A π-conjugated optical functional organic compound comprising an electron donor(D) and acceptor(A) was synthesized. The crystal structure was determined through single-crystal X-ray diffraction analysis. It crystalli...A π-conjugated optical functional organic compound comprising an electron donor(D) and acceptor(A) was synthesized. The crystal structure was determined through single-crystal X-ray diffraction analysis. It crystallizes in monoclinic, space group P2_(1) with a = 9.6610(5), b = 8.9093(4), c = 26.303(1)Å, β = 96.262(4)°, V = 2250.5(2)Å^(3), Z = 4, D_(c)= 1.220 Mg/m^(3), F(000) = 872, Μr = 413.50, μ = 0.072 mm^(-1), the final R = 0.0569 and wR = 0.1700 for 8976 observed reflections with I > 2σ(I). Optical properties were studied in detail through theoretical calculation and experimental study. The result reveals that the compound exhibits excellent fluorescence performance and it can be compatible in the cytoplasm of NIH/3T3 cells, showing potential in fluorescence microscopy bioimaging.展开更多
基金supported by the Major Project of Natural Science Research in Universities of Anhui Province(KJ2020A0533,KJ2020A0525)Natural Science Foundation of Anhui Province(1508085MB21)+2 种基金National Students Research Training Program(201910371016,201910371004,S202010371055)Research Innovation Team of Fuyang Normal University(kytd201710)Key Laboratory of Degradation and Detection of Environmental Pollutants of Anhui Province。
文摘A π-conjugated optical functional organic compound comprising an electron donor(D) and acceptor(A) was synthesized. The crystal structure was determined through single-crystal X-ray diffraction analysis. It crystallizes in monoclinic, space group P2_(1) with a = 9.6610(5), b = 8.9093(4), c = 26.303(1)Å, β = 96.262(4)°, V = 2250.5(2)Å^(3), Z = 4, D_(c)= 1.220 Mg/m^(3), F(000) = 872, Μr = 413.50, μ = 0.072 mm^(-1), the final R = 0.0569 and wR = 0.1700 for 8976 observed reflections with I > 2σ(I). Optical properties were studied in detail through theoretical calculation and experimental study. The result reveals that the compound exhibits excellent fluorescence performance and it can be compatible in the cytoplasm of NIH/3T3 cells, showing potential in fluorescence microscopy bioimaging.
