Ensuring high power conversion efficiency,partially or completely replacing Pt electrodes with inexpensive materials is one of the important development directions of dye-sensitized solar cells(DSSCs).In this work,we ...Ensuring high power conversion efficiency,partially or completely replacing Pt electrodes with inexpensive materials is one of the important development directions of dye-sensitized solar cells(DSSCs).In this work,we have developed a threecomponent(MWCNTs,carbon black and graphite) carbon(tri-carbon) electrode material for DSSC devices combined with the advantages of high electron transfer kinetics of MWCNTs,plentiful catalytic sites in crystal edges of carbon black and superior electrical conductivity and catalytic activity of graphite.Using a tri-carbon electrode,a Pt electrode,and two N719-sensitized photoanodes,a parallel tandem dye-sensitized solar cells are assembled obtaining a high PCE of 10.26%(V_(OC)=0.70 V,J_(SC)=19.99 mA/cm~2,FF=73.33%).It opens up a new avenue for the development of low-cost and highperformance DSSCs.展开更多
A novel maximum power point tracking method based on sliding mode control and average state model of PV generation systems is developed.This method consists of two parts:term of constant control and term of index cont...A novel maximum power point tracking method based on sliding mode control and average state model of PV generation systems is developed.This method consists of two parts:term of constant control and term of index control.It is different from the conventional sliding mode control which uses a constant speed control law.The developed method uses a controllable sliding mode switching function which can automatically adjust the approaching speed,so as to enable the photovoltaic system to achieve fast dynamic response and stable output power.System simulations using MATLAB are performed.Compared with conventional methods,simulation results show that maximum power point tracking times for the novel method both in start-up phase and in cases of environmental changes can be shorten by more than 50%.A experimental platform of 150W PV system has been established to conduct tests.Experimental results show that the maximum power point tracking times both in start-up phase and in load stepping phase including the illumination change phase,can be significantly decreased.These results indicate that the developed method owns better dynamic response than constant speed control law.It can be used in photovoltaic generation system.展开更多
基金supported financially by the National Natural Science Foundation of China(Nos.21788102,22075083)the Open Foundation of the Key Laboratory of Functional Inorganic Material Chemistry+1 种基金the Ministry of Education National Key R&D Program of China(No.2017YFB0309603)the Programme of Introducing Talents of Discipline to Universities(No.B16017)。
文摘Ensuring high power conversion efficiency,partially or completely replacing Pt electrodes with inexpensive materials is one of the important development directions of dye-sensitized solar cells(DSSCs).In this work,we have developed a threecomponent(MWCNTs,carbon black and graphite) carbon(tri-carbon) electrode material for DSSC devices combined with the advantages of high electron transfer kinetics of MWCNTs,plentiful catalytic sites in crystal edges of carbon black and superior electrical conductivity and catalytic activity of graphite.Using a tri-carbon electrode,a Pt electrode,and two N719-sensitized photoanodes,a parallel tandem dye-sensitized solar cells are assembled obtaining a high PCE of 10.26%(V_(OC)=0.70 V,J_(SC)=19.99 mA/cm~2,FF=73.33%).It opens up a new avenue for the development of low-cost and highperformance DSSCs.
基金This work was supported in part by the hunan natural science foundation(2018jj2367),hunan science and technology plan project(2016tp1023).
文摘A novel maximum power point tracking method based on sliding mode control and average state model of PV generation systems is developed.This method consists of two parts:term of constant control and term of index control.It is different from the conventional sliding mode control which uses a constant speed control law.The developed method uses a controllable sliding mode switching function which can automatically adjust the approaching speed,so as to enable the photovoltaic system to achieve fast dynamic response and stable output power.System simulations using MATLAB are performed.Compared with conventional methods,simulation results show that maximum power point tracking times for the novel method both in start-up phase and in cases of environmental changes can be shorten by more than 50%.A experimental platform of 150W PV system has been established to conduct tests.Experimental results show that the maximum power point tracking times both in start-up phase and in load stepping phase including the illumination change phase,can be significantly decreased.These results indicate that the developed method owns better dynamic response than constant speed control law.It can be used in photovoltaic generation system.