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聚环氧乙烷聚合物固态电解质的现状及改性策略
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作者 王青磊 王涵 +4 位作者 马静 上官跃伟 颜文超 上官雪慧 李法强 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2022年第4期165-173,共9页
锂二次电池普遍采用有机碳酸酯液态电解质,存在易泄露、易燃烧、甚至爆炸等安全隐患;聚合物固态电解质能够有效克服传统液态电解质的缺陷,同时具有质量轻、可加工性好、与电极界面兼容性好等优点,在固态锂电池领域具有十分重要的应用前... 锂二次电池普遍采用有机碳酸酯液态电解质,存在易泄露、易燃烧、甚至爆炸等安全隐患;聚合物固态电解质能够有效克服传统液态电解质的缺陷,同时具有质量轻、可加工性好、与电极界面兼容性好等优点,在固态锂电池领域具有十分重要的应用前景。聚环氧乙烷(PEO)固态电解质是研究最早、应用最广泛的聚合物固态电解质体系。文中综述了目前PEO聚合物固态电解质的现状,重点从离子电导率改性、电化学窗口改性、力学强度改性和阻燃性能改性4个方面介绍了其改性策略;最后,展望了PEO聚合物固态电解质的发展趋势。 展开更多
关键词 锂二次电池 聚合物固态电解质 聚环氧乙烷 改性策略
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Collimated gamma rays from laser wakefield accelerated electrons
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作者 Minghua Li Liming Chen +8 位作者 Dazhang Li Kai Huang Yifei Li Yong Ma wenchao yan Mengze Tao Junhao Tan Zhengming Sheng Jie Zhang 《Matter and Radiation at Extremes》 SCIE EI CAS 2018年第4期188-196,共9页
Betatron radiation from laser wakefield accelerated electrons and X-rays scattered off a counter-propagating relativistic electron bunch arecollimated and hold the potential to extend the energy range to hard X-ray or... Betatron radiation from laser wakefield accelerated electrons and X-rays scattered off a counter-propagating relativistic electron bunch arecollimated and hold the potential to extend the energy range to hard X-ray or gamma ray band. The peak brightness of these incoherent radiations could reach the level of the brightest synchrotron light sources in the world due to their femtosecond pulse duration and source sizedown to a few micrometers. In this article, the principle and properties of these radiation sources are briefly reviewed and compared. Then wepresent our recent progress in betatron radiation enhancement in the perspective of both photon energy and photon number. The enhancement istriggered by using a clustering gas target, arousing a second injection of a fiercely oscillating electron bunch with large charge or stimulating aresonantly enhanced oscillation of the ionization injected electrons. By adopting these methods, bright photon source with energy over 100 keVis generated which would greatly impact applications such as nuclear physics, diagnostic radiology, laboratory astrophysics and high-energydensity science. 展开更多
关键词 Laser wakefield accelerator Gamma ray Hard X-ray Betatron radiation ENHANCEMENT
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Genetic Analysis of Leucine Content in Indica-Japonica Hybrid Rice (Oryza sativa L.)
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作者 Xiaoming Zhang Chunhai Shi +3 位作者 Jianguo Wu Shenghai Ye Genliang Bao wenchao yan 《American Journal of Plant Sciences》 2010年第1期17-23,共7页
Genetic control of leucine content in indica-japonica hybrid rice (Oryza sativa L.) was studied in 35 crosses of F1 and F2 generations, which were derived from crossing 7 male sterile indica rice lines with 5 restorer... Genetic control of leucine content in indica-japonica hybrid rice (Oryza sativa L.) was studied in 35 crosses of F1 and F2 generations, which were derived from crossing 7 male sterile indica rice lines with 5 restorer japonica rice lines along with their parents. Two genetic models and their corresponding statistical methods for quantitative traits of triploid seeds in cereal crops were used for the analysis. The first was the unconditional genetic model, which refers to the analysis of cumulative measurements (from flowering to a specific time) along the developmental stages, while the second was the conditional genetic model, which relates to analysis from one developmental stage to another stage (t - 1→t). The results showed that leucine content of indica-japonica hybrid rice was controlled by the expression of triploid endosperm effect (endosperm additive effect and endosperm dominant effect), cytoplasm effect, diploid maternal plant effect (maternal additive effect and maternal dominant effect) and their environmental interaction effects. Of these effects, endosperm dominant effect and maternal dominant effect were more important at the earlier stages, while endosperm additive effect and maternal additive effect were more important at the later stages of rice grain development under both unconditional and conditional genetic analyses. Due to the high heritabilities, which came from endosperm, maternal and cytoplasm effects for leucine content at different developmental stages, selection for leucine content of indica-japonica hybrid rice would be more efficient at early generations in breeding programs. 展开更多
