A mild and highly efficient amine-catalyzed, IBX-mediated oxidation of aldehydes to （E） selective a, β-unsamrated aldehydes has been achieved in good yields. The process features a new oxidation of enamines to imin...A mild and highly efficient amine-catalyzed, IBX-mediated oxidation of aldehydes to （E） selective a, β-unsamrated aldehydes has been achieved in good yields. The process features a new oxidation of enamines to iminium ions in a catalytic fashion.展开更多
基金the financial support from the National Science Foun-dation (CHE-1057569,W. W.)the China 111 Project (B07023,J. L. and W. W.)+1 种基金the National Natural Science Foundation of China (20972051,X. Y.-H.)the Science and Technology Commission of Shanghai Mu-nicipality (08430703900 & 08431901800,X. Y.-H.)
文摘A mild and highly efficient amine-catalyzed, IBX-mediated oxidation of aldehydes to （E） selective a, β-unsamrated aldehydes has been achieved in good yields. The process features a new oxidation of enamines to iminium ions in a catalytic fashion.
