Background:With the rapid development of the world’s technology,the connection and integration between traditional medicine and modern machine learning technology are increasingly close.In this study,we aimed to anal...Background:With the rapid development of the world’s technology,the connection and integration between traditional medicine and modern machine learning technology are increasingly close.In this study,we aimed to analyze publications on machine learning in traditional medicine by using bibliometric methods and explore global trends in the field.Methods:Relevant research on machine learning in traditional medicine extracted from the Web of Science Core Collection database.Bibliometric analysis and visualization were performed using the Bibliometrix package in R software.Global trends,source journals,authorship,and thematic keywords analysis were performed in this study.Results:From 2012 to 2022,a total of 282 publications on machine learning in traditional medicine were identified and analyzed.The average annual growth rate of the publications was 13.35%.China had the largest contribution in this field(53.9%),followed by the United States(32.6%).IEEE Access had the largest number of published articles,with a total of 15 articles.Calvin Yu-Chian Chen,Xiao-juan Hu and Jue Wang were the main researchers in this field.Shanghai University of Traditional Chinese Medicine and University of California,San Francisco were the main research institutions.Conclusion:This study provides information on research trends in machine learning in traditional medicine to better understand research hotspots and future developments in this field.According to current global trends,the number of publications in this field will gradually increase.China currently dominated the field.Applied research of machine learning techniques may be the next hot topic in this field and deserves further attention.展开更多
The microstructure and corrosion behavior of the as-homogenized and as-extruded Mg-xLi-3Al-2Zn-0.5Y alloys(x=4,8,12,wt.%)were studied.The results show that as the Li content increases from 4%to 12%,the matrix transfer...The microstructure and corrosion behavior of the as-homogenized and as-extruded Mg-xLi-3Al-2Zn-0.5Y alloys(x=4,8,12,wt.%)were studied.The results show that as the Li content increases from 4%to 12%,the matrix transfers from singleα-Mg phase,(α-Mg+β-Li)dual phase to singleβ-Li phase.A mixed corrosion feature of intergranular corrosion and pitting corrosion occurs in the Mg-4Li-3Al-2Zn-0.5Y and Mg-12Li-3Al-2Zn-0.5Y alloys.The former is related to the precipitated AlLi phase along the grain boundaries,and the latter is related to the high potential difference between the second phase and the matrix.The corrosion resistance of the as-extruded alloys is better than that of the as-homogenized alloys.The superior corrosion resistance of the as-extruded Mg-8Li-3Al-2Zn-0.5Y alloy with the lowest corrosion rate(P_(W)=(0.63±0.26)mm/a)is attributed to the more uniform distribution of second phases,the protectiveα-Mg phase via sacrificing theβ-Li phase and the relatively integrated oxide film.展开更多
The effects of Al/Zn ratio(mass ratio) on microstructure and mechanical properties of the Mg-8 Li alloy were investigated. The results indicate that in the as-cast Mg-8Li-xAl-yZn(x+y=5) alloys(LAZ alloys), when the Al...The effects of Al/Zn ratio(mass ratio) on microstructure and mechanical properties of the Mg-8 Li alloy were investigated. The results indicate that in the as-cast Mg-8Li-xAl-yZn(x+y=5) alloys(LAZ alloys), when the Al/Zn ratio is 1:4 and 2:3, the secondary phases are mainly AlLi and MgLiZn phases;when the Al/Zn ratio is 3:2 and 4:1, the secondary phases are mainly AlLi and MgLi2Al phases. The decomposition temperature of MgLiZn phase is about 300 ℃ and the decomposition temperatures of AlLi phase and MgLi2 Al phase are higher(~350 ℃). Solid solution strengthening is the main factor for the improvement of strength of Mg-8Li-xAl-yZn alloys. The Mg-8 Li-3 Al-2 Zn alloy after solution treatment at 350 ℃ for 4 h has the best comprehensive mechanical properties(yield strength of 272.5 MPa, ultimate tensile strength of 315.0 MPa and elongation of 3.4%) among the studied as-cast and solid solution treated Mg-8Li-xAl-yZn alloys.展开更多
The as-cast Mg-8 Li-xZn-yGd(x=1 2, 3,4;y=1,2;wt.%)alloys were prepared in a vacuum induction furnace and their microstructure and mechanical properties were investigated. The results show that the increase of Zn conte...The as-cast Mg-8 Li-xZn-yGd(x=1 2, 3,4;y=1,2;wt.%)alloys were prepared in a vacuum induction furnace and their microstructure and mechanical properties were investigated. The results show that the increase of Zn content results in the volume fraction of W-phase(Mg3 Zn3 Gd2) increasing while that of Mg3 Gd phase decreasing. The strength of Mg-8 Li-xZn-1 Gd alloys is improved with the increase of Zn content,which is ascribed to the second phase strengthening of fine strip-like W-phase and the solid solution strengthening of Zn element.For Mg-8 Li-4 Zn-yGd alloys,the increase of Gd content leads to the appearance of coarse and discontinuous net-like W-phase, which decreases the strength. The Mg-8 Li-4 Zn-1 Gd alloy exhibits an optimum comprehensive performance with the yield strength, ultimate tensile strength and elongation of 154.7 MPa, 197.0 MPa and 12.4%, respectively. In addition,the aging behavior of the typical alloys was also investigated.展开更多
