为得到乌江航道千吨级标准船型的K、T指数计算经验公式,基于乌江航道和乌江千吨级船舶特点,提出适应于该船型的船舶操纵运动数学模型研讨小组(Ship Maneuvering Mathematical Model Group,MMG)模型,利用船模试验资料验证模型的准确性。...为得到乌江航道千吨级标准船型的K、T指数计算经验公式,基于乌江航道和乌江千吨级船舶特点,提出适应于该船型的船舶操纵运动数学模型研讨小组(Ship Maneuvering Mathematical Model Group,MMG)模型,利用船模试验资料验证模型的准确性。利用该模型对一系列千吨级船舶进行模拟仿真,得到Z形操舵运动曲线,并使用野本法得到该系列船舶的无因次化K、T指数。将所得结果作为样本库,利用交叉二次回归方法,计算得到适应于乌江千吨级船舶的无因次化K、T指数计算的经验公式。在此基础上使用3条实船的试验数据验证所提经验公式的精确性。展开更多
Black polyimides(BPIs)have attracted increasing attention owing to their growing demand in optoelectronics.However,commonly used black polyimides doped with black fillers suffer from poor mechanical and electrical pro...Black polyimides(BPIs)have attracted increasing attention owing to their growing demand in optoelectronics.However,commonly used black polyimides doped with black fillers suffer from poor mechanical and electrical properties.To address these issues,a new diamine(2,5-bis(4′-amino-[1,1′-biphenyl]-4-yl)-3,4-bis(4-fluorophenyl)cyclopenta-2,4-dien-1-one,TPCPFPDA)bearing a tetraphenylcyclopentadienone(TPCP)moiety bonded with benzene and fluorine units was synthesized.The diamine was reacted with 4,4′-(hexafluoroisopropylidene)diphthalic anhydride(6FDA)to yield a soluble intrinsic black polyimide(TPCPFPPI).Bonding fluorine(auxochrome group)and benzene units to TPCP can increase the conjugation ofπ-electrons systems and facilitate the movement of electron throughout the bigπbond,respectively.Owing to the structural features,the synthesized TPCPFPPI exhibited complete visible-light absorption with high blackness and opacity.Its cutoff wavelength(λ_(cut))and CIE(Commission Internationale de I′Eclairage)parameter L^(*)were 684 nm and 1.33,respectively.Moreover,TPCPFPPI displayed exceptional electrical,mechanical,and thermal properties as well as excellent solubility.A detailed theoretical calculation was conducted to gain better insight into the electronic properties of the TPCPFPPI.Results showed that the blackness of TPCPFPPI was chiefly attributed to the electron transition from highest occupied molecular orbital(HOMO)to lowest unoccupied molecular orbital(LUMO)in the diamines,where the charges primarily migrated from the aryl groups in the 2-and 5-positions to the cyclopentadienone center.The as-obtained intrinsic BPI(TPCPFPPI),exhibiting both high solubility and outstanding overall properties,has important applications in photo-electronics.展开更多
文摘为得到乌江航道千吨级标准船型的K、T指数计算经验公式,基于乌江航道和乌江千吨级船舶特点,提出适应于该船型的船舶操纵运动数学模型研讨小组(Ship Maneuvering Mathematical Model Group,MMG)模型,利用船模试验资料验证模型的准确性。利用该模型对一系列千吨级船舶进行模拟仿真,得到Z形操舵运动曲线,并使用野本法得到该系列船舶的无因次化K、T指数。将所得结果作为样本库,利用交叉二次回归方法,计算得到适应于乌江千吨级船舶的无因次化K、T指数计算的经验公式。在此基础上使用3条实船的试验数据验证所提经验公式的精确性。
基金supported by the National Natural Science Foundation of China (Grant Nos.51973055&52103004)the Natural Science Foundation of Hunan Province (Grant No.2021JJ50004)+1 种基金the Science Research Project of Hunan Provincial Department of Education (Grant No.21A0364)the Student Innovation and Entrepreneurship Training Program of Hunan Province (Grant No.S202211535096)。
文摘Black polyimides(BPIs)have attracted increasing attention owing to their growing demand in optoelectronics.However,commonly used black polyimides doped with black fillers suffer from poor mechanical and electrical properties.To address these issues,a new diamine(2,5-bis(4′-amino-[1,1′-biphenyl]-4-yl)-3,4-bis(4-fluorophenyl)cyclopenta-2,4-dien-1-one,TPCPFPDA)bearing a tetraphenylcyclopentadienone(TPCP)moiety bonded with benzene and fluorine units was synthesized.The diamine was reacted with 4,4′-(hexafluoroisopropylidene)diphthalic anhydride(6FDA)to yield a soluble intrinsic black polyimide(TPCPFPPI).Bonding fluorine(auxochrome group)and benzene units to TPCP can increase the conjugation ofπ-electrons systems and facilitate the movement of electron throughout the bigπbond,respectively.Owing to the structural features,the synthesized TPCPFPPI exhibited complete visible-light absorption with high blackness and opacity.Its cutoff wavelength(λ_(cut))and CIE(Commission Internationale de I′Eclairage)parameter L^(*)were 684 nm and 1.33,respectively.Moreover,TPCPFPPI displayed exceptional electrical,mechanical,and thermal properties as well as excellent solubility.A detailed theoretical calculation was conducted to gain better insight into the electronic properties of the TPCPFPPI.Results showed that the blackness of TPCPFPPI was chiefly attributed to the electron transition from highest occupied molecular orbital(HOMO)to lowest unoccupied molecular orbital(LUMO)in the diamines,where the charges primarily migrated from the aryl groups in the 2-and 5-positions to the cyclopentadienone center.The as-obtained intrinsic BPI(TPCPFPPI),exhibiting both high solubility and outstanding overall properties,has important applications in photo-electronics.
