In this paper, a low-profile wideband dielectric resonator antenna(DRA) with a very compact planar size is investigated. The antenna consists of a high permittivity dielectric sheet on the top, a low permittivity subs...In this paper, a low-profile wideband dielectric resonator antenna(DRA) with a very compact planar size is investigated. The antenna consists of a high permittivity dielectric sheet on the top, a low permittivity substrate in the middle, and a probe feeding structure at the bottom. By digging an annular slot in the designated area of the square dielectric sheet, the resonant frequency of fundamental TE111 mode can be effectively increased to be close to the high-order TE131 mode. The two modes can be finally merged together, yielding a wide impedance bandwidth of16.6%. Most importantly, the combination of the two modes is done on the premise of a fixed antenna planar size, which can be very compact and suitable for beam-scanning applications. A probe feeding structure is used to excite the DRA, making the antenna simple and practical to be integrated with other RF circuits. For verification, antenna prototypes with singlefeed linear polarization and differential-feed dual polarization were fabricated and measured. Reasonable agreement between the measured and simulated results is observed.展开更多
Hard carbon (HC) has been considered as promising anode material for sodium-ion batteries (SIBs).The optimization of hard carbon’s microstructure and solid electrolyte interface (SEI) property are demonstrated effect...Hard carbon (HC) has been considered as promising anode material for sodium-ion batteries (SIBs).The optimization of hard carbon’s microstructure and solid electrolyte interface (SEI) property are demonstrated effective in enhancing the Na+storage capability,however,a one-step regulation strategy to achieve simultaneous multi-scale structures optimization is highly desirable.Herein,we have systematically investigated the effects of boron doping on hard carbon’s microstructure and interface chemistry.A variety of structure characterizations show that appropriate amount of boron doping can increase the size of closed pores via rearrangement of carbon layers with improved graphitization degree,which provides more Na+storage sites.In-situ Fourier transform infrared spectroscopy/electrochemical impedance spectroscopy (FTIR/EIS) and X-ray photoelectron spectroscopy (XPS) analysis demonstrate the presence of more BC3and less B–C–O structures that result in enhanced ion diffusion kinetics and the formation of inorganic rich and robust SEI,which leads to facilitated charge transfer and excellent rate performance.As a result,the hard carbon anode with optimized boron doping content exhibits enhanced rate and cycling performance.In general,this work unravels the critical role of boron doping in optimizing the pore structure,interface chemistry and diffusion kinetics of hard carbon,which enables rational design of sodium-ion battery anode with enhanced Na+storage performance.展开更多
Six bis-tridentate and two tris-bidentate cyclometalated ruthenium complexes with a 1,2,3-triazole-containing ligand have been prepared and characterized. Single-crystal X-ray analyses of complexes [(MeOptpy)Ru(Bud...Six bis-tridentate and two tris-bidentate cyclometalated ruthenium complexes with a 1,2,3-triazole-containing ligand have been prepared and characterized. Single-crystal X-ray analyses of complexes [(MeOptpy)Ru(Budtab)]-(PF6) and [(Mebip)Ru(Budtab)](PF6) are presented, where MeOptpy is 4′-p-methoxyphenyl-2,2′:6′,2"-terpyridine, Budtab is the 2-deprotonated form of 1,3-di(N-n-butyl-l,2,3-triazol-4-yl)benzene, and Mebip is bis(N-methyl-ben-zimidazolyl)pyridine. The electronic properties of these complexes are probed by spectroscopic and electrochemical analyses. Time-dependent density functional theory calculations have been performed to assist the assignment of the absorption spectra.展开更多
A compact input-reflectionless balanced bandpass filter(BPF)with flexible bandwidth(BW)using a three-line coupled structure(TLCS)is presented in this paper.For the differential mode(DM),the TLCS is applied to achieve ...A compact input-reflectionless balanced bandpass filter(BPF)with flexible bandwidth(BW)using a three-line coupled structure(TLCS)is presented in this paper.For the differential mode(DM),the TLCS is applied to achieve the bandpass response;meanwhile,the input coupled-feed line of the TLCS is reused in the input absorption network.This design shows a good fusion of the absorptive and BPF sections,effectively reducing the circuit size,and the BWs of the two sections that can be controlled separately result in a flexibly controllable DM response BW of the proposed input-reflectionless balanced BPF.Detailed analyses of the ratio of the two-part BWs have been given for the first time,which is vital for the passband flatness and reflectionless feature.In the codesign of this work,the input-reflectionless DM bandpass response can be optimized easily,while wideband common mode(CM)noise absorption is achieved by the input absorption network.To verify the design method,a prototype with a compact layout(0.52λ×0.36λ)is designed and measured in the 0-7.0 GHz range.The DM center frequency(f0)is 2.45 GHz with a measured 3 dB fractional bandwidth of 31.4%.The simulation and measurement results with good agreement are presented,showing good performance,e.g.,low insertion loss(0.43 dB),wide upper stopband for the DM bandpass response(over 20 dB rejection level up to 2.72f0),and wideband DM reflectionless and CM noise absorption(fractional absorption bandwidth of 285.7%).展开更多
基金supported by the National Natural Science Foundation of China under Grant 62071256National Natural Science Foundation of Jiangsu under Grant BK20201438+1 种基金supported by State Key Laboratory of Millimeter Waves (Nanjing) and Nantong Research Institute for Advanced Communication Technologies (Nantong)sponsored by Qing Lan Project of Jiangsu Province。
文摘In this paper, a low-profile wideband dielectric resonator antenna(DRA) with a very compact planar size is investigated. The antenna consists of a high permittivity dielectric sheet on the top, a low permittivity substrate in the middle, and a probe feeding structure at the bottom. By digging an annular slot in the designated area of the square dielectric sheet, the resonant frequency of fundamental TE111 mode can be effectively increased to be close to the high-order TE131 mode. The two modes can be finally merged together, yielding a wide impedance bandwidth of16.6%. Most importantly, the combination of the two modes is done on the premise of a fixed antenna planar size, which can be very compact and suitable for beam-scanning applications. A probe feeding structure is used to excite the DRA, making the antenna simple and practical to be integrated with other RF circuits. For verification, antenna prototypes with singlefeed linear polarization and differential-feed dual polarization were fabricated and measured. Reasonable agreement between the measured and simulated results is observed.