The effects of Li content on the microstructure and mechanical properties of the as-cast Mg−xLi−3Al−2Zn−0.5Y(LAZx32-0.5Y)alloys were investigated by XRD,SEM,TEM,hardness tester and universal testing machine.The result...The effects of Li content on the microstructure and mechanical properties of the as-cast Mg−xLi−3Al−2Zn−0.5Y(LAZx32-0.5Y)alloys were investigated by XRD,SEM,TEM,hardness tester and universal testing machine.The results show that the matrix of the alloy transforms fromα-Mg toα-Mg+β-Li and then toβ-Li when the Li content increases from 4%to 14%(mass fraction).All LAZx32-0.5Y alloys contain AlLi and Al_(2)Y,while MgLi_(2)Al appears only in the alloy containing theβ-Li matrix.As the Li content increases,the content of AlLi and MgLi_(2)Al gradually increases,while the content of Al_(2)Y does not change much.As the Li content increases from 4%to 10%,the ultimate tensile strength and hardness of the as-cast LAZx32-0.5Y alloys gradually decrease while the elongation gradually increases.The corresponding fracture mechanism changes from cleavage fracture to quasi-cleavage fracture and then to microporous aggregation fracture.This is mainly attributed to the decrease ofα-Mg and the increase ofβ-Li in the alloy.When the Li content continues to increase to 10%and 14%,the yield strength,ultimate tensile strength and hardness of the as-cast LAZx32-0.5Y alloys gradually increase,while the elongation decreases sharply,which is mainly attributed to the nano-scale MgLi_(2)Al uniformly distributed in theβ-Li matrix.展开更多
Microstructure evolution and mechanical properties of the rheo-processed ADC12 alloy were investigated by means ofoptical microscopy, X-ray diffraction and scanning electron microscopy. Primary dendritic Al of rheo-ca...Microstructure evolution and mechanical properties of the rheo-processed ADC12 alloy were investigated by means ofoptical microscopy, X-ray diffraction and scanning electron microscopy. Primary dendritic Al of rheo-casting (RC) andrheo-diecasting (RDC) ADC12 alloys are sheared off. The average size, as well as solid fraction of the primary Al increase withdescending pouring temperature. The mechanical properties of alloys are strengthened by rheo-processing. Ultimate tensile strengthsof RC samples increase with the decrease of the pouring temperature, and reach the maximum in the range from 580 to 600 °C. Atpouring temperature of 595 °C, the RDC sample obtains the best ultimate tensile strength and elongation. Great reductions onporosity and primary Al globularization are crucial to the mechanical properties. Relationships of the primary Al size and yield stressare depicted with Hall?Petch equation.展开更多
In this study,the effect of rotating gas bubble stirring treatment on the microstructures of semi-solid AZ91-2Ca alloy was investigated.The semi-solid slurry was produced by injecting fine gas bubbles into the melt th...In this study,the effect of rotating gas bubble stirring treatment on the microstructures of semi-solid AZ91-2Ca alloy was investigated.The semi-solid slurry was produced by injecting fine gas bubbles into the melt through a rotating steel diffuser during solidification,and the samples of semi-solid slurry were taken by the rapid quenching method.The results show that fine and sphericalα-Mg particles can be obtained under rotating gas bubble stirring treatment.The process parameters such as gas flow rate,cooling rate and rotation speed have significant influence on the morphology of primary solid particles.After rotating gas bubble stirring treatment,the higher the particle density,the finer and rounder the primaryα-Mg particles.The formation of numerous solid particles is due to the combination mechanisms of copious nucleation and dendrite fragmentation.展开更多
This work investigated the effects of different Y additions(0,1.5,3.0 and 4.5 wt.%)on the microstructural evolution and mechanical performance of cast Mg−3Nd−0.2Zn−0.5Zr alloy.The results show that as the Y content in...This work investigated the effects of different Y additions(0,1.5,3.0 and 4.5 wt.%)on the microstructural evolution and mechanical performance of cast Mg−3Nd−0.2Zn−0.5Zr alloy.The results show that as the Y content increases,the key secondary phases in as-cast alloys change from the Mg_(12)Nd type to the Mg_(24)Y_(5) type.Meanwhile,the number density of Zn−Zr particles in the grains of as-quenched alloys gradually decreases.HAADF-STEM observations of peak-aged samples reveal that element Y is greatly enriched in the globularβ¢precipitates,leading to a significantly increased volume fraction and promoted precipitation kinetics ofβ¢precipitates,resulting in enhanced strength of the alloy.Tensile tests reveal that,with the addition of 4.5 wt.%Y,the yield strength of the base alloy is substantially increased by 88 and 61 MPa after being aged at 200 and 225°C under peak-aged conditions,respectively.展开更多
