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污水处理中雌酮的定量分析 被引量:8
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作者 阳春 胡碧波 wheatley andrew 《重庆大学学报(自然科学版)》 EI CAS CSCD 北大核心 2009年第6期716-720,共5页
采用酶联免疫吸附检测(ELISA)试剂盒定量分析了某采用生物脱氮活性污泥工艺的污水厂中的原水、一级处理出水、二级处理出水、尾水和出水口下游受纳河水中的雌酮浓度,分析方法的定量检测限为0.5 ng/L。ELISA分析中增加的凝胶色谱净化步... 采用酶联免疫吸附检测(ELISA)试剂盒定量分析了某采用生物脱氮活性污泥工艺的污水厂中的原水、一级处理出水、二级处理出水、尾水和出水口下游受纳河水中的雌酮浓度,分析方法的定量检测限为0.5 ng/L。ELISA分析中增加的凝胶色谱净化步骤可降低E1检测值73.0%的假阳性,使其检测结果平均值从液相色谱-飞行时间质谱联用(HPLC-MS(TOF))的对照分析结果平均值的1.52倍降为1.15倍。ELISA分析检测值的假阳性与水样的污染程度呈正相关。 展开更多
关键词 污水分析 内分泌干扰物 雌酮 酶联免疫吸附检测 液相色谱分行时间质谱检测
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Removal characteristics of steroid estrogens in trickling filters 被引量:3
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作者 阳春 胡碧波 +1 位作者 wheatley andrew GLASGOW Graeme 《Journal of Central South University》 SCIE EI CAS 2009年第S1期357-362,共6页
The discharge of steroid estroens from sewage treatment works (STW) is to be regulated by Environmental Quality Standard in the UK,thus requiring the understanding of removal characteristics of steroid estroens in tri... The discharge of steroid estroens from sewage treatment works (STW) is to be regulated by Environmental Quality Standard in the UK,thus requiring the understanding of removal characteristics of steroid estroens in trickling filters to benefit UK water industry with trickling filters used in 75% STWs. Two pilot-scale trickling filters were operated in parallel to treat synthetic sewage spiked with oestrone (E1),oestradiol (E2) and 17α-ethinyl oestradiol (EE2) at environmentally related concentrations. Control experiments show that biodegradation is the dominant removal mechanism although adsorption onto biofilm solids prior to biodegradation would be part of the overall mechanisms of estrogen removal. Approximately 44.7%-58.9% is removed by the pilot trickling filter normally operated,whilst the 1:1 recirculation increases 29.0%-32.2% estrogen removals by improved wetting rate and hydraulic retention time supported by tracer experiment with lithium chloride. Extra feed solids with 32.0% higher suspended solids levels inhibited estrogen removals by 10.8%-34.4% rather than helping bridge adsorption to the biofilm,and the change of particle characteristics with higher adsorption potency would benefit the removal. 展开更多
关键词 ESTROGEN WASTEWATER TREATMENT trickling FILTER SORPTION BIODEGRADATION
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