关键词 INDICA-JAPONICA Hybrid Rice Developmental Genetics Quality LEUCINE CONTENT GENETIC Variance Conditional GENETIC Variance HERITABILITY
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Luminescent d-f transition Yb(Ⅱ)-containing azacryptates with high photoluminescence quantum yields
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作者 wenchao yan Zifeng Zhao +5 位作者 Gang Yu Hao Qi Ruoyao Guo Nanlong Zheng Zuqiang Bian Zhiwei Liu 《Science China Chemistry》 SCIE EI CAS CSCD 2023年第6期1750-1757,共8页
Emission tunable d-f transition lanthanide complexes have wide applications in many fields such as lighting and photoredox catalysis.Compared with Ce(Ⅲ)and Eu(Ⅱ)complexes,which have achieved near-unity photoluminesc... Emission tunable d-f transition lanthanide complexes have wide applications in many fields such as lighting and photoredox catalysis.Compared with Ce(Ⅲ)and Eu(Ⅱ)complexes,which have achieved near-unity photoluminescence quantum yields(PLQYs),Yb(Ⅱ)complexes still suffer from low reported PLQYs not exceeding 10%.In this work,two luminescent Yb(Ⅱ)-containing azacryptates YbI_(2)-N8M6(N8M6=4,7,13,16,21,24-hexamethyl-1,4,7,10,13,16,21,24-octaazabicyclo[8.8.8]hexacosane)and YbI2-N8E6(N8E6=4,7,13,16,21,24-hexaethyl-1,4,7,10,13,16,21,24-octaazabicyclo[8.8.8]hexacosane)were synthesized and characterized.YbI2-N8M6 in solid powder exhibits blue emission with a maximum emission wavelength(λm)of 464 nm and a PLQY of 76%,while YbI_(2)-N8E6 in solid powder exhibits green emission with a λ_(m) of 537 nm and a PLQY up to93%.Moreover,YbI_(2)-N8M6 exhibits mechanochromic property,showing an emission color change from deep-blue to cyan under mechanical grinding.These results will inspire the studies about luminescent Yb(Ⅱ)complexes and their further applications. 展开更多
关键词 d-f transition Yb(ll)complex LUMINESCENCE mechanochromic property
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Gamma-ray Vortex Burst in Nonlinear Thomson Scattering withRefocusing Spiral Plasma Mirror
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作者 Wejun Zhou wenchao yan +1 位作者 Jinguang Wang Liming Chen 《Ultrafast Science》 2023年第1期11-17,共7页
The gamma-ray vortex burst in the nonlinear Thomson scattering when the laser wakefield accelerated electron bunch collides with an ultra-intense Laguerre-Gaussian laser that was reflected from the refocusing spiral p... The gamma-ray vortex burst in the nonlinear Thomson scattering when the laser wakefield accelerated electron bunch collides with an ultra-intense Laguerre-Gaussian laser that was reflected from the refocusing spiral plasma mirror.The orbit angular momentum of the scattering laser would be transferred to the gamma radiation through the scattering process.The 3-dimensional particle-in-cell simulations gave the electron dynamics in the scattering,which determines the characteristics of the vortical radiation.The radiation calculation results ilustrated the burst of gamma-ray vortex and surprisingly revealed the radiation pattern distortion phenomenon due to the nonlinear effect.This scheme can not only simplifty the experimental setup for the generation of twisted radiation but also boost the yield of vortical gamma photons.The peak brightness of the gamma-ray vortex was estimated to be 1 × 10^(22) photons/s/mm^(2)/mrad^(2)/0.1%BW at 1 MeV,which might pave the way for the researches on angular momentum-related nuclear physics. 展开更多