This study focused on modifying heat treatment schemes to enhance the mechanical properties of sand cast Al−2Li−2Cu−0.5Mg−0.2Sc−0.2Zr alloy.Different three-stage solution treatment schemes((460℃,32 h)+(520℃,24 h)+(5...This study focused on modifying heat treatment schemes to enhance the mechanical properties of sand cast Al−2Li−2Cu−0.5Mg−0.2Sc−0.2Zr alloy.Different three-stage solution treatment schemes((460℃,32 h)+(520℃,24 h)+(530/540/550℃,4/12/24/32 h))and aging temperatures(125,175,225℃)were designed for comparison.The microstructure evolutions were analyzed by optical microscopy(OM),scanning electron microscopy(SEM)and transmission electron microscopy(TEM).The results showed that the three-stage solution treatment of(460℃,32 h)+(520℃,24 h)+(530℃,12 h)could dissolve most of the secondary phases.The TEM results illustrated that fineδ'(Al_(3)Li)particles were homogeneously distributed in the matrix after aging at 175℃for 8 h,accompanied by a small amount of lath-shaped S′(Al_(2)CuMg)and plate-like T_(1)(Al_(2)CuLi)phases.The best comprehensive properties of yield strength of 376 MPa,ultimate tensile strength of 458 MPa and elongation of 4.1%were obtained by the optimal heat treatment scheme((460℃,32 h)+(520℃,24 h)+(530℃,12 h)+(175℃,8 h)).展开更多
The microstructure,mechanical properties and flame resistance behavior of the AZ91−1Ce alloys with different Ca additions were firstly investigated.Then,the effect of processing parameters,including applied pressures ...The microstructure,mechanical properties and flame resistance behavior of the AZ91−1Ce alloys with different Ca additions were firstly investigated.Then,the effect of processing parameters,including applied pressures and rotation speeds,on the microstructure and mechanical properties of the rheo-squeeze casting AZ91−1Ce−2Ca alloy was studied.The results indicate that with the increase of Ca content,the microstructure is refined and the flame resistance of the AZ91−1Ce−xCa alloys increases.But when the Ca content exceeds 1 wt.%,with the Ca content increasing,the mechanical properties of the AZ91−1Ce−xCa alloys reduce rapidly.For rheo-squeeze casting process,the increase of applied pressure and rotation speed can both bring about significant refinement in the microstructure of the AZ91−1Ce−2Ca alloy and reduction of the porosity,so the mechanical properties increase.Compared to conventional casting,the AZ91−1Ce alloy with the addition of 2 wt.%Ca by rheo-squeeze casting not only guarantees the oxidation resistance(801℃),but also improves mechanical properties.展开更多
The corrosion behaviors of low-pressure sand cast Mg-10Gd-3Y-0.5Zr(wt.%)alloys in as-cast,solution treated(T4)and aged(T6)conditions were studied by means of immersion test and electrochemical measurements in 5wt.%NaC...The corrosion behaviors of low-pressure sand cast Mg-10Gd-3Y-0.5Zr(wt.%)alloys in as-cast,solution treated(T4)and aged(T6)conditions were studied by means of immersion test and electrochemical measurements in 5wt.%NaCl solution saturated with Mg(OH)_(2).It was observed that the corrosion rate in the T4 condition was lower than that of the as-cast and T6 conditions by both sand casting and permanent mold casting with the same order of as-cast>T6>T4;while the corrosion resistance of the permanent mold casting is superior to the sand casting.The morphologies of the corrosion products are similar porous structures consisting of tiny erect flakes perpendicular to the corroded surface of the alloy,irrespective of the heat treatment conditions.Especially,the corrosion film in T4 condition is more compact than that in the other two conditions.In addition,the severer corrosion happening to the as-cast condition is correlated with the galvanic corrosion between the matrix and the eutectic compounds;while improved corrosion resistance for the T4 and T6 conditions is ascribed to the dissolution of the secondary eutectic compounds.The measured corrosion current densities of Mg-10Gd-3Y-0.5Zr alloys in as-cast,T4,and T6 conditions are 36μA·cm^(-2),10μA·cm^(-2),and 33μA·cm^(-2),respectively.The proposed equivalent circuit[Rs(CPE_(1)R_(t)R_(f)CPE_(2))]by Zview software matches well with the tested electrochemical impedance spectra(EIS)data.展开更多
