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Catalytic combustion of vinyl chloride emissions over Co_(3)O_(4) catalysts with different crystallite sizes 被引量:1
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作者 wen-chao hua Ming-Qi Li +5 位作者 Yang-Long Guo Guang-Tao Chai Hao Liu Yun Guo Li Wang Wang-Cheng Zhan 《Rare Metals》 SCIE EI CAS CSCD 2021年第4期817-827,共11页
A series of Co_(3) O_(4) catalysts was prepared by ammonia(Co-AP) and oxalate(Co-OP) precipitation,solgel(Co-SG),and urea hydrothermal(Co-UH) methods,and their physicochemical properties were characterised by numerous... A series of Co_(3) O_(4) catalysts was prepared by ammonia(Co-AP) and oxalate(Co-OP) precipitation,solgel(Co-SG),and urea hydrothermal(Co-UH) methods,and their physicochemical properties were characterised by numerous techniques including X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),nitrogen sorption,X-ray photoelectron spectroscopy(XPS),temperature-programmed reduction of H_(2)(H_(2)-TPR),temperature-programmed desorption of O_(2)(O_(2)-TPD),and temperature-programmed desorption of NH_(3)(NH_(3)-TPD).The catalytic activity of each catalyst was estimated for the catalytic combustion of vinyl chloride(VC) emissions.The crystallite size of the Co_(3) O_(4) catalyst was found to be well correlated with the amounts of surface-adsorbed oxygen species and number of acid sites on the catalyst surface,and consequently,determined several physicochemical properties of the catalyst.Of the catalysts studied here,the Co-AP catalyst exhibits the smallest crystallite size,which increases the specific surface area and the concentration of Co^(2+) on the catalyst surface.This,in turn,enhances the redox property,oxygen mobility,and the number of acid sites associated with the Co-AP catalyst.In fact,the Co-AP catalyst exhibits the best catalytic activity for VC combustion at 360℃and does not produce any chlorinated by-products. 展开更多
关键词 Catalytic combustion Vinyl chloride Cobalt oxides Crystallite size Preparation methods
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