Since China broke the blockade and opened the country to the outside world, many township enterprises develop quickly. Together with the pollution caused by China’s coal-burning as the main source of national energy,...Since China broke the blockade and opened the country to the outside world, many township enterprises develop quickly. Together with the pollution caused by China’s coal-burning as the main source of national energy, the pollution caused by small and medium-sized enterprises in towns and villages due to their small investment, low technology level and weak environmental awareness, and the pollution caused by a sharp increase in motor vehicle emissions lead to the fact that fog-haze has been rampant in China’s cities and urban agglomerations for nearly two decades, especially in the Beijing-Tianjin-Hebei region. This paper sorted out the current situation of fog-haze and analyzed the causes of fog-haze from the two aspects of natural and man-made causes, discussed the harms of fog-haze to human body, environment and life, and put forward the concrete measures to solve the fog-haze problem.展开更多
Computer-aided synthesis planning(CASP)integrates intuition of chemists and reliability of computers.As an in-between of unique creativities of human beings and unparalleled calculational capability of computers,CASP ...Computer-aided synthesis planning(CASP)integrates intuition of chemists and reliability of computers.As an in-between of unique creativities of human beings and unparalleled calculational capability of computers,CASP has become an important tool used in academic and industrial research.With explosion of novel chemical reactions,increasing of computer performance,and revolution of algorithms,CASP will play more significant roles in the synthetic chemistry field,inspiring novel and highly efficient syntheses of natural products and drug candidates.In this article,we review the progress in computational analysis of synthetic planning from rule-based programs(e.g.,LHASA and SECS)in the early stage to machine learning(e.g.,neural networks and seq2seq methods)in more recent years.展开更多
Reinforcing electronic and ionic conductivity is very important to realize the high-rate Li_(2)ZnTi_(3)O_(8)(LZTO)anode for Lithium-ion batteries(LIBs).Here,we reported a synthetic strategy toward in situ growth of ho...Reinforcing electronic and ionic conductivity is very important to realize the high-rate Li_(2)ZnTi_(3)O_(8)(LZTO)anode for Lithium-ion batteries(LIBs).Here,we reported a synthetic strategy toward in situ growth of homodispersed Li_(2)ZnTi_(3)O_(8)on ultralight 3D carbon aerogels(CAs)via facile heat treatment and activation process taking LiOH as activating agent.Such an optimized composite obtains a specific surface area of 154.427 m^(2) g^(-1) and a high pore volume.The strong interaction between the LZTO and N-doped CAs,a highly electrical conductivity and multidimensional ion transport channels of the hybrid result in a high capacity,outstanding high-rate performance and long cycle life.As a result,the NPC-LZTO electrode(NPC-LZTO-B)delivers a commendable reversible capacity at high-rate(e.g.162.4 mAh g^(-1) at 5 A g^(-1)(22 C)and 127.3 mAh g^(-1) at 10 A g^(-1))and durable long-term performance(capacity retention of 73% after 4500 cycles at 5 A g^(-1)).Moreover,the kinetic analysis confirms that the feature of pseudocapacitance boosts lithium-ion storage performance at high rate.Porous carbon aerogels frame constructed LZTO nanocomposite electrodes provide a facile way to design high durable LIBs anode.展开更多
文摘Since China broke the blockade and opened the country to the outside world, many township enterprises develop quickly. Together with the pollution caused by China’s coal-burning as the main source of national energy, the pollution caused by small and medium-sized enterprises in towns and villages due to their small investment, low technology level and weak environmental awareness, and the pollution caused by a sharp increase in motor vehicle emissions lead to the fact that fog-haze has been rampant in China’s cities and urban agglomerations for nearly two decades, especially in the Beijing-Tianjin-Hebei region. This paper sorted out the current situation of fog-haze and analyzed the causes of fog-haze from the two aspects of natural and man-made causes, discussed the harms of fog-haze to human body, environment and life, and put forward the concrete measures to solve the fog-haze problem.
基金support from the NSFC of China(21925106)Sichuan University(2020SCUNL204)for Dr.Bo Liu and Zhuang Wang.Dr.Wenhan Zhang is not supported by any funding.
文摘Computer-aided synthesis planning(CASP)integrates intuition of chemists and reliability of computers.As an in-between of unique creativities of human beings and unparalleled calculational capability of computers,CASP has become an important tool used in academic and industrial research.With explosion of novel chemical reactions,increasing of computer performance,and revolution of algorithms,CASP will play more significant roles in the synthetic chemistry field,inspiring novel and highly efficient syntheses of natural products and drug candidates.In this article,we review the progress in computational analysis of synthetic planning from rule-based programs(e.g.,LHASA and SECS)in the early stage to machine learning(e.g.,neural networks and seq2seq methods)in more recent years.
基金This work was financially supported by Science and Technology Commission of Shanghai Municipality(19DZ2271100).
文摘Reinforcing electronic and ionic conductivity is very important to realize the high-rate Li_(2)ZnTi_(3)O_(8)(LZTO)anode for Lithium-ion batteries(LIBs).Here,we reported a synthetic strategy toward in situ growth of homodispersed Li_(2)ZnTi_(3)O_(8)on ultralight 3D carbon aerogels(CAs)via facile heat treatment and activation process taking LiOH as activating agent.Such an optimized composite obtains a specific surface area of 154.427 m^(2) g^(-1) and a high pore volume.The strong interaction between the LZTO and N-doped CAs,a highly electrical conductivity and multidimensional ion transport channels of the hybrid result in a high capacity,outstanding high-rate performance and long cycle life.As a result,the NPC-LZTO electrode(NPC-LZTO-B)delivers a commendable reversible capacity at high-rate(e.g.162.4 mAh g^(-1) at 5 A g^(-1)(22 C)and 127.3 mAh g^(-1) at 10 A g^(-1))and durable long-term performance(capacity retention of 73% after 4500 cycles at 5 A g^(-1)).Moreover,the kinetic analysis confirms that the feature of pseudocapacitance boosts lithium-ion storage performance at high rate.Porous carbon aerogels frame constructed LZTO nanocomposite electrodes provide a facile way to design high durable LIBs anode.
