U.V. irradiation of N,N-dimethylaniline (DMA) in the presence of 7,7-dichloronorcarane (DCN) in acetonitrile solution produces N-methyianiline, 4,4'-methylenebis-(N,N-dimethylaniline), N-(4'-N',N'-dime...U.V. irradiation of N,N-dimethylaniline (DMA) in the presence of 7,7-dichloronorcarane (DCN) in acetonitrile solution produces N-methyianiline, 4,4'-methylenebis-(N,N-dimethylaniline), N-(4'-N',N'-dimethylaminobenzyl)-N-methylaniline and 7-chloronorcarane as the major products. A photoinduced electron transfer mechanism is proposed.展开更多
U.V. irradiation of N-methylphenothiazine 1 in carbon tetrachloride produced 3-(phenothiazin-N-yl-carbonyl)-N-methylphenothiazine 2 together with the radical cation salt 1(+) CCl4- and methyl chloride, presumably via ...U.V. irradiation of N-methylphenothiazine 1 in carbon tetrachloride produced 3-(phenothiazin-N-yl-carbonyl)-N-methylphenothiazine 2 together with the radical cation salt 1(+) CCl4- and methyl chloride, presumably via a photoinduced electron transfer mechanism.展开更多
文摘U.V. irradiation of N,N-dimethylaniline (DMA) in the presence of 7,7-dichloronorcarane (DCN) in acetonitrile solution produces N-methyianiline, 4,4'-methylenebis-(N,N-dimethylaniline), N-(4'-N',N'-dimethylaminobenzyl)-N-methylaniline and 7-chloronorcarane as the major products. A photoinduced electron transfer mechanism is proposed.
文摘U.V. irradiation of N-methylphenothiazine 1 in carbon tetrachloride produced 3-(phenothiazin-N-yl-carbonyl)-N-methylphenothiazine 2 together with the radical cation salt 1(+) CCl4- and methyl chloride, presumably via a photoinduced electron transfer mechanism.
