiagnosis of this condition may cause unnecessary treatment for dyspnea.CASE SUMMARY Herein,we report the case of a 40-year-old man with acute neck tendonitis.The patient presented to the pneumology department clinic with a complaint of acute neck tendonitis with dyspnea.An emergency cervical magnetic resonance examination was performed,and the preliminary diagnosis was“acute longus cervicalis tendinitis.”After aggressive medical treatment,the symptoms obviously improved.CONCLUSION LCT is a self-limiting disease that usually improves after three to seven days of conservative treatment following a definite diagnosis.However,owing to its insidious onset and complex clinical manifestations,most relevant personnel are not fully understood.The definite diagnosis of LCT is based on a comprehensive understanding of the triad,rare symptoms,and the clear identification of cervical 1 and 2 levels calcification and prevertebral edema by medical imaging examination,especially magnetic resonance imaging and computed tomography.
基金supported by the National Key R&D Program of China 2021YFA1600502(2021YFA1600500)the NSFC 41974203。
文摘How ions evolve in the Earth’s ion foreshock is a basic problem in the heliosphere community,and the ion beam instability is usually proposed to be one major mechanism affecting the ion dynamics therein.This work will perform comprehensive analyses of the oblique ion beam instability in the Earth’s ion foreshock.We show that in addition to two well-known parallel instabilities (i.e.,the parallel fast-magnetosonic whistler instability and the parallel Alfvén ion cyclotron instability),the oblique Alfvén ion beam (OA/IB) instability can also be triggered by free energy relating to the relative drift d V between the solar wind proton and reflected proton populations.For slow d V (e.g.,d V■2.2V_(A),where VAdenotes the Alfvén speed),it only triggers the OA/IB instability.When d V■2.2V_(A),the growth rate in the OA/IB instability can be about 0.6 times the maximum growth rate in parallel instabilities.Moreover,this work finds the existence of two types of OA/IB instabilities.The first one appears at slow d V and in the small wavenumber region at fast d V,and this instability can be described by the cold fluid model.The second one arises in large wavenumber regions at fast d V,and this instability only appears in warm plasmas.Furthermore,through the energy transfer rate method,we propose that the OA/IB instability is driven by the competition among the Landau and cyclotron wave-particle interactions of beam protons,the cyclotron wave-particle interaction of core protons,and the Landau wave-particle interaction of electrons.Because oblique waves can experience significant damping,the importance of the OA/IB instability may be the effective heating of ions in the Earth’s foreshock.
基金This work was supported by the 2022 Zhejiang Technical Institute of Economics School-Level General Project“Study on the Influencing Factors of College Students’Entrepreneurship Intention under the Background of‘Innovation and Entrepreneurship’”(Project Number:X2022096).
文摘The study of entrepreneurial models carries significance in guiding the development of entrepreneurial activities.On the basis of a literature review,this paper reviews and analyzes six classic and widely influential entrepreneurial models:entrepreneurial event model(EEM),entrepreneurial intention model(EIM),revised EIM,theory of planned behavior(TPB),economic psychological model(EPM),and structural model of entrepreneurial intention(SMEI).This paper aims to discuss the similarities and differences of these entrepreneurial intention models and their applications in different contexts,which carries important theoretical and practical significance for further research on entrepreneurial behavior and intention.
文摘By applying nonequilibrium Green’s functions (NEGF) in combination with the density functional theory (DFT), we investigate the electronic transport properties of gated phenalenyl molecular devices with two different contact geometries. The calculated results show that electronic transport properties of the two different devices can be modulated by external transverse gates. When the molecule contacts the Au electrodes through two second-nearest sites, the current-voltage (<em>I</em>-<em>V</em>) characteristic curves are symmetric and suppressed by the gate electrodes. However, a rectifying behavior will occur when the electrodes connect the molecule on both sides, one second-nearest site and one third-nearest site, respectively. Mechanisms for such phenomena are proposed and these findings suggest a new opportunity for developing molecular devices.