Novel ternary Ag/CeVO_4/g-C_3N_4 nanocomposite as a highly efficient visible-light-driven photocatalyst

The CeVO_4/graphitic C_3N_4 composites have exhibited much enhanced photocatalytic property for degrading methylene blue(MB) pollutant under visible light irradiation compared with single-phase g-C_3N_4 or CeVO_4. The composite S5 obtained from an optimized mass ratio(5%) of CeVO_4 to dicyanamide(DCDA) exhibits the highest photocatalytic activity. Here, ternary Ag/CeVO_4/g-C_3N_4 composites denoted as X%Ag/S5 were prepared by an ultrasonic precipitation method to improve the photocatalytic property of S5. The TEM images show that CeVO_4 and Ag nanoparticles are well distributed on the layered g-C_3N_4, which agree well with the XRD results. The UV spectra show that the 7%Ag/S5 sample has the widest absorption range and the enhanced absorption intensity under visible light irradiation. The corresponding band gap of 7%Ag/S5(2.5 eV) is much lower than that of S5(2.65 eV). The corresponding k value of 7%Ag/S5 is much higher than those of g-C_3N_4 and CeVO_4. The degradation experiments for MB solution suggest that the 7%Ag/S5 sample has the optimal photocatalytic performance, which can degrade MB solution completely within 120 min. The enhanced photocatalytic property of the composites is ascribed to not only the effect of heterojunction structure, but also the surface plasma resonance effect of Ag nanoparticles.

Construction of hybrid Z-scheme graphitic C_(3)N_(4)/reduced TiO_(2) microsphere with visible-light-driven photocatalytic activity

A novel Z-scheme graphitic C_(3)N_(4)/reduced TiO_(2)microsphere(g-C_(3)N_(4)/r-TiO_(2))has been successfully synthesized by a solvothermal method.The as-prepared samples with different contents of g-C_(3)N_(4)were characterized by X-ray diffraction,electron paramagnetic resonance,scanning electron microscope,UV evis.diffuse reflectance and photoluminescence spectra.The r-TiO_(2)microspheres are aggregated on the surface of g-C_(3)N_(4)sheets in the as-prepared g-C_(3)N_(4)/r-TiO_(2)composites.All g-C_(3)N_(4)/r-TiO_(2)catalysts show enhanced photocatalytic activity for the degradation of rhodamine B under visible light irradiation.It could be attributed to these influences of oxygen vacancy(changing the band gap of TiO_(2)),the large specific surface area(providing much more active sites for photocatalytic reaction),and the synergetic effect between g-C_(3)N_(4)and r-TiO_(2)(promoting the separation for photoinduced electron-hole pairs).Moreover,the Z-scheme carriers transfer mechanism in the photocatalytic process has been discussed through trapping experiments of active species.The work demonstrates the strategies of the construction of Z-scheme carriers transfer system,the introduction of oxygen vacancy and structure designing are beneficial to design materials toward solar energy conversion like contaminant degradation.