A novel synthesis process for ETS-4 titanosilicate using commercial anatase as the titanium source in the absence of fluoride ions was studied. Fluoride ions and traced ETS-4 seeds have important roles in forming ETS-...A novel synthesis process for ETS-4 titanosilicate using commercial anatase as the titanium source in the absence of fluoride ions was studied. Fluoride ions and traced ETS-4 seeds have important roles in forming ETS-4 structures. However, the method using ETS-4 seeds instead of fluoride ions to improve product purity and productivity is environment-friendly. ETS-4, ETS-4(NS), and ETS-4(NaF) were respectively synthesized using traced ETS-4 seeds, without seeds, and with fluoride ions. The as-synthesized samples were identified by X-ray diffraction, scanning electron microscopy, and thermogravimetric analysis. Adsorption isotherms and adsorption heats of nitrogen and methane on the prepared ETS-4 were also measured. The results showed that ETS-4 samples could be prepared using anatase in the absence of fluoride ions, with good purity, comparable physicochemical properties, and excellent adsorption properties.展开更多
Traditional processes for treating vanadium slag generate a huge volume of solid residue and a large amount of harmful gas,which cause serious environmental problems.In this study,a new process for the comprehensive u...Traditional processes for treating vanadium slag generate a huge volume of solid residue and a large amount of harmful gas,which cause serious environmental problems.In this study,a new process for the comprehensive utilization of vanadium slag was proposed,wherein zeolite A and a V2O5/TiO2 system were synthesized.The structural properties of the as-synthesized zeolite A and the V2O5/TiO2system were characterized using various experimental techniques,including X-ray diffraction,X-ray fluorescence,scanning electron microscopy,and infrared spectroscopy.The results reveal that zeolite A and the V2O5/TiO2 system are successfully obtained with high purity.The results of gas adsorption measurements indicate that the prepared zeolite A exhibits high selectivity for CO2 over N2 and is a candidate material for CO2 capture from flue-gas streams.展开更多
As the brightest gamma-ray burst ever observed,GRB 221009A provided a precious opportunity to explore spectral line features.In this article,we performed a comprehensive spectroscopy analysis of GRB 221009A jointly wi...As the brightest gamma-ray burst ever observed,GRB 221009A provided a precious opportunity to explore spectral line features.In this article,we performed a comprehensive spectroscopy analysis of GRB 221009A jointly with GECAM-C and Fermi/GBM data to search for emission and absorption lines.For the first time we investigated the line feature throughout this GRB including the most bright part where many instruments suffered problems,and identified prominent emission lines in multiple time intervals.The central energy of the Gaussian emission line evolves from about 37 to 6 MeV,with a nearly constant ratio(about 10%)between the line width and central energy.Particularly,we find that both the central energy and the energy flux of the emission line evolve with time as a power law decay with power law index of–1 and–2,respectively.We suggest that the observed emission lines most likely origin from the blue-shifted electron positron pair annihilation 511 ke V line.We find that a standard high latitude emission scenario cannot fully interpret the observation,thus we propose that the emission line comes from some dense clumps with electron positron pairs traveling together with the jet.In this scenario,we can use the emission line to directly,for the first time,measure the bulk Lorentz factor of the jet(Γ)and reveal its time evolution(i.e.,Γ~t^(-1))during the prompt emission.Interestingly,we find that the flux of the annihilation line in the co-moving frame keeps constant.These discoveries of the spectral line features shed new and important lights on the physics of GRB and relativistic jet.展开更多
基金supported by the National Natural Science Foundation of China (No. 51074205)
文摘A novel synthesis process for ETS-4 titanosilicate using commercial anatase as the titanium source in the absence of fluoride ions was studied. Fluoride ions and traced ETS-4 seeds have important roles in forming ETS-4 structures. However, the method using ETS-4 seeds instead of fluoride ions to improve product purity and productivity is environment-friendly. ETS-4, ETS-4(NS), and ETS-4(NaF) were respectively synthesized using traced ETS-4 seeds, without seeds, and with fluoride ions. The as-synthesized samples were identified by X-ray diffraction, scanning electron microscopy, and thermogravimetric analysis. Adsorption isotherms and adsorption heats of nitrogen and methane on the prepared ETS-4 were also measured. The results showed that ETS-4 samples could be prepared using anatase in the absence of fluoride ions, with good purity, comparable physicochemical properties, and excellent adsorption properties.
基金supported by the Natural Science Foundation of China (Nos. 51406029 and 51474067)the Key Laboratory Project of Liaoning Province of Education (No.LZ2015032)
文摘Traditional processes for treating vanadium slag generate a huge volume of solid residue and a large amount of harmful gas,which cause serious environmental problems.In this study,a new process for the comprehensive utilization of vanadium slag was proposed,wherein zeolite A and a V2O5/TiO2 system were synthesized.The structural properties of the as-synthesized zeolite A and the V2O5/TiO2system were characterized using various experimental techniques,including X-ray diffraction,X-ray fluorescence,scanning electron microscopy,and infrared spectroscopy.The results reveal that zeolite A and the V2O5/TiO2 system are successfully obtained with high purity.The results of gas adsorption measurements indicate that the prepared zeolite A exhibits high selectivity for CO2 over N2 and is a candidate material for CO2 capture from flue-gas streams.
基金supported by the National Key R&D Program of China(Grant Nos.2021YFA0718500,and 2023YFE0101200)the Strategic Priority Research Program of Chinese Academy of Sciences(Grant Nos.XDA15360102,XDA15360300,and XDA15052700)+3 种基金the National Natural Science Foundation of China(Grant Nos.12273042,61234003,61434004,61504141,11673062,12393813,2333007,12027803,and 12303045)the CAS Interdisciplinary Project(Grant No.KJZD-EW-L11-04)supported by the Strategic Priority Research Program on Space Science(Grant No.XDA15360000)of the Chinese Academy of Sciencessupported by the Yunnan Revitalization Talent Support Program(Yun Ling Scholar Award)。
文摘As the brightest gamma-ray burst ever observed,GRB 221009A provided a precious opportunity to explore spectral line features.In this article,we performed a comprehensive spectroscopy analysis of GRB 221009A jointly with GECAM-C and Fermi/GBM data to search for emission and absorption lines.For the first time we investigated the line feature throughout this GRB including the most bright part where many instruments suffered problems,and identified prominent emission lines in multiple time intervals.The central energy of the Gaussian emission line evolves from about 37 to 6 MeV,with a nearly constant ratio(about 10%)between the line width and central energy.Particularly,we find that both the central energy and the energy flux of the emission line evolve with time as a power law decay with power law index of–1 and–2,respectively.We suggest that the observed emission lines most likely origin from the blue-shifted electron positron pair annihilation 511 ke V line.We find that a standard high latitude emission scenario cannot fully interpret the observation,thus we propose that the emission line comes from some dense clumps with electron positron pairs traveling together with the jet.In this scenario,we can use the emission line to directly,for the first time,measure the bulk Lorentz factor of the jet(Γ)and reveal its time evolution(i.e.,Γ~t^(-1))during the prompt emission.Interestingly,we find that the flux of the annihilation line in the co-moving frame keeps constant.These discoveries of the spectral line features shed new and important lights on the physics of GRB and relativistic jet.