基金National Key Research and Development Program of China (2022YFE0206300)National Natural Science Foundation of China (U21A2081,22075074, 22209047)+3 种基金Guangdong Basic and Applied Basic Research Foundation (2024A1515011620)Hunan Provincial Natural Science Foundation of China (2024JJ5068)Foundation of Yuelushan Center for Industrial Innovation (2023YCII0119)Student Innovation Training Program (S202410532594,S202410532357)。
文摘Hard carbon (HC) has been considered as promising anode material for sodium-ion batteries (SIBs).The optimization of hard carbon’s microstructure and solid electrolyte interface (SEI) property are demonstrated effective in enhancing the Na+storage capability,however,a one-step regulation strategy to achieve simultaneous multi-scale structures optimization is highly desirable.Herein,we have systematically investigated the effects of boron doping on hard carbon’s microstructure and interface chemistry.A variety of structure characterizations show that appropriate amount of boron doping can increase the size of closed pores via rearrangement of carbon layers with improved graphitization degree,which provides more Na+storage sites.In-situ Fourier transform infrared spectroscopy/electrochemical impedance spectroscopy (FTIR/EIS) and X-ray photoelectron spectroscopy (XPS) analysis demonstrate the presence of more BC3and less B–C–O structures that result in enhanced ion diffusion kinetics and the formation of inorganic rich and robust SEI,which leads to facilitated charge transfer and excellent rate performance.As a result,the hard carbon anode with optimized boron doping content exhibits enhanced rate and cycling performance.In general,this work unravels the critical role of boron doping in optimizing the pore structure,interface chemistry and diffusion kinetics of hard carbon,which enables rational design of sodium-ion battery anode with enhanced Na+storage performance.
文摘Six bis-tridentate and two tris-bidentate cyclometalated ruthenium complexes with a 1,2,3-triazole-containing ligand have been prepared and characterized. Single-crystal X-ray analyses of complexes [(MeOptpy)Ru(Budtab)]-(PF6) and [(Mebip)Ru(Budtab)](PF6) are presented, where MeOptpy is 4′-p-methoxyphenyl-2,2′:6′,2"-terpyridine, Budtab is the 2-deprotonated form of 1,3-di(N-n-butyl-l,2,3-triazol-4-yl)benzene, and Mebip is bis(N-methyl-ben-zimidazolyl)pyridine. The electronic properties of these complexes are probed by spectroscopic and electrochemical analyses. Time-dependent density functional theory calculations have been performed to assist the assignment of the absorption spectra.
基金Project supported by the National Natural Science Foundation of China(No.20201438)。
文摘A compact input-reflectionless balanced bandpass filter(BPF)with flexible bandwidth(BW)using a three-line coupled structure(TLCS)is presented in this paper.For the differential mode(DM),the TLCS is applied to achieve the bandpass response;meanwhile,the input coupled-feed line of the TLCS is reused in the input absorption network.This design shows a good fusion of the absorptive and BPF sections,effectively reducing the circuit size,and the BWs of the two sections that can be controlled separately result in a flexibly controllable DM response BW of the proposed input-reflectionless balanced BPF.Detailed analyses of the ratio of the two-part BWs have been given for the first time,which is vital for the passband flatness and reflectionless feature.In the codesign of this work,the input-reflectionless DM bandpass response can be optimized easily,while wideband common mode(CM)noise absorption is achieved by the input absorption network.To verify the design method,a prototype with a compact layout(0.52λ×0.36λ)is designed and measured in the 0-7.0 GHz range.The DM center frequency(f0)is 2.45 GHz with a measured 3 dB fractional bandwidth of 31.4%.The simulation and measurement results with good agreement are presented,showing good performance,e.g.,low insertion loss(0.43 dB),wide upper stopband for the DM bandpass response(over 20 dB rejection level up to 2.72f0),and wideband DM reflectionless and CM noise absorption(fractional absorption bandwidth of 285.7%).