关键词 process MOMENTUM VORTEX
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超重力法制备CNT负载MnFe_(2)O_(4)纳米材料及吸附Pb(Ⅱ)应用 被引量:1
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作者 高雨松 祁贵生 +2 位作者 闫文超 郭达 刘有智 《过程工程学报》 CAS CSCD 北大核心 2022年第11期1504-1511,共8页
为改善MnFe_(2)O_(4)纳米颗粒在实际应用中的团聚问题,结合多壁碳纳米管(CNT)原位负载,提出超重力法制备CNT负载MnFe_(2)O_(4)纳米材料(MnFe_(2)O_(4)/CNT)。以典型的重金属污染Pb(Ⅱ)作为研究对象,对其吸附性能进行研究。首先考察了MnF... 为改善MnFe_(2)O_(4)纳米颗粒在实际应用中的团聚问题,结合多壁碳纳米管(CNT)原位负载,提出超重力法制备CNT负载MnFe_(2)O_(4)纳米材料(MnFe_(2)O_(4)/CNT)。以典型的重金属污染Pb(Ⅱ)作为研究对象,对其吸附性能进行研究。首先考察了MnFe_(2)O_(4)负载量对Pb(Ⅱ)吸附容量的影响,确定最佳MnFe_(2)O_(4)负载量为83.3wt%。采用XRD,SEM,N 2吸附-脱附比表面分析仪和VSM对最佳MnFe_(2)O_(4)负载量条件下的MnFe_(2)O_(4)/CNT进行表征。MnFe_(2)O_(4)/CNT展现出优异的磁性,其饱和磁化强度为35.85 emu/g,因而可应用于水体中污染物的磁性分离。吸附实验结果表明在初始Pb(Ⅱ)浓度300 mg/L和溶液pH=6的条件下,Pb(Ⅱ)在MnFe_(2)O_(4)/CNT上180 min达到吸附平衡,吸附平衡容量为80.7 mg/g,远高于单独的CNT(28.4 mg/g)。动力学研究表明Pb(Ⅱ)在MnFe_(2)O_(4)/CNT上的吸附符合Elvoch动力学模型,说明吸附机理中存在化学吸附。Freundlich等温线模型能够很好地描述Pb(Ⅱ)在MnFe_(2)O_(4)/CNT上的吸附过程,其代表发生在非均匀表面的多分子层吸附。另外,吸附等温线实验中获得的MnFe_(2)O_(4)/CNT最大吸附容量为106.2 mg/g,展现出了对重金属Pb(Ⅱ)优异的吸附性能,在去除溶液中重金属中具有较大的应用潜力。根据X射线光电子能谱分析,表明吸附机理涉及到Pb(Ⅱ)与MnFe_(2)O_(4)表面羟基的络合。 展开更多
关键词 超重力技术 MnFe_(2)O_(4) 多壁碳纳米管 重金属
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南麂列岛东侧海域春秋季虾蟹类生物多样性 被引量:3
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作者 孙蓓蓓 俞存根 +3 位作者 刘惠 颜文超 张文俊 戴冬旭 《生物多样性》 CAS CSCD 北大核心 2019年第7期787-795,共9页
本文根据2017年11月和2018年5月对南麂列岛国家海洋自然保护区东侧海域进行渔业资源定点底拖网调查所获得的虾蟹类数据,对调查海域的虾蟹类群落结构及多样性进行了研究。结果表明:(1)共鉴定出调查海域的虾蟹类30种,其中虾类16种,隶属于1... 本文根据2017年11月和2018年5月对南麂列岛国家海洋自然保护区东侧海域进行渔业资源定点底拖网调查所获得的虾蟹类数据,对调查海域的虾蟹类群落结构及多样性进行了研究。结果表明:(1)共鉴定出调查海域的虾蟹类30种,其中虾类16种,隶属于1目6科12属,蟹类14种,隶属于1目5科6属;(2)秋季虾蟹类物种数高于春季,且春秋季物种数在整个调查海域大致呈现由北向南逐渐增多的趋势;(3)春季优势种依次为:三疣梭子蟹(Portunus trituberculatus)、双斑蟳(Charybdis bimaculata)、日本鼓虾(Alpheus juponicus)、细巧仿对虾(Parapenaeopsis tenella)和日本蟳(Charybdis japonica),秋季优势种均为蟹类,依次为三疣梭子蟹、双斑蟳和日本蟳;(4)虾蟹类Shannon-Wiener多样性指数(H’)和Pielou均匀度指数(J’)是春季大于秋季,丰富度指数(D)则是秋季远高于春季;(5)根据聚类分析(CLUSTER)与非度量多维标度排序(non-metric multidimensional scaling,nMDS)分析,可将虾蟹类划分为3个群落;(6)丰度/生物量曲线(abundance-biomass comparison curve, ABC曲线)显示,南麂列岛调查海域的虾蟹类群落处于稳定未受干扰的状态。 展开更多
关键词 虾蟹类 生物多样性 群落结构 南麂列岛东侧海域 相对重要性指数
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Micro-size picosecond-duration fast neutron source driven by a laser-plasma wakefield electron accelerator 被引量:1
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作者 Yaojun Li Jie Feng +7 位作者 Wenzhao Wang Junhao Tan Xulei Ge Feng Liu wenchao yan Guoqiang Zhang Changbo Fu Liming Chen 《High Power Laser Science and Engineering》 SCIE CAS CSCD 2022年第5期57-64,共8页
A pulsed fast neutron source is critical for applications of fast neutron resonance radiography and fast neutron absorption spectroscopy.However,due to the large transversal source size(of the order of mm)and long pul... A pulsed fast neutron source is critical for applications of fast neutron resonance radiography and fast neutron absorption spectroscopy.However,due to the large transversal source size(of the order of mm)and long pulse duration(of the order of ns)of traditional pulsed fast neutron sources,it is difficult to realize high-contrast neutron imaging with high spatial resolution and a fine absorption spectrum.Here,we experimentally present a micro-size ultra-short pulsed neutron source by a table-top laser-plasma wakefield electron accelerator driving a photofission reaction in a thin metal converter.A fast neutron source with source size of approximately 500μm and duration of approximately 36 ps has been driven by a tens of MeV,collimated,micro-size electron beam via a hundred TW laser facility.This micro-size ultra-short pulsed neutron source has the potential to improve the energy resolution of a fast neutron absorption spectrum dozens of times to,for example,approximately 100 eV at 1.65 MeV,which could be of benefit for high-quality fast neutron imaging and deep understanding of the theoretical model of neutron physics. 展开更多
关键词 fast neutrons high-power laser laser wakefield acceleration photofission reaction
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