Structural and electronic effects boosting Ni-doped Mo_(2)C catalyst toward high-efficiency C-O/C-C bonds cleavage

The selective cleavage of C-O and C-C is facing a challenge in the field of catalysis.In the present work,we studied the influence of doped Ni on the structure and electronic properties,as well as the selective C-O/C-C bond cleavages in the hydrodeoxygenation of palmitic acid over Ni-Mo_(2)C catalyst.The catalytic activity on Ni doped Mo_(2)C with TOF of 6.9×10^(3)h^(-1)is much superior to intrinsic Mo_(2)C catalyst,which is also higher than most noble metal catalysts.Structurally,the doped Ni raises the active particle dispersion and the coordination numbers of Mo species(Mo-C and Mo-O),improves the graphitization degree to promote the electron transfer,and increases the amount of Lewis and Br?nsted acid,which are responsible for the excellent hydrodeoxygenation performance.The Ni promotes simultaneously C-O and C-C bonds cleavage to produce pentadecane and hexadecane owing to the increase of electron-rich Mo sites after Ni doping.These findings contribute to the understanding of the nature of Ni-doped Mo_(2)C on the roles as catalytic active sites for C-O and C-C bonds cleavage.

Stretchable on-skin touchless screen sensor enabled by ionic hydrogel

Screen sensors are the most commonly used human-machine interfaces in our everyday life,which have been extensively applied in personal electronics like cellphones.Touchless screen sensors are attracting growing interest due to their distinct advantages of high interaction freedom,comfortability,and hand hygiene.However,the material compositions of current touchless screen sensors are rigid and fragile,hardly meeting the needs of wearable and stretchable on-skin electronics development.Additionally,these touchless screen sensors are also restricted by high power consumption,limited gesture types of recognition,and the requirement of light conditions.Here,we report a stretchable on-skin touchless screen sensor(OTSS)enabled by an ionic hydrogel-based triboelectric nanogenerator(TENG).Compared with current touchless screen sensors,the OTSS is stretchable,self-powered,and competent to recognize diverse gestures by making use of charges naturally carried on fingers without the need of sufficient light conditions.An on-skin noncontact screen operating system is further demonstrated on the basis of the OTSS,which could unlock a cellphone interface in touchless operation mode on the human skin.This work for the first time introduces the on-skin touchless concept to screen sensors and offers a direction to develop new-generation screen sensors for future cellphones and personal electronics.

Characterization of the asymmetric evolving yield and flow of 6016-T4 aluminum alloy and DP490 steel

6016-T4 aluminum alloy and DP490 steel were systematically tested under 24 proportional loading paths,including uniaxial tensile tests with a 15°increment,uniaxial compressive and simple shear tests with a 45°increment,and biaxial tensile tests using cruciform specimens.Cruciform specimens in the rolling/transverse and 45°/135°sampling directions were tested with seven and four different stress ra-tios,respectively.The normal and diagonal planes plastic work contours and the yield stresses under uniaxial tension and compression were measured to investigate the anisotropic yield.Meanwhile,the normal and diagonal planes directions of plastic strain rate and the rα-values under uniaxial tension and compression were characterized to confirm the plastic flow.Several existing asymmetric yield crite-ria under the associated and non-associated flow rules were comprehensively evaluated to describe the asymmetric plastic anisotropy of 6016-T4 aluminum alloy and DP490 steel.The results suggest that in the investigated yield criteria,the non-associated models can predict the tension and compression asym-metry of materials more accurately than the associated models,and the function of stress triaxiality can more effectively describe the asymmetric yield behavior than the first stress invariant.In addition,the pure shear stress states are helpful in assessing the validity and applicability of advanced asymmetric yield stress functions,and the inspection of diagonal plane plastic work contours containing more pure shear stress states should prioritized over that of normal plane plastic work contours.The evaluation of plastic potential functions should not only consider the prediction accuracy of the normal plane di-rections of plastic strain rate,but also further check the diagonal plane directions of plastic strain rate.Expressing mechanical properties as a function of equivalent plastic strain to calibrate parameters of the yield criterion allows the continuous capture of anisotropic evolution of the asymmetric yield surface and the changes in the asymmetric plastic potential surface.

A Hot Cracking Initiation Criterion Based on Solidification Liquid Film Characteristic and Microstructure

Herein,a hot cracking initiation criterion based on the characteristics of solidification liquid film and the microstructure was proposed,which integrated both the mechanical and non-mechanical factors during solidification.The criterion also took the effect of the shrinkage volume of the solid-liquid two-phase in the mushy zone,the flow behavior of the liquid film and the microstructure on the feeding behavior into account.Meanwhile,the effect factors of hot cracking initiation such as alloy composition,microstructure,mold design and process condition were included in this criterion,and it could quantitatively calculate whether hot cracks occurred under a certain state or not during solidification.The criterion was utilized to predict whether hot cracks occurred in Al-4.0 wt%Cu alloy in different initial solidification states or not,which was consistent with the experimental results and verified its reliability.According to the criterion expression,Vfeeding*was related with five effect factors includingη,ΔP*,l*,r*and n,in which r*and n were in positive correlation with Vfeeding*whileη,ΔP*and l*were in negative correlation with that,which provided a good instructive significance for mold design,process optimization and composition and microstructure regulation of alloys and simultaneously further enriched the mechanism and influencing factors of hot cracking initiation.Furthermore,a multiscale simulation method for calculating the characteristic parameters of hot tearing behavior during solidification was also provided in this study.

Infuence of Liquid Film Characteristics on Hot Cracking Initiation in Al–Cu Alloys at the End of Solidifcation

In this study,Al–4Cu alloy specimens with spherical grains and liquid flms were obtained by isothermal reheating treatment.The hot cracking of the solidifcation process was determined using a modifed constrained rod casting experimental apparatus,and the efect of liquid flm characteristics at the end of solidifcation on hot cracking initiation of Al–4Cu alloys was systematically investigated by combining molecular dynamics simulations and other methods.With the extension of soaking time,the liquid fraction(liquid flm fraction at the end of solidifcation)and grain shape factor increased with higher isothermal reheating temperatures.Additionally,the widened flling channel decreased the hot cracking initiation temperature and the critical hot cracking shrinkage stress was found to increase,thus reducing the hot cracking severity in Al–4Cu alloys.Molecular dynamics simulations revealed that with the extension of soaking time,the composition of the liquid flm changed at diferent isothermal reheating temperatures,but the short-range structure and atomic ordering of the liquid flm remained the same.The activity of the liquid flm increased in equilibrium,leading to a decrease in viscosity and an increase in fuidity,which contributed to the flling behaviour.After isothermal reheating at 640℃for 60 min,the liquid fraction reached the maximum,and the viscosity of the liquid flm was the minimum.In addition,almost no hot cracks were found.

Cascade-Cas3 facilitates high-accuracy genome engineering in Pseudomona s using phage-encoded homologous recombination

Phage-encoded homologous recombination(PEHR)is an efficient tool for bacterial genome editing.We previously developed and utilized a Pseudomonas-specific PEHR system.However,when using the PEHR system for Pseu-domonas genome editing,false positives can be a problem.In this study,we combined a compact Cascade-Cas3 system from P.aeruginosa(PaeCas3c)with a Pseudomonas-specific PEHR system,and the results of our recom-bineering assay showed that this compact Cascade-Cas3 system can significantly improve PEHR recombineering accuracy.