In this work, the effects of reclaimed sand additions on the microstructure characteristics, mechanical properties and fracture behavior of furan no-bake resin sand have been investigated systematically within the tem...In this work, the effects of reclaimed sand additions on the microstructure characteristics, mechanical properties and fracture behavior of furan no-bake resin sand have been investigated systematically within the temperature range from 25 to 600 oC. The addition of 20%-100% reclaimed sand showed dramatic strength deterioration effect at the same temperature, which is associated with the formation of bonding bridges. Both the ultimate tensile strength(UTS) and compressive strength(CS) of the moulding sand initially increase with the increase of temperature, and then sharply decrease with the further increase of temperature, which is attributed to the thermal decomposition of furan resin. The addition amount of reclaimed sand has a remarkable effect on the room temperature fracture mode, i.e., with the addition of 0-20% reclaimed sand, the fracture mode was mainly cohesive fracture; the fracture mode converts to be mixture fracture mode as the addition of reclaimed sand increases to 35%-70%; further increasing the addition to 100% results in the fracture mode of typical adhesive fracture. The fracture surface of the bonding bridge changes from a semblance of cotton or holes to smooth with the increase of test temperature.展开更多
Magnesium-lithium(Mg-Li) alloy,as the lightest metal structure material,has unparalleled market prospects in aerospace,weapons and equipment,electronic technology,transportation,and many other fields.However,it is har...Magnesium-lithium(Mg-Li) alloy,as the lightest metal structure material,has unparalleled market prospects in aerospace,weapons and equipment,electronic technology,transportation,and many other fields.However,it is hard to balance the superlight and high strength of Mg-Li alloy,and the inferior high-temperature strength and poor high-temperature stability limit the wide application of Mg-Li alloy.At present,the main methods to improve the mechanical properties of Mg-Li alloy are alloying,grain refinement,and compound strengthening.The domestic and overseas research progress in the strengthening and toughening methods and mechanisms of Mg-Li alloy are reviewed,and the future development of the high strength and high toughness Mg-Li alloy is prospected.展开更多
Formaldehyde(FA,a typical reactive carbonyl species)is a well-known environmental pollutant and a disease-related biomarker,making its sensitive and selective detection significant.Fluorescent probes have been explore...Formaldehyde(FA,a typical reactive carbonyl species)is a well-known environmental pollutant and a disease-related biomarker,making its sensitive and selective detection significant.Fluorescent probes have been explored for FA perception in environment,intracellular media and in vivo.In this review,we majorly conclude the recently represented fluorescence FA analysis based on small molecule probes.The general FA sensing mechanisms are first introduced.Regarding the FA detection in various environments,sensing tactics and performances are discussed in order of natural environment,living cells and in vivo.In the end,this review discusses the challenges and future trends of FA detection based on fluorescent probes.展开更多
基金National Natural Science Foundation of China(Nos.U2037601,51821001)Key Basic Research Project of the National Basic Strengthening Plan,China(No.2022-xxxx-ZD-093-xx)。
文摘Background:With the rapid development of the world’s technology,the connection and integration between traditional medicine and modern machine learning technology are increasingly close.In this study,we aimed to analyze publications on machine learning in traditional medicine by using bibliometric methods and explore global trends in the field.Methods:Relevant research on machine learning in traditional medicine extracted from the Web of Science Core Collection database.Bibliometric analysis and visualization were performed using the Bibliometrix package in R software.Global trends,source journals,authorship,and thematic keywords analysis were performed in this study.Results:From 2012 to 2022,a total of 282 publications on machine learning in traditional medicine were identified and analyzed.The average annual growth rate of the publications was 13.35%.China had the largest contribution in this field(53.9%),followed by the United States(32.6%).IEEE Access had the largest number of published articles,with a total of 15 articles.Calvin Yu-Chian Chen,Xiao-juan Hu and Jue Wang were the main researchers in this field.Shanghai University of Traditional Chinese Medicine and University of California,San Francisco were the main research institutions.Conclusion:This study provides information on research trends in machine learning in traditional medicine to better understand research hotspots and future developments in this field.According to current global trends,the number of publications in this field will gradually increase.China currently dominated the field.Applied research of machine learning techniques may be the next hot topic in this field and deserves further attention.
