Thermogravimetry-differential scanning calorimetry-mass spectrometry-Fourier transform infrared spectrometry（TG-DSC-MS-FTIR） simultaneous analysis was used to study the effects of 10.7 μm and 40 nm Al on the therma...Thermogravimetry-differential scanning calorimetry-mass spectrometry-Fourier transform infrared spectrometry（TG-DSC-MS-FTIR） simultaneous analysis was used to study the effects of 10.7 μm and 40 nm Al on the thermal decomposition of the Hexogen/ammonium perchlorate（RDX/AP,1/2,mass ratio） mixture.TG-DSC results show that there are two mass loss processes for the thermal decomposition of RDX/AP/Al.The first one is mainly ascribed to the thermal decomposition of RDX.The reaction rate of RDX/AP/10.7 μm Al is so fast that the apparent activation energy,calculated by model-free Friedman method,is negative,which is the same as that of RDX/AP.30％（mass fraction） 40 nm Al added in RDX/AP change the activation energy from negative to positive value.The second mass loss process of the RDX/AP/A1 mixture is ascribed to the thermal decomposition of AP.This process can be divided into three stages for RDX/AP with and without Al.The kinetics model is not changed in the presence of micro-sized Al,while it is changed from CnB/D1/D1 to CnB/D1/D4 after the addition of 40 nm Al to RDX/AP.The reaction rate constant of the first stage and the end temperature of the second stage decrease,while the end temperatures of the third stage increase in the presence of 40 nm Al.The MS-FTIR results show there is a competition between the formation reactions of HNCO,N2O and NO2 during the second mass loss process.展开更多
Primary solidification phase and lamellar orientation are investigated in Ti-45Al-7Nb alloy at very high ratio of temperature gradient to growth rate （G/v） by a liquid-metal-cooled directionally solidified method. I...Primary solidification phase and lamellar orientation are investigated in Ti-45Al-7Nb alloy at very high ratio of temperature gradient to growth rate （G/v） by a liquid-metal-cooled directionally solidified method. It shows that Ti-45Al-7Nb alloy solidifies with primary ct phase. Longitudinal （parallel to growth direction） microstructure shows that a dendrites in solid-liquid mushy zone are discontinuous and transverse mierostructure of a dendrites is worm-like feature. Growth direction of a phase is about 80° away from （0001）,a direction, and close to （1120） a direction. The corresponding lamellar orientation is aligned at the angle of about 10° to growth direction, which is consistent with a-dendrite growth direction according to Blackburn orientation relationship. Therefore, due to the altered growth direction of a phase, the lamellar orientation in Ti-45Al-7Nb alloy is controlled at the G/v ratio of 5 × 10^9 K.sm^-2.展开更多
基金Supported by the National Natural Science Foundation of China（Nos.11172042, 51304024） and the Scientific Research Foundation for Retumed Overseas Students, Ministry of Education, China.
文摘Thermogravimetry-differential scanning calorimetry-mass spectrometry-Fourier transform infrared spectrometry（TG-DSC-MS-FTIR） simultaneous analysis was used to study the effects of 10.7 μm and 40 nm Al on the thermal decomposition of the Hexogen/ammonium perchlorate（RDX/AP,1/2,mass ratio） mixture.TG-DSC results show that there are two mass loss processes for the thermal decomposition of RDX/AP/Al.The first one is mainly ascribed to the thermal decomposition of RDX.The reaction rate of RDX/AP/10.7 μm Al is so fast that the apparent activation energy,calculated by model-free Friedman method,is negative,which is the same as that of RDX/AP.30％（mass fraction） 40 nm Al added in RDX/AP change the activation energy from negative to positive value.The second mass loss process of the RDX/AP/A1 mixture is ascribed to the thermal decomposition of AP.This process can be divided into three stages for RDX/AP with and without Al.The kinetics model is not changed in the presence of micro-sized Al,while it is changed from CnB/D1/D1 to CnB/D1/D4 after the addition of 40 nm Al to RDX/AP.The reaction rate constant of the first stage and the end temperature of the second stage decrease,while the end temperatures of the third stage increase in the presence of 40 nm Al.The MS-FTIR results show there is a competition between the formation reactions of HNCO,N2O and NO2 during the second mass loss process.
文摘Primary solidification phase and lamellar orientation are investigated in Ti-45Al-7Nb alloy at very high ratio of temperature gradient to growth rate （G/v） by a liquid-metal-cooled directionally solidified method. It shows that Ti-45Al-7Nb alloy solidifies with primary ct phase. Longitudinal （parallel to growth direction） microstructure shows that a dendrites in solid-liquid mushy zone are discontinuous and transverse mierostructure of a dendrites is worm-like feature. Growth direction of a phase is about 80° away from （0001）,a direction, and close to （1120） a direction. The corresponding lamellar orientation is aligned at the angle of about 10° to growth direction, which is consistent with a-dendrite growth direction according to Blackburn orientation relationship. Therefore, due to the altered growth direction of a phase, the lamellar orientation in Ti-45Al-7Nb alloy is controlled at the G/v ratio of 5 × 10^9 K.sm^-2.
