The sorption of and from aqueous solution on AFN membrane has been studied and the equilibrium isotherms determined. The experimental data have been analyzed using the Langmuir, Freundlich, Temkin and Dubinin-Radushke...The sorption of and from aqueous solution on AFN membrane has been studied and the equilibrium isotherms determined. The experimental data have been analyzed using the Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models at different temperatures varying from 283 to 313 K. The results were analyzed using three kinetic models, Lagergen first order, second order and the Elovich model. The obtained results show that the best-fit correlation of the experimental data was obtained using the second order model. Thermodynamic parameters for the adsorption system were determined at 283, 298 and 313 K.展开更多
Saline waters treatment has become increasingly important for drinking water supply in a greater part of the world. However, some serious limitations had recently been discovered during water treatment, among them the...Saline waters treatment has become increasingly important for drinking water supply in a greater part of the world. However, some serious limitations had recently been discovered during water treatment, among them the boron problem seems to have a critical meaning. According to the WHO regulations (2011), the boron concentration should be reduced to less than 2.4 mg/L for drinking water. The purpose of this study is to investigate the feasibility of electrocoagulation (EC) as a pretreatment process to remove boron from saline waters. To optimize the experimental conditions of boron removal, the effects of some parameters were studied such as inter-electrode distance (die), electrode connection mode, (S/V) ratio, pHi and initial conductivity of the solution (σi). Subsequently, an experimental design methodology was implemented to evaluate statistically the most significant operating parameters. The effects of current density, EC time and initial boron concentration and their mutual interaction were investigated using 23 full factorial design. At optimal conditions, boron removal from synthetic aqueous solutions containing initial boron concentrations of 5 and 50 mg/L reached 81% and 79%, respectively. Applied to boron removal from seawater samples, EC reduces boron concentration to less to 2.4 mg/L with excessive energy consumption under optimal parameters.展开更多
文摘The sorption of and from aqueous solution on AFN membrane has been studied and the equilibrium isotherms determined. The experimental data have been analyzed using the Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models at different temperatures varying from 283 to 313 K. The results were analyzed using three kinetic models, Lagergen first order, second order and the Elovich model. The obtained results show that the best-fit correlation of the experimental data was obtained using the second order model. Thermodynamic parameters for the adsorption system were determined at 283, 298 and 313 K.
文摘Saline waters treatment has become increasingly important for drinking water supply in a greater part of the world. However, some serious limitations had recently been discovered during water treatment, among them the boron problem seems to have a critical meaning. According to the WHO regulations (2011), the boron concentration should be reduced to less than 2.4 mg/L for drinking water. The purpose of this study is to investigate the feasibility of electrocoagulation (EC) as a pretreatment process to remove boron from saline waters. To optimize the experimental conditions of boron removal, the effects of some parameters were studied such as inter-electrode distance (die), electrode connection mode, (S/V) ratio, pHi and initial conductivity of the solution (σi). Subsequently, an experimental design methodology was implemented to evaluate statistically the most significant operating parameters. The effects of current density, EC time and initial boron concentration and their mutual interaction were investigated using 23 full factorial design. At optimal conditions, boron removal from synthetic aqueous solutions containing initial boron concentrations of 5 and 50 mg/L reached 81% and 79%, respectively. Applied to boron removal from seawater samples, EC reduces boron concentration to less to 2.4 mg/L with excessive energy consumption under optimal parameters.