基金financially supported by the National Natural Science Foundation of China(Nos.51771115,51775334,51821001,U2037601)Open Fund of State Key Laboratory of Advanced Forming Technology and Equipment(No.SKL2020005)。
文摘The microstructure and corrosion behavior of the as-homogenized and as-extruded Mg-xLi-3Al-2Zn-0.5Y alloys(x=4,8,12,wt.%)were studied.The results show that as the Li content increases from 4%to 12%,the matrix transfers from singleα-Mg phase,(α-Mg+β-Li)dual phase to singleβ-Li phase.A mixed corrosion feature of intergranular corrosion and pitting corrosion occurs in the Mg-4Li-3Al-2Zn-0.5Y and Mg-12Li-3Al-2Zn-0.5Y alloys.The former is related to the precipitated AlLi phase along the grain boundaries,and the latter is related to the high potential difference between the second phase and the matrix.The corrosion resistance of the as-extruded alloys is better than that of the as-homogenized alloys.The superior corrosion resistance of the as-extruded Mg-8Li-3Al-2Zn-0.5Y alloy with the lowest corrosion rate(P_(W)=(0.63±0.26)mm/a)is attributed to the more uniform distribution of second phases,the protectiveα-Mg phase via sacrificing theβ-Li phase and the relatively integrated oxide film.
基金financial supports from the National Natural Science Foundation of China (51771115,51775334)Joint Fund for Space Science and Technology (6141B06310106),ChinaChina and National Defense Science and Technology Innovation Special Zone Project (002-002-01),China。
文摘The effects of Al/Zn ratio(mass ratio) on microstructure and mechanical properties of the Mg-8 Li alloy were investigated. The results indicate that in the as-cast Mg-8Li-xAl-yZn(x+y=5) alloys(LAZ alloys), when the Al/Zn ratio is 1:4 and 2:3, the secondary phases are mainly AlLi and MgLiZn phases;when the Al/Zn ratio is 3:2 and 4:1, the secondary phases are mainly AlLi and MgLi2Al phases. The decomposition temperature of MgLiZn phase is about 300 ℃ and the decomposition temperatures of AlLi phase and MgLi2 Al phase are higher(~350 ℃). Solid solution strengthening is the main factor for the improvement of strength of Mg-8Li-xAl-yZn alloys. The Mg-8 Li-3 Al-2 Zn alloy after solution treatment at 350 ℃ for 4 h has the best comprehensive mechanical properties(yield strength of 272.5 MPa, ultimate tensile strength of 315.0 MPa and elongation of 3.4%) among the studied as-cast and solid solution treated Mg-8Li-xAl-yZn alloys.
