Here is an operable and rare strategy for copper-initiated radical dearomative 2,5-alkylarylation of furan. By means of this strategy, we realized the dearomatization of furans to construct spirooxindoles with good yi...Here is an operable and rare strategy for copper-initiated radical dearomative 2,5-alkylarylation of furan. By means of this strategy, we realized the dearomatization of furans to construct spirooxindoles with good yield in one-step via trihalomethylation/spirocyclization cascade progress.展开更多
基金supported by the National Natural Science Foundation of China(21871094)the Guangxi Key Laboratory of Zhuang and Yao Ethnic Medicine[(2014)No.32]We also thank the support of the Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation(No.2021CL04).
文摘Here is an operable and rare strategy for copper-initiated radical dearomative 2,5-alkylarylation of furan. By means of this strategy, we realized the dearomatization of furans to construct spirooxindoles with good yield in one-step via trihalomethylation/spirocyclization cascade progress.
