The adsorption kinetics of Pb2+ in rocks has been studied using ion selective electrodes and atomic absorption spectrophotometer. The results showed that the adsorption process is a fractal-like reaction. The adsorpti...The adsorption kinetics of Pb2+ in rocks has been studied using ion selective electrodes and atomic absorption spectrophotometer. The results showed that the adsorption process is a fractal-like reaction. The adsorption rate was relatively high before 30 minutes, and then dropped. The saturated adsorption capacity (a) of Pb2+ and kinetic parameters (b, α , D and k) increased with increasing initial concentrations of Pb2+. These parameters (except a) decreased while Na+ was present in the solution. Furthermore, the smaller the rocks were in grain size, the bigger these kinetic parameters would be, though the parameter a was almost constant.展开更多
Effects of temperature and pressure differences on water seepage in breccia were investigated by using the physicochemical seepage instrument.The results show that the relationship of flow and pressure differences can...Effects of temperature and pressure differences on water seepage in breccia were investigated by using the physicochemical seepage instrument.The results show that the relationship of flow and pressure differences can be expressed by a linear equation,and the seepage coefficient is linearly correlated with temperature.The relation-ship between seepage flow and temperature could be described with the linear equation.The constant and tempera-ture seepage coefficient showed a linear relation with pressure.Binary quantitative equation for the seepage flow,temperature and pressure was obtained,and explained with experimental data and theoretical analysis.展开更多
文摘The adsorption kinetics of Pb2+ in rocks has been studied using ion selective electrodes and atomic absorption spectrophotometer. The results showed that the adsorption process is a fractal-like reaction. The adsorption rate was relatively high before 30 minutes, and then dropped. The saturated adsorption capacity (a) of Pb2+ and kinetic parameters (b, α , D and k) increased with increasing initial concentrations of Pb2+. These parameters (except a) decreased while Na+ was present in the solution. Furthermore, the smaller the rocks were in grain size, the bigger these kinetic parameters would be, though the parameter a was almost constant.
文摘Effects of temperature and pressure differences on water seepage in breccia were investigated by using the physicochemical seepage instrument.The results show that the relationship of flow and pressure differences can be expressed by a linear equation,and the seepage coefficient is linearly correlated with temperature.The relation-ship between seepage flow and temperature could be described with the linear equation.The constant and tempera-ture seepage coefficient showed a linear relation with pressure.Binary quantitative equation for the seepage flow,temperature and pressure was obtained,and explained with experimental data and theoretical analysis.