基金Project(2016YFB0301004)supported by the National Key Research and Development Program of ChinaProject(51771115)supported by the National Natural Science Foundation of China+3 种基金Project(6141B06310106)supported by the Joint Fund for Space Science and Technology,ChinaProject(009-031-001)supported by the Science and Technology Innovation Program,ChinaProject(USCAST2016-18)supported by the Research Program of Joint Research Center of Advanced Spaceflight Technologies,ChinaProject(SAST2016048)supported by the Science Innovation Foundation of Shanghai Academy of Spaceflight Technology,China
文摘The as-cast Mg-8 Li-xZn-yGd(x=1 2, 3,4;y=1,2;wt.%)alloys were prepared in a vacuum induction furnace and their microstructure and mechanical properties were investigated. The results show that the increase of Zn content results in the volume fraction of W-phase(Mg3 Zn3 Gd2) increasing while that of Mg3 Gd phase decreasing. The strength of Mg-8 Li-xZn-1 Gd alloys is improved with the increase of Zn content,which is ascribed to the second phase strengthening of fine strip-like W-phase and the solid solution strengthening of Zn element.For Mg-8 Li-4 Zn-yGd alloys,the increase of Gd content leads to the appearance of coarse and discontinuous net-like W-phase, which decreases the strength. The Mg-8 Li-4 Zn-1 Gd alloy exhibits an optimum comprehensive performance with the yield strength, ultimate tensile strength and elongation of 154.7 MPa, 197.0 MPa and 12.4%, respectively. In addition,the aging behavior of the typical alloys was also investigated.
基金financially supported by the National Natural Science Foundation of China (Nos.51821001, U2037601)Open Fund of State Key Laboratory of Advanced Forming Technology and Equipment (No. SKL2020005)。
文摘The effects of Li content on the microstructure and mechanical properties of the as-cast Mg−xLi−3Al−2Zn−0.5Y(LAZx32-0.5Y)alloys were investigated by XRD,SEM,TEM,hardness tester and universal testing machine.The results show that the matrix of the alloy transforms fromα-Mg toα-Mg+β-Li and then toβ-Li when the Li content increases from 4%to 14%(mass fraction).All LAZx32-0.5Y alloys contain AlLi and Al_(2)Y,while MgLi_(2)Al appears only in the alloy containing theβ-Li matrix.As the Li content increases,the content of AlLi and MgLi_(2)Al gradually increases,while the content of Al_(2)Y does not change much.As the Li content increases from 4%to 10%,the ultimate tensile strength and hardness of the as-cast LAZx32-0.5Y alloys gradually decrease while the elongation gradually increases.The corresponding fracture mechanism changes from cleavage fracture to quasi-cleavage fracture and then to microporous aggregation fracture.This is mainly attributed to the decrease ofα-Mg and the increase ofβ-Li in the alloy.When the Li content continues to increase to 10%and 14%,the yield strength,ultimate tensile strength and hardness of the as-cast LAZx32-0.5Y alloys gradually increase,while the elongation decreases sharply,which is mainly attributed to the nano-scale MgLi_(2)Al uniformly distributed in theβ-Li matrix.
基金Project(51404153)supported by the National Natural Science Foundation of China
文摘Microstructure evolution and mechanical properties of the rheo-processed ADC12 alloy were investigated by means ofoptical microscopy, X-ray diffraction and scanning electron microscopy. Primary dendritic Al of rheo-casting (RC) andrheo-diecasting (RDC) ADC12 alloys are sheared off. The average size, as well as solid fraction of the primary Al increase withdescending pouring temperature. The mechanical properties of alloys are strengthened by rheo-processing. Ultimate tensile strengthsof RC samples increase with the decrease of the pouring temperature, and reach the maximum in the range from 580 to 600 °C. Atpouring temperature of 595 °C, the RDC sample obtains the best ultimate tensile strength and elongation. Great reductions onporosity and primary Al globularization are crucial to the mechanical properties. Relationships of the primary Al size and yield stressare depicted with Hall?Petch equation.
基金This project is sponsored by National Natural Science Foundation of China(No.51275295)Funded Projects of SAST-SJTU Joint Research Centre of Advanced Aerospace Technology(No.USCAST2012-15)Research Fund for the Doctoral Program of Higher Education of China(No.20120073120011).
文摘In this study,the effect of rotating gas bubble stirring treatment on the microstructures of semi-solid AZ91-2Ca alloy was investigated.The semi-solid slurry was produced by injecting fine gas bubbles into the melt through a rotating steel diffuser during solidification,and the samples of semi-solid slurry were taken by the rapid quenching method.The results show that fine and sphericalα-Mg particles can be obtained under rotating gas bubble stirring treatment.The process parameters such as gas flow rate,cooling rate and rotation speed have significant influence on the morphology of primary solid particles.After rotating gas bubble stirring treatment,the higher the particle density,the finer and rounder the primaryα-Mg particles.The formation of numerous solid particles is due to the combination mechanisms of copious nucleation and dendrite fragmentation.
基金supported by the National Natural Science Foundation of China(Nos.U2037601,51775334 and 51821001)the National Key Research&Development Program of China(No.2016YFB0701205)+2 种基金the Joint Innovation Fund of CALT and College,China(No.CALT2020-TS07)the Open Fund of State Key Laboratory of Advanced Forming Technology and Equipment,China(No.SKL2020005)the Research Program of Joint Research Center of Advanced Spaceflight Technologies,China(No.USCAST2020-14).
文摘This work investigated the effects of different Y additions(0,1.5,3.0 and 4.5 wt.%)on the microstructural evolution and mechanical performance of cast Mg−3Nd−0.2Zn−0.5Zr alloy.The results show that as the Y content increases,the key secondary phases in as-cast alloys change from the Mg_(12)Nd type to the Mg_(24)Y_(5) type.Meanwhile,the number density of Zn−Zr particles in the grains of as-quenched alloys gradually decreases.HAADF-STEM observations of peak-aged samples reveal that element Y is greatly enriched in the globularβ¢precipitates,leading to a significantly increased volume fraction and promoted precipitation kinetics ofβ¢precipitates,resulting in enhanced strength of the alloy.Tensile tests reveal that,with the addition of 4.5 wt.%Y,the yield strength of the base alloy is substantially increased by 88 and 61 MPa after being aged at 200 and 225°C under peak-aged conditions,respectively.
基金the National Natural Science Foundation of China(Nos.51871148,51821001)the United Fund of National Department of Education and Equipment Development,China(No.6141A02033245).
文摘This study focused on modifying heat treatment schemes to enhance the mechanical properties of sand cast Al−2Li−2Cu−0.5Mg−0.2Sc−0.2Zr alloy.Different three-stage solution treatment schemes((460℃,32 h)+(520℃,24 h)+(530/540/550℃,4/12/24/32 h))and aging temperatures(125,175,225℃)were designed for comparison.The microstructure evolutions were analyzed by optical microscopy(OM),scanning electron microscopy(SEM)and transmission electron microscopy(TEM).The results showed that the three-stage solution treatment of(460℃,32 h)+(520℃,24 h)+(530℃,12 h)could dissolve most of the secondary phases.The TEM results illustrated that fineδ'(Al_(3)Li)particles were homogeneously distributed in the matrix after aging at 175℃for 8 h,accompanied by a small amount of lath-shaped S′(Al_(2)CuMg)and plate-like T_(1)(Al_(2)CuLi)phases.The best comprehensive properties of yield strength of 376 MPa,ultimate tensile strength of 458 MPa and elongation of 4.1%were obtained by the optimal heat treatment scheme((460℃,32 h)+(520℃,24 h)+(530℃,12 h)+(175℃,8 h)).
基金financial supports from National Natural Science Foundation of China(Nos.51775334,51771115,U2037601)Research Program of Joint Research Center of Advanced Spaceflight Technologies,China(No.USCAST2020-14)。
文摘The microstructure,mechanical properties and flame resistance behavior of the AZ91−1Ce alloys with different Ca additions were firstly investigated.Then,the effect of processing parameters,including applied pressures and rotation speeds,on the microstructure and mechanical properties of the rheo-squeeze casting AZ91−1Ce−2Ca alloy was studied.The results indicate that with the increase of Ca content,the microstructure is refined and the flame resistance of the AZ91−1Ce−xCa alloys increases.But when the Ca content exceeds 1 wt.%,with the Ca content increasing,the mechanical properties of the AZ91−1Ce−xCa alloys reduce rapidly.For rheo-squeeze casting process,the increase of applied pressure and rotation speed can both bring about significant refinement in the microstructure of the AZ91−1Ce−2Ca alloy and reduction of the porosity,so the mechanical properties increase.Compared to conventional casting,the AZ91−1Ce alloy with the addition of 2 wt.%Ca by rheo-squeeze casting not only guarantees the oxidation resistance(801℃),but also improves mechanical properties.
基金sponsored by the National Natural Science Foundation of China(No.51275295)Research Fund for the Doctoral Program of Higher Education of China(Nos.20120073120011 and 20130073110052)
文摘The corrosion behaviors of low-pressure sand cast Mg-10Gd-3Y-0.5Zr(wt.%)alloys in as-cast,solution treated(T4)and aged(T6)conditions were studied by means of immersion test and electrochemical measurements in 5wt.%NaCl solution saturated with Mg(OH)_(2).It was observed that the corrosion rate in the T4 condition was lower than that of the as-cast and T6 conditions by both sand casting and permanent mold casting with the same order of as-cast>T6>T4;while the corrosion resistance of the permanent mold casting is superior to the sand casting.The morphologies of the corrosion products are similar porous structures consisting of tiny erect flakes perpendicular to the corroded surface of the alloy,irrespective of the heat treatment conditions.Especially,the corrosion film in T4 condition is more compact than that in the other two conditions.In addition,the severer corrosion happening to the as-cast condition is correlated with the galvanic corrosion between the matrix and the eutectic compounds;while improved corrosion resistance for the T4 and T6 conditions is ascribed to the dissolution of the secondary eutectic compounds.The measured corrosion current densities of Mg-10Gd-3Y-0.5Zr alloys in as-cast,T4,and T6 conditions are 36μA·cm^(-2),10μA·cm^(-2),and 33μA·cm^(-2),respectively.The proposed equivalent circuit[Rs(CPE_(1)R_(t)R_(f)CPE_(2))]by Zview software matches well with the tested electrochemical impedance spectra(EIS)data.
基金sponsored by the National Natural Science Foundation of China(Nos.51275295 and 51201102)the Shanghai Rising–Star Program(No.14QB1403200)Research Fund for the Doctoral Program of Higher Education of China(Nos.20120073120011 and 20130073110052)
文摘In this work, the effects of reclaimed sand additions on the microstructure characteristics, mechanical properties and fracture behavior of furan no-bake resin sand have been investigated systematically within the temperature range from 25 to 600 oC. The addition of 20%-100% reclaimed sand showed dramatic strength deterioration effect at the same temperature, which is associated with the formation of bonding bridges. Both the ultimate tensile strength(UTS) and compressive strength(CS) of the moulding sand initially increase with the increase of temperature, and then sharply decrease with the further increase of temperature, which is attributed to the thermal decomposition of furan resin. The addition amount of reclaimed sand has a remarkable effect on the room temperature fracture mode, i.e., with the addition of 0-20% reclaimed sand, the fracture mode was mainly cohesive fracture; the fracture mode converts to be mixture fracture mode as the addition of reclaimed sand increases to 35%-70%; further increasing the addition to 100% results in the fracture mode of typical adhesive fracture. The fracture surface of the bonding bridge changes from a semblance of cotton or holes to smooth with the increase of test temperature.
基金the National Natural Science Foundation of China(Nos.51771115,51775334,51821001 and U2037601)the Joint Fund for Space Science and Technology(No.6141B06310106)。
文摘Magnesium-lithium(Mg-Li) alloy,as the lightest metal structure material,has unparalleled market prospects in aerospace,weapons and equipment,electronic technology,transportation,and many other fields.However,it is hard to balance the superlight and high strength of Mg-Li alloy,and the inferior high-temperature strength and poor high-temperature stability limit the wide application of Mg-Li alloy.At present,the main methods to improve the mechanical properties of Mg-Li alloy are alloying,grain refinement,and compound strengthening.The domestic and overseas research progress in the strengthening and toughening methods and mechanisms of Mg-Li alloy are reviewed,and the future development of the high strength and high toughness Mg-Li alloy is prospected.
基金supported by the National Natural Science Foundation of China(22074005)the Natural Science Foundation of Beijing Municipality(2202038)the Open Research Fund Program of Beijing Key Lab of Plant Resource Research and Development,Beijing Technology and Business University(PRRD-2021-YB6)
文摘Formaldehyde(FA,a typical reactive carbonyl species)is a well-known environmental pollutant and a disease-related biomarker,making its sensitive and selective detection significant.Fluorescent probes have been explored for FA perception in environment,intracellular media and in vivo.In this review,we majorly conclude the recently represented fluorescence FA analysis based on small molecule probes.The general FA sensing mechanisms are first introduced.Regarding the FA detection in various environments,sensing tactics and performances are discussed in order of natural environment,living cells and in vivo.In the end,this review discusses the challenges and future trends of FA detection based on fluorescent probes.